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Preparation, Characterization and Catalytic Application of Pd, Ni, and Cu Nano-materials and Organotin Compounds

TABLE OF CONTENTS第4-8页
ACKNOWLEGEMENTS第8-10页
ABSTRACT第10-12页
LIST OF TABLES第12-13页
LIST OF FIGURES第13-15页
LIST OF ABBREVIATIONS第15-16页
Chapter-1 Introduction第16-43页
    1.1 Nanomaterials第16页
    1.2 Methods of nanomaterials synthesis第16-17页
    1.3 Chemical reduction Method第17-23页
        1.3.1 Synthesis of nanoparticles via polyol method第17-19页
        1.3.2 Synthesis of nanoparticles by borohydride reduction第19-20页
        1.3.3 Synthesis of nanoparticles via hydrazine reduction第20-21页
        1.3.4 Synthesis of nanoparticles by citric acid/L-Ascorbic Acid/sodium citrate reduction第21页
        1.3.5 Synthesis of nanoparticles by electrochemical reduction第21-22页
        1.3.6 Synthesis of nanoparticles via other reduction methods第22-23页
    1.4 Preparation of bimetallic nanoparticles第23-26页
    1.5 Catalysts for dehydrogenation of cyclic ketones第26-28页
    1.6 Catalysts for transesterification of vegetable oil第28-30页
    1.7 Reduction of nitrobenzene第30-31页
    1.8 Objectives第31-32页
    References第32-43页
Chapter-2 Preparation and characterization of metallic and bimetallic nickel, copper and palladium nanoparticles第43-57页
    2.1 Introduction第43-45页
    2.2 Results and Discussions第45-51页
    2.3 Experimental第51-53页
        2.3.1 Materials第51页
        2.3.2 Methods第51-52页
            2.3.2.1 Preparation of nanoparticles第51-52页
        2.3.3 Instrumentation第52-53页
    Summary第53页
    References第53-57页
Chapter-3 Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by various nanocatalysts第57-67页
    3.1 Introduction第57-58页
    3.2 Results and Discussions第58-63页
    3.3 Experimental第63-64页
        3.3.1 Materials and Methods第63页
        3.3.2 Instrumentation第63-64页
    Summary第64-65页
    References第65-67页
Chapter-4 Transesterification of jojoba oil, sunflower oil, neem oil, rocket seed oil and linseed oil第67-79页
    4.1 Introduction第67-68页
    4.2 Results and Discussions第68-74页
        4.2.1 Chemical Characterization of Biodiesel第70-74页
    4.3 Experimental第74-76页
        4.3.1 Materials and Methods第74页
        4.3.2 Methods for the synthesis of catalysts and biodiesel第74-75页
        4.3.3 Instrumentation第75-76页
    Summary第76页
    References第76-79页
Chapter-5 Products and production routes for catalytic conversion of seed oil into fuel and chemicals第79-106页
    5.1 Introduction第79-81页
    5.2 Source of biodiesel第81-82页
    5.3 Production of biodiesel from edible and nonedible vegetable oils第82页
    5.4 Conversion methods第82-83页
    5.5 Factor affecting transesterification reaction第83-87页
        5.5.1 Free fatty acid and moisture第83-84页
        5.5.2 Catalyst type and concentration第84-85页
        5.5.3 Molar ratio and type of alcohol第85页
        5.5.4 Reaction temperature and time第85-87页
        5.5.5 Stirring and co-solvents第87页
    5.6 Homogeneous and heterogeneous catalyst for transesterification第87-89页
        5.6.1 Homogeneous catalysts第87-88页
        5.6.2 Heterogeneous catalysts第88-89页
    5.7 By-product utilization第89-98页
        5.7.1 Hydrocarbons, hydrogen and ethers第89-92页
        5.7.2 Polyglycerols第92页
        5.7.3 Oxygenates第92-93页
        5.7.4 Acrolein第93-94页
        5.7.5 Propylene glycol and ethylene glycol第94-96页
        5.7.6 Monoglycerides, polyglycerol esters第96-97页
        5.7.7 Glycerol carbonate and glycidol第97-98页
    Summary第98-99页
    References第99-106页
Chapter-6 Synthesis, characterization and catalytic application of unsupportednickel-tin bimetallic nanoparticles with tunable composition第106-121页
    6.1 Introduction第106-108页
    6.2 Results and Discussions第108-116页
    6.3 Experimental第116-117页
        6.3.1 Materials第116页
        6.3.2 Methods第116-117页
            6.3.2.1 Preparaiton and catalytic application of nanoparticles第116-117页
        6.3.3 Instrumentation第117页
    Summary第117-118页
    References第118-121页
General conclusion & perspectives第121-124页
    References第122-124页
Publications第124页

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