| 中文摘要 | 第6-7页 |
| ABSTRACT | 第7-8页 |
| Chapter 1 Summary of Literature | 第12-55页 |
| 1.1 Introduction | 第12-16页 |
| 1.2 Utilization and importance of CO_2 for DRM reaction | 第16-17页 |
| 1.3 Research progress of CH_4/CO_2 reforming reaction | 第17-20页 |
| 1.3.1 Syngas and CH_4/CO_2 reforming | 第17页 |
| 1.3.2 Reaction mechanisms for CH_4/CO_2 reforming | 第17-20页 |
| 1.4 The main aspects of the research on CH_4/CO_2 reforming reaction | 第20-40页 |
| 1.4.1 Effect of additives | 第22-30页 |
| 1.4.2 Effect of carriers | 第30-34页 |
| 1.4.3 Effect of catalyst preparation methods | 第34-38页 |
| 1.4.4 Change of process conditions | 第38页 |
| 1.4.5 Kinetics and thermodynamic studies | 第38-40页 |
| 1.5 Research on biomass reforming reaction | 第40-42页 |
| 1.6 References | 第42-55页 |
| Chapter 2 Hydrogen and syn gas production via CO_2 dry Reforming of Methane over Mg /Lapromoted Co-Ni/ MSU-S catalyst | 第55-81页 |
| 2.1 Introduction | 第55-57页 |
| 2.2 Experimental | 第57-60页 |
| 2.2.1 Synthesis of MSU-S | 第57页 |
| 2.2.2 Preparation of xMg/La promoted Co-Ni catalysts | 第57-58页 |
| 2.2.3 Characterization of fresh and used catalysts | 第58-59页 |
| 2.2.4 Study of catalytic activity | 第59-60页 |
| 2.3 Results and discussion | 第60-75页 |
| 2.3.1 Catalyst characterization | 第60-69页 |
| 2.3.2 Evaluation of catalytic performance | 第69-71页 |
| 2.3.3 Effect of reaction temperature and space velocity on catalytic activity | 第71-73页 |
| 2.3.4 Effect of catalyst composition on activity and stability | 第73-75页 |
| 2.4 References | 第75-81页 |
| Chapeter 3 Role of CeO_2 for Hydrogen production and Carbon suppression over Ni-basedMCM-22 catalyst for dry reforming of Methane | 第81-103页 |
| 3.1 Introduction | 第81-83页 |
| 3.2 Experimental | 第83-84页 |
| 3.2.1 Preparation of MCM-22 | 第83页 |
| 3.2.2 Preparation of catalysts | 第83-84页 |
| 3.2.3 Characterization of catalysts | 第84页 |
| 3.3 Results and discussion | 第84-96页 |
| 3.3.1 BET, XRD, O_2 –TPD, H_2 –TPR, and FT-IR analysis of catalysts | 第84-91页 |
| 3.3.2 Evaluation of Catalytic activity | 第91-93页 |
| 3.3.3 Effect of reaction temperature | 第93-94页 |
| 3.3.4 Effect of CeO_2 on coking | 第94-96页 |
| 3.4 References | 第96-103页 |
| Chapter 4 Study of Coking and Catalyst Stability over CaO promoted Ni-Based MCFsynthesized by different methods for CH_4/CO_2 reforming reaction | 第103-121页 |
| 4.1 Introduction | 第103-105页 |
| 4.2 Experimental section | 第105-106页 |
| 4.2.1 Synthesis of Mesocellular siliceous foams (MCF) | 第105页 |
| 4.2.2 Catalysts preparation | 第105-106页 |
| 4.3 Results and discussion | 第106-115页 |
| 4.3.1 N2 adsorption isotherm and FT-IR analysis of MCF | 第106-107页 |
| 4.3.2 XRD, H_2-TPR and FTIR studies of catalysts | 第107-110页 |
| 4.3.3 Evaluation of catalytic performance and stability | 第110-112页 |
| 4.3.4 Influence of reaction temperature on atalytic activity | 第112-113页 |
| 4.3.5 Effect of catalyst preparation methods on the activity and stability | 第113-115页 |
| 4.4 References | 第115-121页 |
| Chapter 5 Hydrogen production by Corncob/CO_2 dry reforming over CeO_2 modified Ni-basedMCM-22 catalyst | 第121-144页 |
| 5.1 Introduction | 第121-123页 |
| 5.2 Materials and Methods | 第123-125页 |
| 5.2.1 Preparation of corncob powder | 第123-124页 |
| 5.2.2 Apparatus used for corncob dry reforming and procedure | 第124-125页 |
| 5.3 Results and discussion | 第125-138页 |
| 5.3.1 Detailed analysis of corncob composition | 第125-127页 |
| 5.3.2 XRD, BET, H_2 –TPR, CO_2 (or O_2) –TPD UV-vis and FT-IR analysis | 第127-133页 |
| 5.3.3 H_2 production using CO_2/corncob (biomass) reforming reaction at 750 oC | 第133-135页 |
| 5.3.4 Catalytic activity at different temperatures and properties of coking | 第135-138页 |
| 5.4 References | 第138-144页 |
| Chapter 6 Conclusion and Novelty | 第144-147页 |
| 6.1 Conclusion | 第144-146页 |
| 6.2 Novelties | 第146-147页 |
| List of Publications | 第147-149页 |
| Curriculum Vita | 第149-150页 |
| Acknowledgements | 第150-152页 |
