| 摘要 | 第1-10页 |
| ABSTRACT | 第10-14页 |
| 本论文主要创新之处 | 第14-15页 |
| Chapter 1. Introduction | 第15-43页 |
| Abstract | 第15页 |
| ·Chronopotentiometry | 第15-24页 |
| ·Theoretical principle | 第15-17页 |
| ·Development of chronopotentiometric methods | 第17-22页 |
| Improved techniques based on chronopotentiometry | 第17-21页 |
| Programmed currents applied | 第21-22页 |
| ·Applications of chronopotentiometry | 第22-23页 |
| ·Why controlled-current? | 第23-24页 |
| ·Cyclic reciprocal derivative chronopotentiometry (CRDCP) | 第24-32页 |
| ·Recall the theoretical principle of CRDCP | 第24-26页 |
| ·Research progress of CRDCP | 第26-28页 |
| ·Comparison with cyclic voltammetry (CV) | 第28-29页 |
| ·Distortion of CRDCP curves | 第29-30页 |
| ·Prospect and outlook | 第30-31页 |
| ·Mathematical methods used in theoretical derivation | 第31-32页 |
| ·Computer programs used for numerical computation | 第32页 |
| ·Aim of this dissertation | 第32-33页 |
| ·References | 第33-43页 |
| Chapter 2. Study of reversible electrode processes with successive symmetrical andunsymmetrical programmed CRDCP | 第43-60页 |
| Abstract | 第43页 |
| ·Introduction | 第43-44页 |
| ·Theory and computation | 第44-45页 |
| ·Results and discussion | 第45-55页 |
| ·Reversible electrode process with symmetrical programmed current applied | 第45-49页 |
| ·Application of two successive current steps | 第45页 |
| ·Application of m successive currents | 第45-49页 |
| ·Reversible electrode process with unsymmetrical programmed current applied | 第49-55页 |
| ·Application of two successive current steps | 第49-52页 |
| ·Application of m successive currents | 第52-55页 |
| ·Conclusions and outlook | 第55页 |
| ·Appendix | 第55-58页 |
| ·Application of two successive unsymmetrical programmed currents | 第55-57页 |
| ·Application of m successive unsymmetrical programmed currents | 第57-58页 |
| ·References | 第58-60页 |
| Chapter 3. Kinetic study of totally irreversible electrode processes using CRDCP | 第60-84页 |
| Abstract | 第60页 |
| ·Introduction | 第60-61页 |
| ·Theory and computation | 第61-62页 |
| ·Results and discussion | 第62-76页 |
| ·Totally irreversible electrode processes with m successive symmetrical programmed currents applied of the form I_1(t)=I_0,I_2(t)=-I_0,..., I_m(t)=(-1)~(m+1)I_0 | 第62-65页 |
| ·Totally irreversible electrode processes with unsymmetrical programmed current applied | 第65-72页 |
| ·Application of two successive currents | 第65-69页 |
| ·Application of m successive currents of the form I_1(t)=b_1I_0,I_2(t)=-b_2I_0,..., I_m(t)= (-1)~(m+1)b_mI_0 | 第69-72页 |
| ·Reversibility study of electrode processes | 第72-75页 |
| ·Determination of kinetic parameters | 第75-76页 |
| ·Conclusions and prospect | 第76页 |
| ·Appendix | 第76-80页 |
| ·Application of m successive symmetrical programmed currents of the form I_1(t)=I_0, I_2(t)=-I_0,..., I_m(t)=(-1)~(m+1)I_0 | 第77-79页 |
| ·Application of m successive unsymmetrical programmed currents of the form I_1(t)=b_1I_0,I_2(t)=-b_2I_0,..., I_m(t)=(-1)~(m+1)b_mI_0 (b_1>0) | 第79-80页 |
| ·References | 第80-84页 |
| Chapter 4. Study on irreversible electrode reactions coupled with Henry adsorption usingsymmetrical CRDCP | 第84-110页 |
| Abstract | 第84页 |
| ·Introduction | 第84-86页 |
| ·Theory and computation | 第86-87页 |
| ·Results and discussion | 第87-98页 |
| ·First cycle of symmetrical programmed current of the form I_1(t)=I_0,I_2(t)=-I_0 | 第88-94页 |
| ·Influences of adsorption constants K_(Ox) and K_(Red) on the dt/dE-E curves | 第89-92页 |
| ·Effects of kinetic parameters k_s~0 and a on chronopotentiograms | 第92-94页 |
| ·Application of m successive symmetrical programmed currents of the form I_1(t)=I_0,I_2(t)=-I_0,...,I_m(t)=(-1)~(m+1)I_0 | 第94-96页 |
| ·Comparison of electrochemical behaviors of different mechanisms in CRDCP | 第96-98页 |
| ·Conclusions and prospect | 第98-100页 |
| ·Appendix | 第100-105页 |
| ·References | 第105-110页 |
| Chapter 5. Theoretical study of the electrolysis sequence of adsorptive and diffusing electroactivereactants by CRDCP | 第110-138页 |
| Abstract | 第110页 |
| ·Introduction | 第110-112页 |
| ·Theory and computation | 第112-114页 |
| ·Results and discussion | 第114-130页 |
| ·Expressions and behavior of the dt/dE-E curves corresponding to the application of one cycle of symmetrical programmed current of the form I_1(t)=I_0,I_2(t)=-I_0 | 第114-121页 |
| ·Effects of the parameter Φ (Φ= 2Γ_((Red)~s)/C~*_(Ox)(πD_(Ox)~(1/2),adsorption), adsorption monolayer thickness land γ (γ= 1/K_(Red))on the dt/dE-E curves | 第121-123页 |
| ·General features of the dt/dE-E curves with m successive symmetrical programmed currents applied of the form I_1(t)=I_0,I_2(t)=-I_0,...,I_m(t)= (-1)~(m+1)I_0 | 第123-128页 |
| ·Theoretical models of electrode processes involving adsorption of electroactive species | 第128-130页 |
| ·Conclusions and prospect | 第130-131页 |
| ·Supporting information | 第131-135页 |
| ·References | 第135-138页 |
| Chapter 6. Numerical simulation study of reversible electrode reaction coupled with Langmuiradsorption using CRDCP | 第138-195页 |
| Abstract | 第138页 |
| ·Introduction | 第138-140页 |
| ·Theory and computation | 第140-148页 |
| ·Results and discussion | 第148-153页 |
| ·Distinct features of six typical models of the dt/dE-E curves for reversible electrode reaction coupled with Langmuir adsorption | 第148-150页 |
| ·Peak splitting of the dt/dE-E curves caused by the difference of the adsorption properties of the electroactive species | 第150-152页 |
| ·Effect of diffusion coefficient on the dt/dE-E curves | 第152-153页 |
| ·Conclusion | 第153-154页 |
| ·References | 第154-160页 |
| ·Supporting information | 第160-195页 |
| 攻读博士学位期间发表和待发表的论文 | 第195-196页 |
| 致谢 | 第196-198页 |
