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转换型高分子分散剂的可控合成与应用

摘要第3-4页
Abstract第4-5页
Chapter 1 Introduction第9-34页
    1.1 Particle aggregation and dispersion第9-10页
    1.2 Molecular surfactants第10-12页
        1.2.1 Chemical surface modifications第10-11页
        1.2.2 Physical surface modifications第11-12页
    1.3 Polymeric surfactants/dispersants第12-20页
        1.3.1 Controlled/living radical polymerization第14-15页
        1.3.2 Homopolymer dispersants第15-16页
        1.3.3 Diblock copolymer dispersants第16-17页
        1.3.4 Triblock copolymer dispersants第17-18页
        1.3.5 Comb copolymer dispersants第18-19页
        1.3.6 Dendritic copolymer dispersants第19-20页
    1.4 Switchable surfactants第20-21页
    1.5 pH-triggered latex systems第21-22页
    1.6 CO_2-switchable latex systems第22-31页
        1.6.1 CO_2-switchable molecular surfactant approach第23-24页
        1.6.2 CO_2-switchable initiator approach第24-25页
        1.6.3 CO_2-switchable comonomer approach第25-26页
        1.6.4 CO_2-switchable surfmer approach第26-28页
        1.6.5 CO_2-switchable polymeric surfactant approach第28-30页
        1.6.6 Applications of CO_2-switchable latexes and emulsions第30-31页
    1.7 Research focus and design第31-34页
Chapter 2 Polymeric Surfactant Synthesis and Characterization第34-55页
    2.1 Introduction第34页
    2.2 Materials第34-35页
    2.3 Instruments第35-36页
    2.4 Synthesis of AB diblock copolymer dispersants第36-43页
        2.4.1 AB diblock copolymers with fixed stabilizing chain第36-40页
        2.4.2 AB diblock copolymers with fixed anchoring chain第40-43页
    2.5 Synthesis of ABA triblock copolymer dispersants第43-45页
    2.6 Synthesis of comb copolymer dispersants第45-47页
    2.7 Preparation of SiO2 particle dispersion第47页
    2.8 Rheological and particle size measurement第47-48页
    2.9 Synthesis of diblock polymeric surfactants第48-50页
    2.10 Synthesis of latexes via emulsion (co)polymerization第50-52页
    2.11 Latex conversion calculation第52-53页
    2.12 Coagulation and redispersion of latexes第53-55页
Chapter 3 Polymeric Dispersants for Particle Dispersion and Stabilization第55-74页
    3.1 Introduction第55-56页
    3.2 Polymeric dispersant synthesis第56-57页
    3.3 Structural optimization of AB type dispersants第57-62页
        3.3.1 Anchoring chain selection第57-59页
        3.3.2 Stabilizing chain selection第59-60页
        3.3.3 Structural optimization of PDMA-b-PEMA第60-62页
    3.4 Structural optimization of ABA type dispersants第62-64页
    3.5 Structural optimization of comb type dispersants第64-65页
    3.6 Structure-performance comparisons between structural types第65-68页
    3.7 Dosage optimization of PDMA30-b-PEMA40第68-69页
    3.8 Generality of structure-performance relationships第69-73页
    3.9 Chapter summary and outlook第73-74页
Chapter 4 Solely Gas-Switchable Latexes with Reversible Coagulability and Redispersibility第74-88页
    4.1 Introduction第74-75页
    4.2 CO_2/N2-switchable latex synthesis and characterization第75-78页
    4.3 Reversible coagulation and redispersion cycles第78-84页
    4.4 Latex coagulation performance第84-87页
    4.5 Chapter summary and outlook第87-88页
Chapter 5 “Solid Emulsion”: Versatile Gas-Switchable Latex System .第88-99页
    5.1 Introduction第88-89页
    5.2 Latex powder redispersibility第89-90页
    5.3 Latex powder long-term storage stability第90-93页
    5.4 Latex system versatility第93-97页
    5.5 Chapter summary and outlook第97-99页
Chapter 6 Overall Summary and Outlook第99-102页
References第102-112页
Acknowledgements第112-114页
Personal Biography and Published Academic Papers第114-115页

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