| 学位论文数据集 | 第4-5页 |
| 摘要 | 第5-8页 |
| ABSTRACT | 第8-12页 |
| CHAPTER1 INTRODUCTION,BACKGROUND AND LITERATUREREVIEW | 第20-36页 |
| 1.1 Motivation | 第20-22页 |
| 1.2 Types of basic polymerization process | 第22-28页 |
| 1.2.1 Polymerization process | 第23页 |
| 1.2.2 Emulsion and miniemulsion polymerization process | 第23-24页 |
| 1.2.3 Suspension Polymerization | 第24-25页 |
| 1.2.4 Precipitation Polymerization | 第25-26页 |
| 1.2.5 Dispersion Polymerization | 第26-28页 |
| 1.3 Particle nucleation in dispersion polymerization | 第28-29页 |
| 1.4 An overview of alpha-methylene-gama-butyrolactone(MBL) | 第29-31页 |
| 1.5 Styrene | 第31-35页 |
| 1.6 Benzyl peroxide(BPO) | 第35-36页 |
| CHAPTER2 PURPOSE AND SIGNIFICANCE | 第36-40页 |
| 2.1 Research objective | 第36-37页 |
| 2.2 Purpose of the research | 第37-38页 |
| 2.3 Innovative points of research | 第38-40页 |
| CHAPTER 3 EXPERIMENTAL SECTION | 第40-52页 |
| 3.1 Experimental materials and equipments | 第40-41页 |
| 3.1.1 Materials | 第40-41页 |
| 3.2 Equipment | 第41页 |
| 3.3 Preparation of poly(MBL-co-St) copolymer particles | 第41-47页 |
| 3.3.1 Procedure | 第41-42页 |
| 3.3.2 The influence of temperature on the copolymerization | 第42-43页 |
| 3.3.3 The influence of initiator concentration on the copolymerization | 第43页 |
| 3.3.4 The influence of initiator on the copolymerization | 第43-44页 |
| 3.3.5 The influence of monomer feed ratio on the copolymerization | 第44页 |
| 3.3.6 The influence of solvent on the size and morphology | 第44-46页 |
| 3.3.7 Poly(MBL-co-St) particles prepared in isoamyl acetate | 第46-47页 |
| 3.3.8 The influence of reaction time and possible particle formation mechanism | 第47页 |
| 3.4 The preparation of poly(MBL-co-MMA) particles | 第47-48页 |
| 3.5 Preparation of poly(MBL-co-BA) particles | 第48-49页 |
| 3.6 Characterization | 第49-52页 |
| 3.6.1 Size and morphology of the polymer microspheres/particles | 第49页 |
| 3.6.2 Chemical composition of the obtained polymer particles | 第49页 |
| 3.6.3 The monomer conversion and the polymer particle yield | 第49-50页 |
| 3.6.4 Thermal property of the resultant poly(MBL-co-St) particles | 第50页 |
| 3.6.5 The molecular weight of the resultant poly(MBL-co-St) | 第50-52页 |
| CHAPTER 4 RESULT AND DISCUSSION | 第52-104页 |
| 4.1 The radical copolymerization of MBL and St | 第52-54页 |
| 4.2 The effect of initiator concentration on the monomer conversion | 第54-62页 |
| 4.3 The influence of monomer feed ratio on the kinetics | 第62-66页 |
| 4.4 The effect of monomer feed ratio on the composition of the polymer particles | 第66-74页 |
| 4.5 The influence of monomer feed ratio on the morphology of the particles | 第74-80页 |
| 4.5.1 [MBL]:[St]=2:1 | 第75-76页 |
| 4.5.2 [MBL]:[St]=1:1 | 第76-77页 |
| 4.5.3 [MBL]:[St]=1:2 | 第77-78页 |
| 4.5.4 Influence of MBL content on the morphology of the polymer particles | 第78-80页 |
| 4.6 The particle formation process and possible mechanism | 第80-86页 |
| 4.7 Preparations of poly(MBL-co-St) microspheres in different solvent | 第86-96页 |
| 4.7.1 Ethyl-n-butyrate | 第87-88页 |
| 4.7.2 Iso butyl acetate | 第88-89页 |
| 4.7.3 The mixture solvent of isoamyl acetate and toluene | 第89-92页 |
| 4.7.4 Preparations of poly (MBL-co-St) microspheres in mixed solvent | 第92-96页 |
| 4.7.4.1 Methyl ethyl ketone with n-hexane | 第93页 |
| 4.7.4.2 Iso amyle acetate with n-hexan | 第93-94页 |
| 4.7.4.3 Iso amyle acetate with n-hexan | 第94页 |
| 4.7.4.4 Iso butyl acetate with ethyl-n-butyrate | 第94-95页 |
| 4.7.4.5 Iso butyl acetate with ethyl-n-butyrate | 第95-96页 |
| 4.8 Thermal properties of the poly (MBL-co-St) copolymer | 第96-98页 |
| 4.9 Molecular weight of the poly(MBL-co-St) copolymer | 第98-99页 |
| 4.10 Preparation of poly(MBL-co-MMA)copolymer | 第99-102页 |
| 4.11 Preparation of poly(MBL-co-BA)copolymer | 第102-104页 |
| CHAPTER 5 CONCLUSIONS | 第104-108页 |
| 5.1 Conclusion | 第104-106页 |
| 5.2 Future works | 第106-108页 |
| REFERENCES | 第108-116页 |
| PAPERS PUBLICATION | 第116-118页 |
| ACKNOWLEDGEMENTS | 第118-120页 |
| BRIEF INTRODUCTION SUPERVISOR | 第120-122页 |
| AUTHOR'S RESUME | 第122-123页 |
| 附件 | 第123-124页 |
