| Abstract | 第9-10页 |
| 摘要 | 第11-13页 |
| Chapter one Organotin compound s used to synthesis C-C bond formation | 第13-41页 |
| 1.1 | 第13-25页 |
| 1.1.1 organotin reagent and catalyst | 第13-14页 |
| 1.1.2 Stille coupling reaction | 第14-17页 |
| 1.1.2.1 PalladiumCatalyst Stille Coupling Reactions | 第14-15页 |
| 1.1.2.2 Stille Coupling using (tri-n-butylstannyl)nitrobenzene | 第15-16页 |
| 1.1.2.4 Suzuki Stille Coupling Reaction using Organotin compounds | 第16-17页 |
| 1.1.3 Lewis acid Catalyzed Alkylation using Organotin Compunds | 第17-21页 |
| 1.1.3.1 AllyltributylIstannane Alkylation of N-Aromatic Imine in presence of Lewisacid | 第17-18页 |
| 1.1.3.2 Preparation of homoallylic amines catalyzed by bismuth (Ⅲ) nitrate pentahydrate in presence of organotin compound | 第18页 |
| 1.1.3.3 Allylation of imine by Iron-catalyzed and allyltributylstannane | 第18-19页 |
| 1.1.3.4 Allyltributylstannane synthesis of homoallylic amines | 第19-20页 |
| 1.1.3.5 Methylation of aryl C-H bonds using catalytic and tetramethylstannane | 第20-21页 |
| 1.1.4 One-pot synthesis of homoallylic amine in present of allyltributylstannane | 第21页 |
| 1.1.5 Tributyl allylstannane as promoter an inter molecular heck reaction | 第21-22页 |
| 1.1.6 Inter molecular aldol reactions of conjugated enones with aldehydeusingtinreagent | 第22页 |
| 1.1.7 Enolates tri-n-butyltin diatereoselective in Michael additions | 第22-23页 |
| 1.1.8 Catalytic Asymmetric Allylation | 第23-24页 |
| 1.1.9 Conclusion | 第24-25页 |
| 1.2. Tin powder used to synthesis C-C bond formation | 第25-36页 |
| 1.2.1. Tin Mediated Alkylation Reactions | 第25-26页 |
| 1.2.2. Tin alkylation of carbonyl compound using temperature to gethomoallylalcohol | 第26-27页 |
| 1.2.3 Barbier type reaction | 第27-30页 |
| 1.2.4 Tin allylation carbonyl group in one pot type reactions | 第30-33页 |
| 1.2.5 Tin metal allylation nitrostyrenes in aqueous media | 第33-34页 |
| 1.2.6 Tin -mediated (chemoslectivity) | 第34页 |
| 1.2.7 α,β unsaturated y-butyrol actones allylation by tin or indium | 第34-35页 |
| 1.2.8 Conclusion | 第35-36页 |
| 1.3 Reference | 第36-41页 |
| Chapter two Synthesis of homoallylic hydrazidesfrom aldehydes, 2-aminoisoindoline-l,3-diones and allyl bromide promoted by tin powder | 第41-62页 |
| 2.1 Tin powder as promoter "one pot" allylation hydrazone to get carbon -carbonbond formation | 第42-45页 |
| 2.1.1 Optimized reaction conditions | 第42-45页 |
| 2.2 Hydrazone allylation by allyl bromide in presence of Lewis acid | 第45-49页 |
| 2.2.1 Optimized reaction conditions | 第45-47页 |
| 2.2.2 Substrate extension | 第47-49页 |
| 2.3. Conclusion | 第49-50页 |
| 2.4. Experimental Section | 第50-60页 |
| 2.4.1 General Information | 第50页 |
| 2.4.2 General Procedure for the Synthesis of | 第50页 |
| 2.4.3 General Procedure for the Synthesis of Different hydrazones | 第50页 |
| 2.4.4 General Procedure for the Synthesis of Homoallylic Hydrazones | 第50-60页 |
| Experimental Sumarry | 第51页 |
| Experimental Part | 第51页 |
| Experimental Data | 第51-60页 |
| 2.6 References | 第60-62页 |
| Chapter three Direct amidation of hydrazones with carbonyl compounds via metal-free C-H Activation | 第62-71页 |
| Introduction | 第62-64页 |
| 3.1 CDC of N, N-Disubstituted Formamides | 第64页 |
| 3.2 C-C Bond Formation Reactions | 第64-65页 |
| 3.3 C-O Bond Formation Reactions | 第65页 |
| 3.4 C-S and C-Se Bond Formation Reactions | 第65-66页 |
| 3.5 C-N Bond Formation Reactions | 第66-68页 |
| 3.6 References | 第68-71页 |
| NMR section | 第71-87页 |
| Achivements and publications | 第87-88页 |
| Acknowledgement | 第88-89页 |
