| 摘要 | 第1-7页 |
| Abstract | 第7-10页 |
| Part Ⅰ Introduction | 第10-18页 |
| 1.Resonance Rayleigh scattering and its application | 第10-11页 |
| ·Light scattering phenomenon | 第10页 |
| ·Rayleigh scattering | 第10页 |
| ·Resonance Rayleigh scattering spectrometry and its application | 第10-11页 |
| 2.Resonance non-linear scattering and its application in analytical chemistry | 第11页 |
| 3.Introduction of erythrosine | 第11-18页 |
| ·Properties of erythrosine | 第11-12页 |
| ·Applications of erythrosine | 第12-13页 |
| ·Determination of erythrosine | 第13-18页 |
| Part Ⅱ Main research works | 第18-80页 |
| Chapter 1.Resonance Rayleigh scattering,second-order scattering and frequency doubling scattering spectra for studing the interaction of erythrosine with Fe(phen)_3~(2+)and its analytical application | 第18-32页 |
| 1.Experimental | 第18-19页 |
| ·Reagents | 第18-19页 |
| ·Apparatus | 第19页 |
| ·General procedure | 第19页 |
| 2.Results and discussion | 第19-31页 |
| ·Spectral characteristics | 第19-22页 |
| ·Optimum conditions for the reaction | 第22-24页 |
| ·Sensitivities of the methods | 第24-26页 |
| ·Interaction mechanism of the Ery-Fe(phen)_3~(2+) system | 第26-28页 |
| ·Reasons for resonance scattering enhancement | 第28-30页 |
| ·Selectivity of the RRS method | 第30-31页 |
| ·Analytical applications | 第31页 |
| 3.Conclusion | 第31-32页 |
| Chapter 2.Study of ethanol sensitizing effect on the interaction of erythrosine withFe(phen)_3~(2+) by resonance scattering spectra and its analytical application | 第32-50页 |
| 1.Materials and methods | 第32-33页 |
| ·Chemicals and reagents | 第32-33页 |
| ·Apparatus | 第33页 |
| ·General procedure | 第33页 |
| 2.Results and discussion | 第33-48页 |
| ·Spectral characteristics | 第33-36页 |
| ·Optimization of analytical conditions | 第36-40页 |
| ·Sensitivities of the methods | 第40页 |
| ·Interaction mechanism of the Ery-Fe(phen)_3~(2+)-ehtanol system | 第40-44页 |
| ·Reasons for RRS enhancement | 第44-46页 |
| ·Selectivity of the RRS method | 第46页 |
| ·Analytical applications | 第46-48页 |
| 3.Conclusion | 第48-50页 |
| Chapter 3.Study of organic solvents sensitizing effect on the erythrosine byresonance Rayleigh scattering,second-order scattering and frequency doublingscattering methods | 第50-66页 |
| 1.Materials and methods | 第50-51页 |
| ·Reagents | 第50页 |
| ·Apparatus | 第50-51页 |
| ·General procedure | 第51页 |
| 2.Results and discussion | 第51-64页 |
| ·Spectral characteristics | 第51-55页 |
| ·Optimum conditions for the reaction | 第55-57页 |
| ·Sensitivities of the methods | 第57-59页 |
| ·Interaction mechanism of the Ery-ethanol system | 第59-60页 |
| ·Reasons for RRS enhancement | 第60-62页 |
| ·Selectivity of the RRS method | 第62页 |
| ·Analytical applications | 第62-64页 |
| 3.Conclusion | 第64-66页 |
| Chapter 4.A highly sensitive resonance Rayleigh scattering spectra assay forerythrosine with cationic surfactants and its analytical application | 第66-80页 |
| 1.Materials and methods | 第66-67页 |
| ·Reagents | 第66页 |
| ·Apparatus | 第66-67页 |
| ·General procedure | 第67页 |
| 2.Results and discussion | 第67-79页 |
| ·RRS spectra | 第67-69页 |
| ·Optimum conditions for the reaction | 第69-71页 |
| ·Sensitivities of the methods | 第71-73页 |
| ·Interaction mechanism of the Ery-CDBAC system | 第73-74页 |
| ·Reasons for RRS enhancement | 第74-77页 |
| ·Selectivity of the RRS method | 第77-78页 |
| ·Analytical applications | 第78-79页 |
| 3.Conclusion | 第79-80页 |
| References | 第80-94页 |
| 致谢 | 第94-96页 |
| Appendix:Paper published during the graduate | 第96页 |
