| 摘要 | 第5-7页 |
| Abstract | 第7-9页 |
| Chapter 1:Introduction | 第18-38页 |
| 1.1 The early proposed catalysts for oxygen reduction reaction | 第20-21页 |
| 1.2 Physicochemical properties of carbides relevant for ORR activity | 第21-24页 |
| 1.3 Carbides as supports for ORR activity | 第24-25页 |
| 1.4 Carbides and non-metal support as ORR electrocatalysts | 第25-26页 |
| 1.5 Carbonitride support | 第26-27页 |
| 1.6 Methods relevant for tuning physicochemical properties of carbon and carbonitrides support | 第27-29页 |
| 1.7 Reference | 第29-38页 |
| Chapter 2:Experimental Preparation | 第38-66页 |
| 2.1 Main reagent adopted in experiments | 第38页 |
| 2.2 Instruments | 第38-39页 |
| 2.3 Synthetic methods for metal carbides | 第39-54页 |
| 2.3.1 Direct element combination | 第39页 |
| 2.3.2 Carbothermal Synthesis | 第39-42页 |
| 2.3.3 Sol-gel synthesis | 第42-43页 |
| 2.3.4 Gas phase reaction synthesis | 第43-45页 |
| 2.3.5 Solvothermal Synthesis | 第45-47页 |
| 2.3.6 Sonochemical synthesis | 第47-49页 |
| 2.3.7 Electrochemical synthesis | 第49-51页 |
| 2.3.8 Solid State Metal Oxide-Organic Reaction | 第51-54页 |
| 2.4 Post-synthesis heat treatment of carbides | 第54-56页 |
| 2.5 Reference | 第56-66页 |
| Chapter 3:Catalytic Effect of Co@TiC_(0.25)N_(0.75):the Electrocatalyst for Oxygen Reduction Reaction Activity in Alkaline Water | 第66-94页 |
| 3.1 Introduction | 第66-68页 |
| 3.2 Experimental section | 第68-72页 |
| 3.2.1 Electrocatalysts preparation | 第68-69页 |
| 3.2.2 Electrocatalysts synthetic mechanism | 第69-71页 |
| 3.2.3 Oxygen Reduction Reaction in Alkaline water | 第71-72页 |
| 3.3 Result and discussion | 第72-88页 |
| 3.3.1 The structural property of the electrocatalyst | 第72-82页 |
| 3.3.2 Co distribution on TiC_(0.25)N_(0.75) support | 第82-84页 |
| 3.3.3 Discussion of Oxygen Reduction Reaction Performance | 第84-87页 |
| 3.3.4 Kinetic modeling | 第87-88页 |
| 3.4 Conclusions | 第88-89页 |
| 3.5 Reference | 第89-94页 |
| Chapter 4:Solid-Solid Separation derived C@CoC_x for High Current Density and Efficient Oxygen Reduction Activity in Alkaline Water | 第94-114页 |
| 4.1 Introduction | 第94-95页 |
| 4.2 Experimental section | 第95-97页 |
| 4.2.1 Catalyst preparation | 第95-96页 |
| 4.2.2 Oxygen reduction of alkaline water | 第96-97页 |
| 4.3 Result and discussion | 第97-110页 |
| 4.3.1 Effect of synthesis design on structural properties of catalyst | 第97-98页 |
| 4.3.2 Structural property of the catalysts,surface area and pore distributions | 第98-103页 |
| 4.3.3 Oxygen reduction reaction activity and Kinetics modeling | 第103-110页 |
| 4.4 Conclusion | 第110页 |
| 4.5 References | 第110-114页 |
| Chapter 5:Single Phase Anti-perovskite Ternary Metal carbides for Oxygen Reduction Reaction on the Surface of Alkaline Water | 第114-142页 |
| 5.1 Introduction | 第114-115页 |
| 5.2 Experiment | 第115-118页 |
| 5.2.1 Anti-perovskite ternary metal carbides preparation | 第115-116页 |
| 5.2.2 Characterization | 第116-118页 |
| 5.3 Results and discussion | 第118-136页 |
| 5.3.1 Physicochemical property of anti-perovskite metal carbides | 第118-129页 |
| 5.3.2 Electrochemical performance of anti-perovskite metal carbides | 第129-136页 |
| 5.4 Conclusion | 第136-137页 |
| 5.5 References | 第137-142页 |
| Chapter 6:Summary and Outlook | 第142-146页 |
| 6.1 Summary | 第142-144页 |
| 6.1.1 Titanium carbonitride as a support for nanoparticles for ORR activity | 第142页 |
| 6.1.2 Hollow carbon supported CoC_x catalyst for alkaline water oxygen reduction activity | 第142-143页 |
| 6.1.3 Modified catalytic property of anti-perovskite metal carbides | 第143-144页 |
| 6.2 Outlook | 第144-146页 |
| Appendix | 第146-148页 |
| Acknowledgement | 第148-150页 |
| Author's resume and academic papers and research results published during the course of this degree | 第150-152页 |
