| 学位论文数据集 | 第3-4页 |
| Dedication | 第4-5页 |
| ABSTRACT | 第5-8页 |
| 摘要 | 第9-20页 |
| Chapter 1 Introduction and literature review | 第20-36页 |
| 1.1 Purpose and significance of the study | 第20-22页 |
| 1.2 Progress in the development of adsorptive desulfurization | 第22-24页 |
| 1.2.1 Hydrodesulfurization (HDS) | 第23页 |
| 1.2.2 Non-hydrodesulfurization technology | 第23-24页 |
| 1.3 Porous materials | 第24-25页 |
| 1.4 Metal Organic Frameworks (MOFs) | 第25-31页 |
| 1.4.1 Structure of MOFs | 第25-26页 |
| 1.4.2 Analogous MOFs | 第26页 |
| 1.4.3 Methods of synthesis of MOFs | 第26-29页 |
| 1.4.4 Functionalization of MOFs | 第29-31页 |
| 1.5 Applications of MOFs | 第31-33页 |
| 1.5.1 Applications of MOFs in Catalysis | 第31页 |
| 1.5.2 Applications of MOFs in gas storage | 第31页 |
| 1.5.3 Application of MOFs in selective gas adsorption | 第31-32页 |
| 1.5.4 Application of MOFs in adsorption desulfurization | 第32-33页 |
| 1.6 Research methodology and main content | 第33-36页 |
| Chapter 2 Experimental section | 第36-50页 |
| 2.1 Introduction | 第36-37页 |
| 2.2 Materials and equipment facilities | 第37-39页 |
| 2.2.1 Materials for experiments | 第37-38页 |
| 2.2.2 Facilities for the experiments | 第38-39页 |
| 2.3 Synthesis of MOFs | 第39-40页 |
| 2.3.1 Synthesis of Eu-MOF | 第39页 |
| 2.3.2 Synthesis of Cu-BTC MOF | 第39-40页 |
| 2.4 Synthesis of MOF/porous composite materials | 第40-42页 |
| 2.4.1 Synthesis of Cu-BTC/γ-Al_2O_3 composites | 第40-41页 |
| 2.4.2 Synthesis of Cu-BTC/Clay composites | 第41页 |
| 2.4.3 Synthesis of Cu-BTC/AC composites | 第41-42页 |
| 2.5 Characterization of MOFs and MOF/composite materials | 第42-43页 |
| 2.5.1 XRD characterization | 第42页 |
| 2.5.2 FT-IR characterization | 第42页 |
| 2.5.3 TEM observations | 第42-43页 |
| 2.5.4 N_2 adsorption-desorption isotherms | 第43页 |
| 2.6 Preparation of model oil solutions | 第43-44页 |
| 2.6.1 Preparation of 1000 ppm thiophene/n-Octane model oil | 第43-44页 |
| 2.7 Evaluation of adsorption desulfurization performance of MOFs and MOFs composites | 第44-50页 |
| 2.7.1 Adsorption desulfurization reaction conditions | 第44-45页 |
| 2.7.2 Analysis of samples and data processing | 第45-50页 |
| Chapter 3 Structure of Eu-MOF and Cu-BTC and their performance inAdsorptive desulfurization of model oil | 第50-80页 |
| 3.1 Introduction | 第50页 |
| 3.2 Characterization and adsorption desulfurization performance of Eu-MOF | 第50-63页 |
| 3.2.1 Characterizations of Eu-MOF | 第50-55页 |
| 3.2.2 Evaluation of adsorption desulfurization performance of Eu-MOF | 第55-60页 |
| 3.2.3 Adsorption kinetics behavior of Eu-MOF | 第60-63页 |
| 3.3 Characterization and adsorption desulfurization performance of Cu-BTC MOF | 第63-77页 |
| 3.3.1 Characterization of Cu-BTC MOF | 第63-68页 |
| 3.3.2 Evaluation of adsorptive desulfurization performance of Cu-BTC MOF | 第68-74页 |
| 3.3.3 Study of adsorption kinetics of Cu-BTC MOF | 第74-77页 |
| 3.4 Summary | 第77-80页 |
| Chapter 4 Structural characterization of Cu-BTC/γ-Al_2O_3 compositematerials and their adsorptive desulfurization performance for removal ofthiophene from model oil | 第80-96页 |
| 4.1 Introduction | 第80-81页 |
| 4.2 Characterization of Cu-BTC/γ-Al_2O_3 composites | 第81-85页 |
| 4.2.1 Study of crystal structure of Cu-BTC/γ-Al_2O_3 composites | 第81页 |
| 4.2.2 Analysis of composition and functional groups of Cu-BTC/γ-Al_2O_3 composites | 第81-82页 |
| 4.2.3 Study of crystal inner structure of Cu-BTC/γ-Al_2O_3 composites | 第82-83页 |
| 4.2.4 Study of surface area and pore structure of Cu-BTC/γ-Al_2O_3 composites | 第83-85页 |
| 4.3 Adsorptive desulfurization performance of Cu-BTC/γ-Al_2O_3 composites | 第85-90页 |
| 4.3.1 Effect of Cu-BTC MOF content | 第85-86页 |
| 4.3.2 Influence of adsorption temperature | 第86-88页 |
| 4.3.3 Effect of model oil/adsorbent mass ratio | 第88-89页 |
| 4.3.4 Reusability of Cu-BTC/γ-Al_2O_3 composite materials | 第89-90页 |
| 4.4 Study of adsorption kinetics of Cu-BTC/γ-Al_2O_3 composites | 第90-94页 |
| 4.5 Summary | 第94-96页 |
| Chapter 5 Cu-BTC/Clay composite materials in adsorption desulfurizationof model oil and related calculation of kinetics | 第96-112页 |
| 5.1 Introduction | 第96页 |
| 5.2 Characterization of Cu-BTC/Clay composite materials | 第96-100页 |
| 5.2.1 Analysis of crystalline phase of Cu-BTC/Clay composites | 第96-97页 |
| 5.2.2 Functional groups analysis in Cu-BTC/Clay composites | 第97-98页 |
| 5.2.3 Observations of core- shell structure in Cu-BTC/AC composites materials | 第98-99页 |
| 5.2.4 Effect of bentonite clay on surface area and pore size of Cu-BTC | 第99-100页 |
| 5.3 Evaluation of performance of Cu-BTC/Clay composite materials | 第100-106页 |
| 5.3.1 Effect of Cu-BTC content | 第101-102页 |
| 5.3.2 Effect of adsorption temperature | 第102-103页 |
| 5.3.3 Effect of model oil/adsorbent mass ratio | 第103-105页 |
| 5.3.4 Reusability of Cu-BTC/Clay composite materials | 第105-106页 |
| 5.4 Study of adsorption kinetics of Cu-BTC/Clay composite | 第106-110页 |
| 5.5 Summary | 第110-112页 |
| Chapter 6 Structure Characterization of Cu-BTC/AC composite materialsin adsorptive desulfurization process and its absorption kinetics | 第112-128页 |
| 6.1 Introduction | 第112-113页 |
| 6.2 Characterization of Cu-BTC/AC composite materials | 第113-117页 |
| 6.2.1 Crystalline structure of Cu-BTC/AC composites | 第113-114页 |
| 6.2.2 Structure and functional group behavior in Cu-BTC/AC composites | 第114-115页 |
| 6.2.3 Observations of internal structure of crystal size in Cu-BTC/AC composites | 第115-116页 |
| 6.2.4 Effect of activated carbon on the surface area and pore structure of Cu-BTC/ACcomposites | 第116-117页 |
| 6.3 Investigation of adsorptive desulfurization performance of Cu-BTC/AC compositesmaterials | 第117-122页 |
| 6.3.1 Effect of Cu-BTC content | 第117-118页 |
| 6.3.2 Effect of adsorption temperature | 第118-120页 |
| 6.3.3 Effect of model oil/adsorbent mass ratio | 第120-121页 |
| 6.3.4 Reusability of Cu-BTC/AC composite materials | 第121-122页 |
| 6.4 Study of adsorption kinetics of Cu-BTC/AC composite materials | 第122-125页 |
| 6.5 Summary | 第125-128页 |
| Chapter 7 Conclusions and outlook | 第128-132页 |
| 7.1 Conclusions | 第128-130页 |
| 7.2 Outlook | 第130-132页 |
| References | 第132-142页 |
| Acknowledgements | 第142-144页 |
| Publications | 第144-146页 |
| Author's resume | 第146-148页 |
| Advisor's resume | 第148-149页 |
| 附件 | 第149-150页 |
