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Boron Trifluoride Catalyzed Conversion of Nitriles to Amides

Abstract第6页
摘要第7-8页
Acknowledgement第8-12页
Abbreviations第12-14页
Chapter 1: Synthesis of difluoroboron complexes 2第14-61页
    1.1 Introduction第14-17页
    1.2 Literature review第17-45页
        1.2.1 Definition of amides第17-20页
        1.2.2 Synthesis of amides第20-28页
        1.2.3 Chemistry of amides第28-38页
        1.2.4 The Chemistry of Functional Groups Related to Amides第38-45页
    1.3 Experimental Section第45-52页
        1.3.1 General Information第45-46页
        1.3.2 General Procedure for the Preparation of 2-Cyanoacetamides 4a,4b,and 4c usingDCC/DMAP as Condensation Reagent第46-47页
        1.3.3 General Procedure for the Synthesis of 2-Cyano-2-diazoacetamides 1 via DiazoTransformation第47-48页
        1.3.4 General Procedure for the Preparation of the Difluoroboron Complexes 2 of Oxindole-3carboxamides第48-51页
        1.3.5 Preparation of 2-Oxo-1-phenylindoline-3-carbonitrile(3a)第51-52页
    1.4 Results and Discussion第52-60页
        1.4.1 Results第52-53页
        1.4.2 Discussion第53-60页
    1.5 Conclusion第60-61页
Chapter 2: Synthesis of β-keto amides/malonamides 3第61-73页
    2.1 Introduction第61-63页
    2.2 Literature review第63-65页
    2.3 Experimental section第65-69页
        2.3.1 General Procedure for the Preparation of compounds 1第65-66页
        2.3.2 General Procedure for the Preparation of compounds 3第66-67页
        2.3.3 General Procedure for the Preparation of compound 2a第67-69页
    2.4 Results and discussion第69-72页
        2.4.1 Results第69-70页
        2.4.2 Discussion第70-72页
    2.5 Conclusion第72-73页
References第73-80页
Appendix ~1H and ~(13)C spectra of compounds 1,2a and 3第80-91页
Resume of the Author第91-92页
Resume of the Supervisor第92-94页
附件第94-95页

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