| ABSTRACT | 第4页 |
| CHAPTER 1: INTRODUCTION | 第7-65页 |
| 1.1 Introduction to propylene | 第7-13页 |
| 1.1.1 History of propene production | 第8-11页 |
| 1.1.2 Application of propylene | 第11-13页 |
| 1.2 Propylene production methods | 第13-27页 |
| 1.2.1 Steam cracking | 第13-14页 |
| 1.2.2 Fluid catalytic cracking (FCC) | 第14-19页 |
| 1.2.3 Propane dehydrogenation | 第19-27页 |
| 1.3 The catalysts used for PDH | 第27-57页 |
| 1.3.1 Platinum(Pt) | 第27-37页 |
| 1.3.2 Chromium catalysts | 第37-48页 |
| 1.3.3 Other metal oxides investigated for propane dehydrogenation | 第48-57页 |
| 1.4 On-purpose industrial production of propylene process based on PDH | 第57-60页 |
| 1.5 Other industrial processes for the production of propylene | 第60-65页 |
| 1.5.1 Metathesis process for propylene production | 第60-62页 |
| 1.5.2 UOP-Methanol to Olefins (MTO) | 第62-64页 |
| 1.5.3 Catalytic Cracking of Higher Hydrocarbons | 第64页 |
| 1.5.4 Olefin Interconversion | 第64-65页 |
| CHAPTER 2: REVIEW OF VANADIUM BASED CATALYST FOR PDH | 第65-87页 |
| 2.1 Introduction | 第65页 |
| 2.2 Vanadium oxide surface coverage, active sites and catalytic properties | 第65-71页 |
| 2.3 Deactivation of vanadium based catalyst | 第71-76页 |
| 2.4 Effect of the support on the catalytic activity of VOx catalyst | 第76-87页 |
| 2.4.1 Effect of the nature and composition of the support | 第77页 |
| 2.4.2 Effect of the preparation process on the coverage of VO_x species | 第77-82页 |
| 2.4.3 Effect of the support-catalyst interactions on the catalytic stability | 第82-84页 |
| 2.4.4 Effect on the support acidity and surface area on the catalyticperformance of VO_x catalysts | 第84-87页 |
| CHAPTER 3: EXPERIMENTAL METHODS AND APPARATUS | 第87-95页 |
| 3.1 Introduction | 第87-88页 |
| 3.2 Preparation Method of VO_x/ γ- Al_2O_3 Catalysts | 第88-89页 |
| 3.2.1 Incipient wetness impregnation methods | 第88-89页 |
| 3.2.2 Vanadium and magnesium containing catalysts preparation | 第89页 |
| 3.3 Characterization Methods of VO_X/ γ-Al_2O_3 Catalyst: Theory andExperimental Procedure | 第89-92页 |
| 3.3.1 Surface Area Determination by BET Method | 第90-91页 |
| 3.3.2 X-Ray Diffraction (XRD) Analysis | 第91页 |
| 3.3.3 Temperature-Programmed Analysis (TPR/TPD) | 第91-92页 |
| 3.3.4 Laser Raman Spectroscopy | 第92页 |
| 3.4 Experimental procedure | 第92-95页 |
| 3.4.1 Catalyst characterization procedure | 第92-94页 |
| 3.4.2 Catalytic tests | 第94-95页 |
| CHAPTER 4: RESULTS AND DISCUSSION | 第95-109页 |
| 4.1 Introduction | 第95页 |
| 4.2 Catalytic performance | 第95-96页 |
| 4.3 Enhanced anti-coke ability after Mg addition | 第96-98页 |
| 4.4 The origin of improved stability | 第98-103页 |
| 4.5 DRIFTS study on the effects of Mg modification on coke formation | 第103-106页 |
| 4.6 Summary | 第106-109页 |
| CHAPTER 5: CONCLUSIONS | 第109-111页 |
| REFERENCES | 第111-119页 |
| PUBLICATION | 第119-120页 |
| ACKNOWLEDGEMENT | 第120-121页 |
