| 摘要 | 第1-4页 |
| Abstract | 第4-10页 |
| Chapter 1 Introduction | 第10-37页 |
| ·Overview | 第10-13页 |
| ·Hetero-Polyoxometalates | 第13-14页 |
| ·Iso-Polyoxometalates | 第14-16页 |
| ·Organic Functionalization of Polyoxometalates | 第16-27页 |
| ·Historical perspective of organo-imido functionalization ofhexamolybdate | 第17-25页 |
| ·Historical perspective of organically modified Lindqvisthexavanadates | 第25-27页 |
| ·Applications of polyoxometalates in electronic devices | 第27-33页 |
| ·Polyoxometalates as cathode active material for Li-ion batteries | 第30-32页 |
| ·Polyoxometalates as anode active materials for Li-ion batteries | 第32-33页 |
| ·Significance and outline of dissertation | 第33-37页 |
| Chapter 2:Remote thiocyanate(-SCN) and sulfonate(-SO_3)groups containingorgano-imido hexamolybdates,synthesis and structural aspects | 第37-64页 |
| ·Introduction | 第37-38页 |
| ·Experimental details for synthesis and characterization of[(Bu_4N)_2[Mo_6O_(18)-N-Ph-(o-CH_3)_2-p-SCN] | 第38-48页 |
| ·Chemical reagents | 第38页 |
| ·Synthesis of Organic ligand 2,6-dimethyl-4-thiocyano aniline(Org-SCN) | 第38-39页 |
| ·Synthesis of organo-imido hexamolybdate[(Bu_4N)2[Mo_6O_(18)-N-Ph-(o-CH_3)_2-p-SCN](MO_6-SCN) | 第39-40页 |
| ·Characterization of organo-imido hexamolybdate Mo_6-SCN | 第40-48页 |
| ·FTIR spectroscopic studies | 第40-41页 |
| ·~1H-NMR measurements | 第41-42页 |
| ·UV-Visible spectroscopic study | 第42-43页 |
| ·ESI-Mass Spectroscopic measurements | 第43-44页 |
| ·Elemental Analysis | 第44页 |
| ·Thermogravimetric analysis | 第44-45页 |
| ·Single crystal X-ray diffraction studies | 第45-48页 |
| ·Experimental details for synthesis and characterization of(Bu_4N)_2[Mo_6O_(18)-N-Ph-o-CH_3-p-SCN] | 第48-56页 |
| ·Chemical reagents | 第48页 |
| ·Synthesis of Organic ligand 2-methyl-4-thiocyano aniline(Org-1Me-SCN) | 第48-49页 |
| ·Synthesis of organo-imido hexamolybdate[(Bu_4N)_2[Mo_6O_(18)-N-Ph-o-CH_3-p-SCN](Mo_6-1Me-SCN) | 第49页 |
| ·Characterization of organo-imido hexamolybdate Mo_6-1Me-SCN | 第49-56页 |
| ·FTIR spectroscopic studies | 第50-51页 |
| ·~1H-NMR measurements | 第51-52页 |
| ·UV-Visible spectroscopic study | 第52-53页 |
| ·ESI-Mass Spectroscopic measurements | 第53页 |
| ·Elemental Analysis | 第53-54页 |
| ·Single crystal X-ray diffraction studies | 第54-56页 |
| ·Experimental details for synthesis and characterization of[(Bu_4N)(K)_2Mo_6O_(18)-N-C_(10)H_6-5-SO_3](Mo_6-naphth-SO_3) | 第56-63页 |
| ·Chemical reagents | 第56页 |
| ·Synthesis of organo-imido hexamolybdate[(Bu_4N)(K)_2Mo_6O_(18)-N-C_(10)H_6-5-SO_3](Mo_6-naphth-SO_3) | 第56-57页 |
| ·Characterization of organo-imido hexamolybdate Mo_6-naphth-SO348 | 第57-63页 |
| ·FTIR spectroscopic studies | 第57-58页 |
| ·UV-Visible spectroscopic observations | 第58-59页 |
| ·ESI-Mass Spectroscopic measurements | 第59-60页 |
| ·Single crystal X-ray diffraction studies | 第60-63页 |
| ·Summary | 第63-64页 |
| Chapter 3:Post-functionalization of organo-imido polyoxometalates via anefficient and stoichiometric approach | 第64-84页 |
| ·Introduction | 第64-65页 |
| ·Experimental section | 第65-69页 |
| ·Materials and Methods | 第65-66页 |
| ·Synthesis of Organic Ligand 1,(2,6-dimethyl-aniline-para-CH_2-Morpholine | 第66-67页 |
| ·Synthesis of Organo-imido Compound 2,Mo_6O_(18)-(2,6-dimethyl-aniline)-para-CH_2-Morpholine | 第67页 |
| ·Synthesis of Post-functionalized Organo-imido Compound 3,Mo_6O_(18)-(2,6-dimethyl-aniline)-para-CH_2-N-benzyl-Morpholine | 第67-68页 |
| ·Synthesis of Post-functionalized Organo-imido Compound 4,Mo_6O_(18)-(2,6-dimethyl-aniline)-para-CH_2-N-allyl-Morpholine | 第68-69页 |
| ·Single Crystal Structural Determinations | 第69页 |
| ·Results and Discussion | 第69-83页 |
| ·Synthesis of the Compounds | 第69-70页 |
| ·Structural Interpretation | 第70页 |
| ·Crystal Structures of Compounds 2-4 | 第70-73页 |
| ·Supramolecular Solid-State Structures of Compounds 2-4 | 第73-77页 |
| ·Spectroscopic Characterization of Compounds 2-4 | 第77-83页 |
| ·Summary and Conclusions | 第83-84页 |
| Chapter 4:Pristine organo-imido hexamolybdates as an anode for lithium ionbatteries | 第84-100页 |
| ·Introduction | 第84-85页 |
| ·Organo-imido functionalized hexamolybdates as anode material | 第85-92页 |
| ·Experimental | 第85-87页 |
| ·Fabrication of anode for Li-ion batteries and electrochemica | 第86页 |
| ·Computational details | 第86-87页 |
| ·Results and Discussion | 第87-92页 |
| ·Effect of organic functionalization and resulting d-π interactions onanode performance | 第87-90页 |
| ·Effect of alteration of remote function groups on anodeperformance | 第90-91页 |
| ·Explanation of higher anode performance for Mo_6-SCN viatheoretical investigation | 第91-92页 |
| ·Post-functionalized organo-imido hexamolvbdates as anode material | 第92-98页 |
| ·Experimental | 第92-93页 |
| ·Results and discussion | 第93-98页 |
| ·Conclusions | 第98-100页 |
| Chapter 5:Pristine organo-hexavanadates as an anode for lithium ion batteries,synthesis to performance | 第100-118页 |
| ·Introduction | 第100-101页 |
| ·Experimental details for synthesis and characterization of[(Bu_4N)_2[V_6(dye-NH_2)_2] | 第101-110页 |
| ·Chemical reagents | 第101-102页 |
| ·Synthesis of Organic ligand 4-((4-amino-3,5-dimethylphenyl)diazenyl)-N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)benzamide [Org (dye)]93 | 第102-103页 |
| ·Synthesis of organo-hexavanadate V6(dye)2 | 第103页 |
| ·Characterization of organo-hexavanadate V_6(dye)_2 | 第103-110页 |
| ·FTIR spectroscopic studies | 第104-105页 |
| ·~1H-NMR measurements | 第105-106页 |
| ·UV-Visible spectroscopic study | 第106-107页 |
| ·ESI-Mass Spectroscopic measurements | 第107-108页 |
| ·Elemental Analysis | 第108页 |
| ·Single crystal X-ray diffraction studies | 第108-110页 |
| ·organo-alkoxo hexamolybdates as anode material | 第110-117页 |
| ·Experimental | 第110页 |
| ·Results and discussion | 第110-117页 |
| ·Summary and conclusions | 第117-118页 |
| Conclusions | 第118-120页 |
| References | 第120-134页 |
| Acknowledgements | 第134-136页 |
| Curriculum Vitae | 第136-137页 |
