| Acknowledgements | 第6-8页 |
| 摘要 | 第8-12页 |
| ABSTRACT | 第12-17页 |
| Table of Contents | 第18-22页 |
| Chapter 1. Literature review | 第22-65页 |
| 1.1. Introduction | 第22-24页 |
| 1.2. Synthesis of ferrocene-based polymers | 第24-44页 |
| 1.2.1. Synthesis of main-chain ferrocene-based polymers | 第24-35页 |
| 1.2.2. Synthesis of side-chain ferrocene-based polymers | 第35-44页 |
| 1.3. Properties and applications of ferrocene-based polymers | 第44-62页 |
| 1.3.1. Liquid-crystalline properties and applications | 第45-51页 |
| 1.3.2. The electrochemical properties and applications | 第51-56页 |
| 1.3.3. Applications based on the collective properties | 第56-58页 |
| 1.3.4. Biological applications | 第58-62页 |
| 1.4. Research Objectives | 第62-65页 |
| Chapter 2. Synthesis and properties of main-chain ferrocene-based polymers containingdiethylene glycol or bis(4-hydroxyoctoxy phenyl)sulfone | 第65-90页 |
| 2.1. Introduction | 第65-67页 |
| 2.2. Experimental | 第67-71页 |
| 2.2.1. Materials | 第67页 |
| 2.2.2. Schlenk line system | 第67-68页 |
| 2.2.3. Synthesis of 1,1'-ferrocenedicarbonyl chloride | 第68-69页 |
| 2.2.4. Synthesis of HOS | 第69页 |
| 2.2.5. Synthesis of PDEFD | 第69页 |
| 2.2.6. Synthesis of PHOSFD | 第69-70页 |
| 2.2.7. Characterization | 第70-71页 |
| 2.3. Results and discussion | 第71-88页 |
| 2.3.1. Synthesis and characterization of HOS, PDEFD and PHOSFD | 第71-75页 |
| 2.3.2. Electrochemical properties of PDEFD and PHOSFD | 第75-83页 |
| 2.3.3. Thermal and liquid crystalline properties of PDEFD and PHOSFD | 第83-88页 |
| 2.4. Conclusion | 第88-90页 |
| Chapter 3. Synthesis and properties of novel main-chain ferrocene-based polymers containingN-methyldiethanolamine, phenyldiethanolamine or bisphenol-P | 第90-112页 |
| 3.1. Introduction | 第90-91页 |
| 3.2. Experimental | 第91-93页 |
| 3.2.1. Materials | 第91-92页 |
| 3.2.2. Synthesis of PPFD and PHDFD | 第92-93页 |
| 3.2.3. Synthesis of PMFD | 第93页 |
| 3.2.4. Characterization | 第93页 |
| 3.3. Results and discussion | 第93-110页 |
| 3.3.1. Synthesis and characterization of the main-chain ferrocene-based polyesters | 第93-98页 |
| 3.3.2. Electrochemical properties of the main-chain ferrocene-based polyesters | 第98-107页 |
| 3.3.3. Thermal and liquid-crystalline properties of the main-chain ferrocene-based polyesters | 第107-110页 |
| 3.4. Conclusion | 第110-112页 |
| Chapter 4. Synthesis and properties of main-chain ferrocene-based polyesters with azobenzenein the side-chain | 第112-132页 |
| 4.1. Introduction | 第112-114页 |
| 4.2. Experimental | 第114-116页 |
| 4.2.1. Materials | 第114页 |
| 4.2.2. Synthesis of PPFD-NT, PPFD-CA and PPFD-CN | 第114-115页 |
| 4.2.3. Characterization | 第115-116页 |
| 4.3. Results and Discussion | 第116-130页 |
| 4.3.1. Synthesis and characterization of the azobenzene-containing main-chain ferrocene-based polyesters | 第116-121页 |
| 4.3.2. Photoisomerization of the synthesized MFPAS | 第121-123页 |
| 4.3.3. Azo-protonation of the azobenzene-containing main-chain ferrocene-based polyesters | 第123-125页 |
| 4.3.4. Thermal and liquid crystalline properties of the azobenzene-containing main-chain ferrocene-based polyesters | 第125-130页 |
| 4.4. Conclusion | 第130-132页 |
| Chapter 5. Synthesis, characterization and properties of some main-chain ferrocene-basedpolymers containing aliphatic units | 第132-158页 |
| 5.1. Introduction | 第132-133页 |
| 5.2. Experimental | 第133-135页 |
| 5.2.1. Materials | 第133页 |
| 5.2.2. Synthesis of PSPUFD and PDAFD | 第133-134页 |
| 5.2.3. Synthesis of PDMFD and PHPFD | 第134-135页 |
| 5.2.4. Characterization | 第135页 |
| 5.3. Results and discussion | 第135-155页 |
| 5.3.1. Synthesis and characterization of the main-chain ferrocene-based polymers containing aliphatic units | 第135-141页 |
| 5.3.2. Electrochemical properties of the aliphatic main-chain ferrocene-based polymers | 第141-152页 |
| 5.3.3. Thermal and liquid crystalline properties of the aliphatic main-chain ferrocene-based polymers | 第152-155页 |
| 5.4. Conclusion | 第155-158页 |
| Chapter 6. Synthesis, characterization and properties of some main-chain ferrocene-basedpolymers containing aromatic units | 第158-184页 |
| 6.1. Introduction | 第158-159页 |
| 6.2. Experimental | 第159-161页 |
| 6.2.1. Materials | 第159页 |
| 6.2.2. Synthesis of PCPFD and PCRFD | 第159-160页 |
| 6.2.3. Synthesis of PQDFD and PSOFD | 第160-161页 |
| 6.2.4. Characterization | 第161页 |
| 6.3. Results and discussion | 第161-181页 |
| 6.3.1. Synthesis and characterization of the main-chain ferrocene-based polymers containing aromatic units | 第161-167页 |
| 6.3.2. Electrochemical properties of the aromatic main-chain ferrocene-based polymers | 第167-178页 |
| 6.3.3. Thermal and liquid crystalline properties of the aromatic main-chain ferrocene-based polymers | 第178-181页 |
| 6.4. Conclusion | 第181-184页 |
| Chapter 7. Conclusion | 第184-189页 |
| References | 第189-210页 |
| Curriculum Vitae | 第210-213页 |
