| 学位论文数据集 | 第3-5页 |
| Abstract | 第5-6页 |
| 摘要 | 第7-8页 |
| Abbreviations | 第8-18页 |
| Chapter 1:Introduction | 第18-44页 |
| 1.1 Introduction to Supramolecular Chemistry | 第18页 |
| 1.2 Self Assembly | 第18-20页 |
| 1.2.1 Types of Self Assembly | 第19-20页 |
| 1.2.2 Common Features of Self-Assembly | 第20页 |
| 1.3 Supramolecular Assembly through Hydrogen-bonding | 第20-28页 |
| 1.3.1 Linear Polymers | 第22-26页 |
| 1.3.1.1 Grafted Architectures | 第23-24页 |
| 1.3.1.2 Networks through Hydrogen-Bonding | 第24-26页 |
| 1.3.2 Supramolecular Assembly through Metal Complexation | 第26-27页 |
| 1.3.3 Host-guest Interactions and Biological Systems | 第27-28页 |
| 1.4 From Supramolecular Chemistry to Supramolecular Materials | 第28-30页 |
| 1.5 Macroscopic Assembly through Various Interactions | 第30-33页 |
| 1.5.1 Macroscopic Assembly of Whitesides Group through Weak Long-Range Interactions | 第31-32页 |
| 1.5.2 Macroscopic Assembly through Chemical Forces | 第32-33页 |
| 1.6 Macroscopic Assembly of Hydrogels Systems | 第33-37页 |
| 1.6.1 Macroscopic Self-Assembly of Hydrogels through Molecular Recognition | 第33-36页 |
| 1.6.1.1 Gel Self-Assembly through Host-Guest Interactions | 第34页 |
| 1.6.1.2 Photo Switchable Gel Self-Assembly | 第34页 |
| 1.6.1.3 Solvent-Switchable Gel Self-Assembly | 第34-35页 |
| 1.6.1.4 Redox-Switchable Gel Self-Assembly | 第35页 |
| 1.6.1.5 pH-Switchable Gel Self-Assembly | 第35-36页 |
| 1.6.1.6 Temperature-Sensitive Gel Self-Assembly | 第36页 |
| 1.6.2 Macroscopic Assembly of Hydrogels through Electrostatic Interactions | 第36页 |
| 1.6.3 Macroscopic Assembly of Hydrogels through Magnetic Interactions | 第36-37页 |
| 1.7 Macroscopic assembly of rigid building blocks | 第37-39页 |
| 1.7.1 Macroscopic Assembly of Rigid Building Blocks Modified with LBL | 第37-38页 |
| 1.7.2 Concept of Flexible Spacing Coating in Macroscopic Assembly | 第38-39页 |
| 1.8 Macroscopic Assembly through Combining Long Range Forces and Molecular Recognition | 第39-40页 |
| 1.9 Applications of Macroscopic Assembly | 第40-41页 |
| 1.10 Aims and Objectives of the Work | 第41-44页 |
| Chapter 2:Macroscopic Assembly Based on Coordinate Covalent Interactions | 第44-58页 |
| 2.1 Introduction | 第44-45页 |
| 2.2 Experimental | 第45-48页 |
| 2.2.1 Materials and Instrument | 第45-46页 |
| 2.2.2 Preparation of PSS Cu~(+2) Solution | 第46页 |
| 2.2.3 Fabrication of Building Blocks | 第46页 |
| 2.2.4 LBL Modification of Building Blocks | 第46-48页 |
| 2.2.5 Assembly-disassembly Experiments | 第48页 |
| 2.3 Results and Discussions | 第48-55页 |
| 2.3.1 UV-Visible Characterization on Quartz Cells | 第49-51页 |
| 2.3.2 Assembly and Disassembly Experiment through Coordinate Covalent Interactions | 第51-52页 |
| 2.3.3 Disassembly Experiments | 第52-54页 |
| 2.3.4 Reproducible Loading and Unloading of PSS-Cu~+ in Multilayer's | 第54-55页 |
| 2.4 Conclusion | 第55-58页 |
| Chapter 3 Toward Understanding Whether Interactive Surface Area Could Direct OrderedMacroscopic Supramolecular Self-Assembly | 第58-78页 |
| 3.1 Introduction | 第58-59页 |
| 3.2 Experimental Section | 第59-62页 |
| 3.2.1 Materials and Instrument | 第59页 |
| 3.2.2 Fabrication of Cylindrical Building Blocks | 第59-60页 |
| 3.2.3 Surface Modification of the Building Blocks | 第60-61页 |
| 3.2.4 Assembly Processes and Statistical Analysis | 第61-62页 |
| 3.3 Results and Discussion | 第62-77页 |
| 3.3.1 Statistical Analysis of Assembled Patterns | 第63-68页 |
| 3.3.2 Transformation of Assembled Forms with Extra Interference of Energy | 第68-69页 |
| 3.3.3 Measurement of Film Thickness | 第69-70页 |
| 3.3.4 Force Measurement with Different d/h Ratios | 第70-73页 |
| 3.3.5 Ordering the Macroscopic Assembly | 第73-77页 |
| 3.5 Conclusion | 第77-78页 |
| Chapter 4:Conclusion | 第78-80页 |
| 4.1 Coordinate Interactions | 第78页 |
| 4.2 Surface Interactive Area | 第78-80页 |
| References | 第80-94页 |
| Acknowledgement | 第94-96页 |
| List of Publications | 第96-98页 |
| Resume of Author | 第98-100页 |
| Resume of Supervisor | 第100-102页 |
| 附件 | 第102-103页 |
