Acknowledgement | 第4-8页 |
摘要 | 第8-10页 |
Abstract | 第10-11页 |
Chapter Ⅰ: General Introduction | 第15-37页 |
1. General introduction | 第15-37页 |
1.1 Background to the research | 第15-16页 |
1.2 Objectives of the research | 第16-17页 |
1.2.1 The specific objectives of this research are as follows | 第16-17页 |
1.3 Scope and limitation | 第17页 |
1.4 Significance of the research and the thesis structure | 第17-19页 |
1.5 An Oveview of catalytic fast pyrolysis | 第19-35页 |
1.5.1 Principles of biomass pyrolysis | 第21-24页 |
1.5.1.1 Pyrolysis of biomass components | 第22-24页 |
1.5.2 Catalytic fast pyrolysis of biomass mechanism | 第24-28页 |
1.5.3 Different CFP reactors potentials | 第28-30页 |
1.5.4 Challenges of CFP conversion of biomass into hydrocarbons | 第30-35页 |
1.5.4.1 Selective conversion of biomass to olefins | 第31-33页 |
1.5.4.2 Coke formation and catalyst deactivation | 第33-34页 |
1.5.4.3 Effect of reaction conditions on coke formation | 第34-35页 |
1.6 Chapter conclusions | 第35-37页 |
Chapter Ⅱ:Fast pyrolysis of different biomass and their Components:pyrolysis characteristics and kinetics | 第37-59页 |
2.1 Introduction | 第37-39页 |
2.2 Material and methods | 第39-42页 |
2.2.1 Materials | 第39页 |
2.2.2 Methods | 第39-42页 |
2.3 Results and discussion | 第42-58页 |
2.3.1 General feedstock's characteristics | 第42-43页 |
2.3.2 Thermal decomposition behavior of different biomass and its main components | 第43-48页 |
2.3.3 Determination of pyrolysis kinetics parameters of ten different biomass materials | 第48-55页 |
2.3.4 Kinetic analysis | 第55-58页 |
2.4 Chapter conclusions | 第58-59页 |
Chapter Ⅲ:Comparison of catalytic and non-catalytic pyrolysis of ten typical biomass materials to produce aromatics and olefins in a fluidized bed reactor | 第59-73页 |
3.1 Introduction | 第59-60页 |
3.2 Materials and methods | 第60-64页 |
3.2.1 Materials | 第60-61页 |
3.2.2 Experimental section | 第61-64页 |
3.3 Results and discussion | 第64-71页 |
3.3.1 Feedstocks analysis | 第64-65页 |
3.3.2 Pyrolysis products distribution | 第65-66页 |
3.3.3 Aromatics in liquid product | 第66-68页 |
3.3.4 Aromatic hydrocarbons selectivities | 第68-69页 |
3.3.5 Olefins in the gaseous product | 第69-70页 |
3.3.6 Olefin compounds selectivities | 第70-71页 |
3.4 Chapter conclusions | 第71-73页 |
Chapter Ⅳ: Effect of inorganic matters in the biomass on the catalytic production of aromatics and olefins in the fluidized-bed reactor | 第73-95页 |
4.1 Introduction | 第73-75页 |
4.2 Materials and methods | 第75-78页 |
4.2.1 Materials | 第75页 |
4.2.2 Washing treatment | 第75页 |
4.2.3 ICP-analysis | 第75-76页 |
4.2.4 SEM analysis | 第76页 |
4.2.5 Pyrolysis procedure | 第76-77页 |
4.2.6 Products analysis | 第77-78页 |
4.2.7 Data evaluation | 第78页 |
4.3 Results and discussion | 第78-93页 |
4.3.1 Characterization of biomass | 第78-79页 |
4.3.2 Effect of temperature on biomass with inorganic matters | 第79-82页 |
4.3.3 Effect of SGFR on biomass with inorganic matters | 第82-85页 |
4.3.4 Effects of temperature on biomass without inorganic matters | 第85-87页 |
4.3.5 Effects of SGFR on biomass without inorganic matters | 第87-89页 |
4.3.6 Effect of inorganic matters on hydrocarbons yields and distribution | 第89-91页 |
4.3.7 Hydrocarbons yields and selectivities at optimum conditions | 第91-93页 |
4.4 Chapter conclusions | 第93-95页 |
Chapter Ⅴ: Improving the hydrocarbon production via co-pyrolysis of bagasse with bio-plastic and dual-catalyst layout | 第95-111页 |
5.1 Introduction | 第95-96页 |
5.2 Materials and methods | 第96-99页 |
5.2.1 Materials | 第96-97页 |
5.2.2 Py-GC/MS experiments | 第97-99页 |
5.3 Results and discussion | 第99-109页 |
5.3.1 Effect of temperature on catalytic production of hydrocarbons from bagasse | 第99-101页 |
5.3.2 Effect of co-feeding ratio on hydrocarbons production using single zeolite catalyst | 第101-104页 |
5.3.3 Effect of type of the catalyst and feed-to-catalyst ratio on hydrocarbons production | 第104-107页 |
5.3.4 Effect of single and dual-catalysts layout on CFP hydrocarbons products from bagasse | 第107-109页 |
5.4 Chapter conclusions | 第109-111页 |
Chapter Ⅵ: General conclusions and recommendations | 第111-115页 |
6.1 General conclusions | 第111-112页 |
6.2 Recommendations for future work | 第112-115页 |
Author's resume | 第115-117页 |
List of references | 第117-125页 |
Publications | 第125页 |