首页--工业技术论文--电工技术论文--独立电源技术(直接发电)论文--化学电源、电池、燃料电池论文--燃料电池论文

Preparation of Anion Exchange Membranes for Electrodialysis and Fuel Cell

Abstract第4-5页
Chapter 1 Introduction and Background第10-34页
    1.1 Introduction第10-12页
    1.2 Alkaline Fuel Cells第12-14页
        1.2.1 Traditional Alkaline Fuel Cell第13页
        1.2.2 Anion Exchange Membrane Fuel Cell(AEMFC)第13-14页
    1.3 AEMs for Alkaline Fuel Cell Application第14-29页
        1.3.1 Summary of AEM Chemistries Used in AFC第14-15页
        1.3.2 Problems with the Use of AEMs第15-16页
        1.3.3 Phase Separated Polymer第16-24页
            1.3.3.1 Comb-Shaped Copolymer第16-18页
            1.3.3.2 Block Copolymer第18-21页
            1.3.3.3 Side-Chain Type Structure第21-24页
        1.3.4 Cross-Linking Ionomers第24-29页
    1.4 Electrodialysis(ED)第29-30页
        1.4.1 AEMs for ED Application第29-30页
            1.4.1.1 Homogeneous AEM第29-30页
            1.4.1.2 Composite AEM第30页
    1.5 Objective of this Thesis第30-34页
Chapter 2 Clustering of Ion on Side Chains Grafted onto the Polymer Backbone for Fuel Cell Application第34-54页
    2.1 Introduction第34-38页
    2.2 Experimental第38-41页
        2.2.1 Materials第38页
        2.2.2 Synthesis of Brominated Poly(2,6-dimethyl-phenylene oxide) (x-BPPO)第38-39页
        2.2.3 Preparation第39页
        2.2.4 Procedure for Quatemization of x-CT-PPO-y第39页
        2.2.5 Instruments and Characterizations第39-41页
    2.3 Results and discussion第41-51页
        2.3.1 Synthesis and Characterization of Brominated BPPO第41-42页
        2.3.2 Cross-linking/Film Formation/Quatemization第42-43页
        2.3.3 FT-IR Spectra of the Membranes第43-44页
        2.3.4 TGA and Mechanical Properties第44-46页
        2.3.5 IEC,Water Uptake and Swelling Ratio第46-48页
        2.3.6 Hydroxide Conductivity第48-50页
        2.3.7 Alkaline Stability第50-51页
    2.4 Conclusion第51-52页
    2.5 Acknowledgement第52-54页
Chapter 3 Dimethyl amine based alkali-stable crosslinked anion exchange membrane prepared via a simple and facile way第54-70页
    3.1 Introduction第54-57页
    3.2 Experimental第57-61页
        3.2.1 Materials第57页
        3.2.2 (BPPO)Base Membrane第57-58页
        3.2.3 Preparation of Crosslinked Anion Exchange Membrane第58-60页
            3.2.3.1 Reaction of BPPO Film with DMA第58-59页
            3.2.3.2 Quaternization of C-TA-PPO-z第59-60页
        3.2.4 Instruments and Characterizations第60-61页
    3.3 Results and discussion第61-68页
        3.3.1 Synthesis and Characterization of Crosslinked CQPPO-z Membranes第61-63页
        3.3.2 TGA and Mechanical Properties第63-64页
        3.3.3 IEC,Water Uptake and Swelling ratio第64-66页
        3.3.4 Hydroxide Conductivity第66-67页
        3.3.5 Alkaline Stability第67-68页
    3.4 Conclusion第68-69页
    3.5 Acknowledgements第69-70页
Chapter 4 Poly(Vinylidene Fluoride)Based Composite Membranes for Electrodialysis Application第70-92页
    4.1 Introduction第70-72页
    4.2 Experimental第72-79页
        4.2.1 Materials第72-73页
        4.2.2 Synthesis of composite polymer(TM-xx)第73页
        4.2.3 Membrane Preparation第73页
        4.2.4 Measurements第73-74页
        4.2.5 Electrochemical Properties of Ion-Exchange Membranes第74-76页
        4.2.6 Current-Voltage(Ⅰ-Ⅴ)Characteristic and Chronopotentiometry第76-77页
        4.2.7 Electrodialysis Experiment第77-79页
    4.3 Results and Discussion第79-90页
        4.3.1 Synthesis of Composite Polymer(TM-xx)and ATR-FTIR Characterization第79-81页
        4.3.2 Membrane Morphologies第81-82页
        4.3.3 Mechanical and TGA Analysis第82-83页
        4.3.4 Physicochemical and Electrochemical Properties of the Membranes第83-84页
        4.3.5 Electrochemical Behavior of the Composite Membranes第84-88页
        4.3.6 Desalination of NaCl by ED第88-90页
    4.4 Conclusion第90-91页
    4.5 Acknowledgments第91-92页
Chapter 5 Overall Conclusions and Future Work第92-96页
    5.1 Overall Conclusions第92-94页
    5.2 Future Work第94-96页
References第96-114页
Acknowledgements第114-116页
List of published/accepted articles第116页

论文共116页,点击 下载论文
上一篇:CitERF13 与 CitVHA-c4 协同调控柑橘果实柠檬酸代谢研究
下一篇:金属卡宾活化C-H和O-H键的理论计算研究