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催化快速热解不同生物质原料生产芳烃和烯烃

Acknowledgement第4-8页
摘要第8-10页
Abstract第10-11页
Chapter Ⅰ: General Introduction第15-37页
    1. General introduction第15-37页
        1.1 Background to the research第15-16页
        1.2 Objectives of the research第16-17页
            1.2.1 The specific objectives of this research are as follows第16-17页
        1.3 Scope and limitation第17页
        1.4 Significance of the research and the thesis structure第17-19页
        1.5 An Oveview of catalytic fast pyrolysis第19-35页
            1.5.1 Principles of biomass pyrolysis第21-24页
                1.5.1.1 Pyrolysis of biomass components第22-24页
            1.5.2 Catalytic fast pyrolysis of biomass mechanism第24-28页
            1.5.3 Different CFP reactors potentials第28-30页
            1.5.4 Challenges of CFP conversion of biomass into hydrocarbons第30-35页
                1.5.4.1 Selective conversion of biomass to olefins第31-33页
                1.5.4.2 Coke formation and catalyst deactivation第33-34页
                1.5.4.3 Effect of reaction conditions on coke formation第34-35页
        1.6 Chapter conclusions第35-37页
Chapter Ⅱ:Fast pyrolysis of different biomass and their Components:pyrolysis characteristics and kinetics第37-59页
    2.1 Introduction第37-39页
    2.2 Material and methods第39-42页
        2.2.1 Materials第39页
        2.2.2 Methods第39-42页
    2.3 Results and discussion第42-58页
        2.3.1 General feedstock's characteristics第42-43页
        2.3.2 Thermal decomposition behavior of different biomass and its main components第43-48页
        2.3.3 Determination of pyrolysis kinetics parameters of ten different biomass materials第48-55页
        2.3.4 Kinetic analysis第55-58页
    2.4 Chapter conclusions第58-59页
Chapter Ⅲ:Comparison of catalytic and non-catalytic pyrolysis of ten typical biomass materials to produce aromatics and olefins in a fluidized bed reactor第59-73页
    3.1 Introduction第59-60页
    3.2 Materials and methods第60-64页
        3.2.1 Materials第60-61页
        3.2.2 Experimental section第61-64页
    3.3 Results and discussion第64-71页
        3.3.1 Feedstocks analysis第64-65页
        3.3.2 Pyrolysis products distribution第65-66页
        3.3.3 Aromatics in liquid product第66-68页
        3.3.4 Aromatic hydrocarbons selectivities第68-69页
        3.3.5 Olefins in the gaseous product第69-70页
        3.3.6 Olefin compounds selectivities第70-71页
    3.4 Chapter conclusions第71-73页
Chapter Ⅳ: Effect of inorganic matters in the biomass on the catalytic production of aromatics and olefins in the fluidized-bed reactor第73-95页
    4.1 Introduction第73-75页
    4.2 Materials and methods第75-78页
        4.2.1 Materials第75页
        4.2.2 Washing treatment第75页
        4.2.3 ICP-analysis第75-76页
        4.2.4 SEM analysis第76页
        4.2.5 Pyrolysis procedure第76-77页
        4.2.6 Products analysis第77-78页
        4.2.7 Data evaluation第78页
    4.3 Results and discussion第78-93页
        4.3.1 Characterization of biomass第78-79页
        4.3.2 Effect of temperature on biomass with inorganic matters第79-82页
        4.3.3 Effect of SGFR on biomass with inorganic matters第82-85页
        4.3.4 Effects of temperature on biomass without inorganic matters第85-87页
        4.3.5 Effects of SGFR on biomass without inorganic matters第87-89页
        4.3.6 Effect of inorganic matters on hydrocarbons yields and distribution第89-91页
        4.3.7 Hydrocarbons yields and selectivities at optimum conditions第91-93页
    4.4 Chapter conclusions第93-95页
Chapter Ⅴ: Improving the hydrocarbon production via co-pyrolysis of bagasse with bio-plastic and dual-catalyst layout第95-111页
    5.1 Introduction第95-96页
    5.2 Materials and methods第96-99页
        5.2.1 Materials第96-97页
        5.2.2 Py-GC/MS experiments第97-99页
    5.3 Results and discussion第99-109页
        5.3.1 Effect of temperature on catalytic production of hydrocarbons from bagasse第99-101页
        5.3.2 Effect of co-feeding ratio on hydrocarbons production using single zeolite catalyst第101-104页
        5.3.3 Effect of type of the catalyst and feed-to-catalyst ratio on hydrocarbons production第104-107页
        5.3.4 Effect of single and dual-catalysts layout on CFP hydrocarbons products from bagasse第107-109页
    5.4 Chapter conclusions第109-111页
Chapter Ⅵ: General conclusions and recommendations第111-115页
    6.1 General conclusions第111-112页
    6.2 Recommendations for future work第112-115页
Author's resume第115-117页
List of references第117-125页
Publications第125页

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