| Abstract | 第10页 |
| Chapter 1 Literature Review of DCC Reactions Adjacent to α-C(sp~3)-H bond ofOxygen and Nitrogen atom Containing Substrates | 第11-100页 |
| 1.1 Introduction | 第11-12页 |
| 1.2 DCC Reactions of α-C(sp~3)-H Bond Adjacent to Oxygen Atom | 第12-13页 |
| 1.3 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Oxygen Atom and C(sp~3)-H Bond | 第13-18页 |
| 1.3.1 Metal Catalyzed Reactions | 第13-17页 |
| 1.3.2 Non-Metal Catalyzed Reactions | 第17-18页 |
| 1.4 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Oxygen Atom andC(sp~2)-H Bond | 第18-24页 |
| 1.4.1 Metal Catalyzed Reactions | 第18-22页 |
| 1.4.2 Non-Metal Catalyzed Reactions | 第22-24页 |
| 1.5 DCC Reactions between α-C(sp~3)-H bond Adjacent to Oxygen Atom andC(sp)-H Bond | 第24-25页 |
| 1.6 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Oxygen Atom withHeteroatom-Hydrogen Bond | 第25-32页 |
| 1.6.1 Metal Catalyzed Reactions | 第25-29页 |
| 1.6.2 Non-Metal Catalyzed Reactions | 第29-32页 |
| 1.7 DCC Reactions of α-C(sp~3)-H Bond Adjacent to Nitrogen Atom | 第32-33页 |
| 1.8 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Nitrogen Atom andC(sp~3)-H Bond | 第33-50页 |
| 1.8.1 Metal Catalyzed Reactions | 第33-46页 |
| 1.8.1.1 Aza-Henry type Reactions | 第33-37页 |
| 1.8.1.2 Aza-Henry type Reactions by Photo Catalyzed | 第37-39页 |
| 1.8.1.3 Mannich type Reactions | 第39-44页 |
| 1.8.1.4 Mannich type Reactions by Photo Catalyzed | 第44-46页 |
| 1.8.2 Non-Metal Catalyzed Reactions | 第46-50页 |
| 1.8.2.1 Aza-Henry type Reactions | 第46-49页 |
| 1.8.2.2 Mannich type Reactions | 第49-50页 |
| 1.9 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Nitrogen Atom and C(sp~2)-H Bond | 第50-66页 |
| 1.9.1 Metal Catalyzed Reactions | 第50-60页 |
| 1.9.1.1 Friedel-Craft type Reactions | 第50-56页 |
| 1.9.1.2 Photo-Catalyzed Reactions | 第56-58页 |
| 1.9.1.3 MBH type Reactions | 第58-60页 |
| 1.9.2 Non-Metal Catalyzed Reactions | 第60-62页 |
| 1.9.3 DCC Reactions between a-C(sp~3)-H Bond Adjacent to NitrogenAtom and C(sp)-H Bond | 第62页 |
| 1.9.4 Metal Caf:alyzed Reactions | 第62-66页 |
| 1.10 DCC Reactions between α-C(sp~3)-H Bond Adjacent to Nitrogen Atom and C(sp)-H Bond | 第66-72页 |
| 1.10.1 Metal Catalyzed Reactions | 第66-69页 |
| 1.10.2 Non-Metal Catalyzed ReactionF | 第69-72页 |
| 1.11 References | 第72-100页 |
| Chapter 2 Highly Chemoselective and Regioselective Deyhrogenative Cross-coupling Reaction between Pyridines and Ethers | 第100-117页 |
| 2.1 Introduction | 第100-101页 |
| 2.2 Optimization of the Reaction conditions | 第101-103页 |
| 2.3 Scope of Pyridines and Ethers | 第103-105页 |
| 2.4 Scope of Ethers with 2-phenyl Pyridines | 第105页 |
| 2.5 Plausible Mechanism | 第105-106页 |
| 2.6 Conclusion | 第106页 |
| 2.7 Experimental Section | 第106-107页 |
| 2.7.1 Reagents and Instruments | 第106-107页 |
| 2.7.2 General Procedure of the DCC Reaction between Pyridine 1 and Ether 2 for the Synthesis of Mono-Coupled pyridine 3 | 第107页 |
| 2.8 Characterization of the 2- or 4-coupled Pyridines | 第107-114页 |
| 2.9 References | 第114-117页 |
| Chapter 3 Dehydrogenative Cross-coupling Reaction between N-Aryl α-Amino Acid Esters and Phenols or Phenol Derivative for Synthesis of α-Aryl α-Amino Acid Esters | 第117-156页 |
| 3.1 Introduction | 第117-118页 |
| 3.2 Optimization of the Reaction Conditions | 第118-121页 |
| 3.3 Scope of Phenol Derivatives with N-Aryl Glycine Esters | 第121-122页 |
| 3.4 Scope of N-Aryl Glycine Esters with Phenol | 第122-123页 |
| 3.5 DCC Reaction between N-Aryl Glycine Esters 1a-i and 1, 3, 5-Trimethoxybenzene 4 | 第123-124页 |
| 3.6 Plausible Mechanism for the DCC Reaction | 第124-125页 |
| 3.7 Conclusion | 第125-126页 |
| 3.8 Experimental Section | 第126-153页 |
| 3.8.1 Reagents and Instrument | 第126页 |
| 3.8.2 General Procedure for the DCC Reaction between Glycine Ester Derivatives 1 and Phenols 2 or 1, 3, 5-Trimethxoybenzene 4 | 第126页 |
| 3.8.3 Characterization of DCC Products | 第126-139页 |
| 3.8.4 Structures Confirmed by ~1H-NMR and HMBC | 第139-153页 |
| 3.9 References | 第153-156页 |
| List of Abbreviation | 第156-159页 |
| Representative Spectrums | 第159-170页 |
| Publications During Ph.D | 第170-171页 |
| Acknowledgements | 第171页 |
