| 摘要 | 第4-5页 |
| ABSTRACT | 第5-6页 |
| Chapter 1 Introduction | 第13-27页 |
| 1.1 Overview | 第13页 |
| 1.2 Synthesis using soft templates | 第13-15页 |
| 1.2.1 Soft templates using emulsion | 第14-15页 |
| 1.3 Synthesis using a hard template | 第15-24页 |
| 1.3.1 Method of the Layered Assembly | 第16-17页 |
| 1.3.2 Method of the chemical sedimentation | 第17-18页 |
| 1.3.3 Polymer hard template | 第18-24页 |
| 1.4 Preparation of TiO_2 particles | 第24-25页 |
| 1.5 Hollow particles | 第25-27页 |
| Chapter 2 Experimental | 第27-33页 |
| 2.1 Materials for Experiments | 第27-28页 |
| 2.2 Instruments and Equipment | 第28页 |
| 2.3 Research Scheme | 第28-29页 |
| 2.3.1 Preparation polymer particle template | 第28页 |
| 2.3.2 Synthesis of hollow particles | 第28-29页 |
| 2.4 Equipment for Soap-Free emulsion polymerization | 第29页 |
| 2.5 Polymerization Characterizations | 第29-30页 |
| 2.5.1 Transmission Electron Microscopy (TEM) | 第29页 |
| 2.5.2 Dynamic Light Scattering (DLS) | 第29-30页 |
| 2.6 Preparation of P (St-co-AA) particles | 第30页 |
| 2.7 Preparation of P (St-co-NaSS) particles | 第30页 |
| 2.8 Preparation of P (St-co-AA) modified by KH570 particles | 第30-31页 |
| 2.9 Preparation of PAANa particles | 第31-33页 |
| Chapter 3 Soap-free emulsion polymerization | 第33-39页 |
| 3.1 Samples preparation | 第33页 |
| 3.2 Results and Discussion | 第33-35页 |
| 3.2.1 Characterization of the P(St-co-AA)copolymer microspheres by DLS | 第33-34页 |
| 3.2.2 Characterization of the P(St-co-AA)copolymer microspheres by TEM | 第34-35页 |
| 3.3 Preparation of the P(St-co-NaS S)samples | 第35-36页 |
| 3.4 Results and Discussion | 第36-37页 |
| 3.4.1 Characterization of the P(St-co-NaSS) microspheres by DLS | 第36页 |
| 3.4.2 Characterization of the P (St-NaSS)copolymer microspheres by TEM | 第36-37页 |
| 3.5 Preparation of P(St-co-AA)+KH570 samples | 第37页 |
| 3.6 Results and Discussion | 第37-39页 |
| 3.6.1 Characterization of the P (St-co-AA)+KH570 microspheres by DLS | 第37-38页 |
| 3.6.2 Characterization of the P(St-co-AA)+KH570 microspheres by TEM | 第38-39页 |
| 4 Chapter preparations of TiO_2 Spheres | 第39-49页 |
| 4.1 Introduction | 第39页 |
| 4.2 Synthesis of Monodisperce Titanium Spheres by using P (St-co-AA) as a template | 第39-43页 |
| 4.2.1 Synthesis by use coupling agent HPC | 第40-41页 |
| 4.2.2 Synthesis by use coupling agent PVP for get uniform titanium spheres | 第41-42页 |
| 4.2.3 Synthesis by use AAC for get monodisperse titanium spheres | 第42-43页 |
| 4.3 Preparation TiO2 composite particles by using P (St-co-NaSS)as a template | 第43-45页 |
| 4.4 Coating core-shell particles with TBOT by using P(St-co-AA)+KH570 polymermicrospheres as a template | 第45-46页 |
| 4.5 Coating core-shell particles with TBOT by using monodisperse polymerSiO2/composite particles as a template | 第46-47页 |
| 4.5.1 Synthesis of SiO_2 monodisperse particles | 第46-47页 |
| 4.5.2 Fabrication TiO2 by using monodisperse silica particles as a template | 第47页 |
| 4.6 Summary | 第47-49页 |
| 5 Chapter Preparation of SiO_2 Spheres Using Poly (styrene-co-acrylicacid) Templates | 第49-55页 |
| 5.1 Introduction | 第49页 |
| 5.2 Synthesis of Monodisperce Silica Spheres by using P (St-co-AA) as a template | 第49-55页 |
| 5.2.1 Synthesis of Monodisperse Silica Spheres by changing amount of NH_4OH | 第49-51页 |
| 5.2.2 Synthesis of Monodisperse Silica Spheres by changing amount of TEOS | 第51页 |
| 5.2.3 Synthesis of Monodisperse Silica Spheres by changing amount of template solution | 第51-52页 |
| 5.2.4 Increase the wall thickness of hollow silica microspheres by simultaneously changingammonia and TEOS | 第52-55页 |
| 6 Chapter Preparation of hollow SiO2 Spheres by using anionic PAANaas a template | 第55-65页 |
| 6.1 Fabrication process of PAANa@SiO2 Core-shell Particles and Hollow Structures | 第55-56页 |
| 6.2 Preparation of PAANa particles | 第56-57页 |
| 6.3 Fabrication of PAANa@SiO2 Core-shell particles and Hollow structure | 第57-64页 |
| Summary | 第64-65页 |
| Conclusion | 第65-67页 |
| References | 第67-71页 |
| Acknowledgement | 第71-73页 |
| Author's Resume and Academic Advisor's Resume | 第73-77页 |
| 附件 | 第77-78页 |
