| 摘要 | 第1-5页 |
| Abstract | 第5-11页 |
| Chapter Ⅰ Introduction | 第11-31页 |
| ·Polymers | 第11-16页 |
| ·General introduction | 第11-12页 |
| ·Block copolymers:experiments and theories | 第12-16页 |
| ·Templated self-assembly of block copolymers | 第16-25页 |
| ·Block copolymer lithography:application in semiconductor field | 第16-18页 |
| ·Graphoepitaxy lithography and chemical epitaxy lithography | 第18-21页 |
| ·Current progress of template directed self-assembly of BCPs | 第21-25页 |
| ·Templated self-assembly of nanoparticles | 第25-29页 |
| ·Introduction of polymer/nanoparticles composites | 第25-26页 |
| ·Directed self-assembly of nanoparticles in copolymer template | 第26-28页 |
| ·Recent progress on synthesis of complex geometrical particles | 第28-29页 |
| ·Outline of the thesis | 第29-31页 |
| Chapter Ⅱ Mean-field theory of polymers and hybrid particle field theory | 第31-51页 |
| ·Coarse grain model of polymers | 第31-36页 |
| ·The freely jointed chain model | 第31-33页 |
| ·Distribution of the end-to-end vector | 第33-35页 |
| ·The Gaussian chain model | 第35-36页 |
| ·Self-consistent theory of block copolymers | 第36-45页 |
| ·Density operators of segments | 第36-37页 |
| ·Partition function of block copolymers | 第37-38页 |
| ·Derivation of free energy | 第38-40页 |
| ·Self-consistent field equations | 第40-43页 |
| ·Combinatorial screening algorithm | 第43-44页 |
| ·Pseudo-spectral algorithm | 第44-45页 |
| ·Hybrid particle field theory | 第45-51页 |
| ·Model of particles:cavities | 第46-47页 |
| ·Derivation of basic equations | 第47-49页 |
| ·Algorithm of hybrid particle field method | 第49-51页 |
| Chapter Ⅲ Directed-assembly of copolymers on graphoepitaxy template | 第51-69页 |
| ·Introduction | 第51-53页 |
| ·Model and methods | 第53-56页 |
| ·Results and discussions | 第56-68页 |
| ·Morphology of block copolymers on smooth template | 第56页 |
| ·Directed assembly of block copolymers on hexagonal template | 第56-61页 |
| ·Directed self-assembly of block copolymers on square template | 第61-63页 |
| ·Effect of the size and shape of posts on the BCP morphologies | 第63-65页 |
| ·Some complex templates to direct the assembly of BCPs | 第65-68页 |
| ·Summary | 第68-69页 |
| Chapter Ⅳ Large-length-scale order induced by rectangle template | 第69-83页 |
| ·Introduction | 第69-70页 |
| ·Model and methods | 第70-74页 |
| ·Results and discussions | 第74-81页 |
| ·Equilibrium structures of block copolymers on rectangle templates | 第74-76页 |
| ·The effects of d_y on the equilibrium structures of BCPs | 第76-79页 |
| ·The effects of d_x on the equilibrium structures of BCPs | 第79-81页 |
| ·Summary | 第81-83页 |
| Chapter Ⅴ Curved template to direct the assembly of block copolymers | 第83-95页 |
| ·Introduction | 第83-84页 |
| ·Model and methods | 第84-87页 |
| ·Results and Discussions | 第87-93页 |
| ·Directed morphology of block copolymers on circle template | 第87-89页 |
| ·The number of ring structures within concentric circles | 第89-91页 |
| ·Phase diagram by varying the radii of inner and outer circles | 第91-92页 |
| ·Assembly of block copolymers on complex curved templates | 第92-93页 |
| ·Summary | 第93-95页 |
| Chapter Ⅵ Self-assembly of rod particles in copolymer templates | 第95-107页 |
| ·Introduction | 第95-96页 |
| ·Model and methods | 第96-99页 |
| ·Results and discussions | 第99-104页 |
| ·Equilibrium structures of block copolymer and nanoparticles | 第99-101页 |
| ·Phase diagram of the block-copolymer/nanoparticle system | 第101-103页 |
| ·Effective volume fraction provided by particles with distinct shape | 第103-104页 |
| ·Summary | 第104-107页 |
| Chapter Ⅶ Conclusion and outlook | 第107-111页 |
| Bibliography | 第111-125页 |
| Publications | 第125-127页 |
| Acknowledgements | 第127-128页 |
