| 学位论文数据集 | 第3-4页 |
| 摘要 | 第4-6页 |
| ABSTRACT | 第6-7页 |
| Abbreviations | 第8-13页 |
| Chapter 1 Introduction | 第13-35页 |
| 1.1 LbL self-assembly | 第13-14页 |
| 1.2 History & development of LbL self-assembly | 第14-15页 |
| 1.3 Advantages of LbL technique over other methods | 第15-16页 |
| 1.4 Conventional LbL self-assembly methods | 第16-20页 |
| 1.4.1 Electrostatic interactions | 第17页 |
| 1.4.2 LbL assembly with hydrogen bonding | 第17-18页 |
| 1.4.3 LbL assembly with step-by-step reaction | 第18页 |
| 1.4.4 Surface sol-gel process for thin films | 第18-19页 |
| 1.4.5 Molecular recognition and bio-recognition | 第19页 |
| 1.4.6 Electrochemical LbL deposition | 第19-20页 |
| 1.5 Unconventional LbL assembling methods | 第20-28页 |
| 1.5.1 Inclusion complexes | 第21页 |
| 1.5.2 Noncovalent modification | 第21页 |
| 1.5.3 Coordination polyelectrolyte | 第21-22页 |
| 1.5.4 Electrostatic complex formation | 第22-23页 |
| 1.5.5 Hydrogen bonding complex | 第23页 |
| 1.5.6 Polymer assisted complex | 第23-24页 |
| 1.5.7 Block copolymer micelles | 第24-26页 |
| 1.5.8 Surface imprinting LbL self-assembly | 第26-28页 |
| 1.6 Fast and efficient methods for fabrication of multilayer thin films | 第28-33页 |
| 1.6.1 Spray- assisted LbL self-assembly method | 第29页 |
| 1.6.2 Spin assisted LbL self-assembly method | 第29-30页 |
| 1.6.3 Spin- spray LbL self-assembly method | 第30页 |
| 1.6.4 Dipping in agitated solutions LbL self-assembly method | 第30-31页 |
| 1.6.5 Electrical field directed LbL self-assembly method | 第31页 |
| 1.6.6 Dewetting method of LbL self-assembly | 第31-32页 |
| 1.6.7 High gravity filed assisted LbL self-assembly method | 第32-33页 |
| 1.7 Thesis frame work | 第33-35页 |
| Chapter 2 Layer-by-layer self-assembly under high-gravity field withpolymer micelles as building block | 第35-55页 |
| 2.1 Introduction | 第35-36页 |
| 2.2 Experiment section | 第36-39页 |
| 2.2.1 Materials and instruments | 第36-37页 |
| 2.2.2 The high gravity equipment | 第37-38页 |
| 2.2.3 Preparation of substrate | 第38页 |
| 2.2.4 Preparation of (pyrene loaded) polymer micelles | 第38-39页 |
| 2.2.5 Fabrication of multilayers under conventional dipping conditions | 第39页 |
| 2.2.6 Fabrication of multilayers in HG fields | 第39页 |
| 2.3 Results and discussion | 第39-53页 |
| 2.3.1 LbL of PDDA and PS-PAA polymer micelles under conventional dippingconditions | 第39-41页 |
| 2.3.2 LbL of PDDA and PS-PAA polymer micelles under a HG field | 第41-44页 |
| 2.3.3 LbL of PDDA and pyrene incorporated PS-PAA polymer micelles under aHG field | 第44-45页 |
| 2.3.4 Release of pyrene from PDDA/pyrene incorporated PS-PAA polymermicelles multilayers | 第45-48页 |
| 2.3.5 Surface morphologies of PDDA/PS-PAA multilayers | 第48-53页 |
| 2.4 Conclusion | 第53-55页 |
| Chapter 3 Layer-by-layer self-assembly under high-gravity field withgraphene oxide as building block | 第55-75页 |
| 3.1 Introduction | 第55-56页 |
| 3.2 Experiment section | 第56-61页 |
| 3.2.1 Materials and instruments | 第56-57页 |
| 3.2.2 Preparation of substrate | 第57-58页 |
| 3.2.3 Preparation of GO by Hummers method | 第58-59页 |
| 3.2.4 Fabrication of PDDA/ GO multilayers | 第59-61页 |
| 3.3 Results and discussion | 第61-72页 |
| 3.3.1 Characterization of prepared GO | 第61-63页 |
| 3.3.2 LbL of PDDA and GO under conventional dipping conditions | 第63-67页 |
| 3.3.3 LbL of PDDA and GO under HG field | 第67-69页 |
| 3.3.4 Surface morphologies of PDDA/PS-PAA multilayers | 第69-70页 |
| 3.3.5 Effect of HG field on the PDDA/GO multilayers construction | 第70-72页 |
| 3.4 Conclusion | 第72-75页 |
| Chapter 4 Improving the efficiency of imprinting through high-gravityfield | 第75-93页 |
| 4.1 Introduction | 第75-76页 |
| 4.2 Experiment section | 第76-80页 |
| 4.2.1 Materials and instruments | 第76-77页 |
| 4.2.2 Quartz substrates surface modification | 第77页 |
| 4.2.3 Fabrication of surface molecular imprinted multilayers | 第77-79页 |
| 4.2.4 The extraction and loading of Por in conventional dipping method | 第79页 |
| 4.2.5 The extraction and loading of Por under HG field method | 第79-80页 |
| 4.3 Results and discussion | 第80-90页 |
| 4.3.1 PAH-Por imprinting complex formation | 第80页 |
| 4.3.2 Fabrication of SMI-LbL self- assembled films | 第80-81页 |
| 4.3.3 Cross-linking of multilayer films | 第81-82页 |
| 4.3.4 Template molecule Por extraction kinetics in conventional dipping methodand HG field method | 第82-84页 |
| 4.3.5 Template molecule Por reloading kinetics in conventional dipping method andHG field method | 第84页 |
| 4.3.6 Template molecule extraction and reloading in conventional dipping and HGfield method | 第84-86页 |
| 4.3.7 Por reloading kinetics in different bulk concentration | 第86-87页 |
| 4.3.8 Binding Constant for bulk concentration in dipping and HG field | 第87-88页 |
| 4.3.9 Surface morphology study | 第88-90页 |
| 4.4 Conclusion | 第90-93页 |
| Chapter 5 Conclusion | 第93-95页 |
| References | 第95-117页 |
| Acknowledgements | 第117-119页 |
| List of Publications | 第119-121页 |
| Resume of the Author | 第121页 |
| Resume of the Supervisor | 第121-123页 |
| 博士研究生学位论文答辩委员会决议书 | 第123-124页 |
