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对碘苯酚在金纳米微粒催化的化学发光体系的增强作用研究及其应用

中文摘要第3-8页
ABSTRACT第8-9页
Chapter1 Literature review第12-36页
    1.1.Chemiluminescence and chemiluminescence analytical methods第12-13页
    1.2.Common chemiluminescence analytical system第13-18页
        1.2.1.Peroxyoxalate chemiluminescence system第13-15页
        1.2.2.Acridinium salts chemiluminescence system第15-16页
        1.2.3.Tris(2,2'-bipyridyl)ruthenium(II)chemiluminescence system第16-17页
        1.2.4.Luminol chemiluminescence system第17-18页
    1.3.Catalysts for luminol-H_2O_2 chemiluminescence system第18-29页
        1.3.1.Metal ions(M~(n+))第18-19页
        1.3.2.Peroxidase第19-21页
        1.3.3.Nanomaterials(as mimetic peroxidase)第21-29页
    1.4.Enhancers for luminol chemiluminescence system第29-34页
        1.4.1.Fluorescein,naphthols,and hexahydroxybenzothiazole第30-31页
        1.4.2.Substituted phenol derivatives第31-32页
        1.4.3.Lophine derivatives and analogues第32页
        1.4.4.Substituted boronic acid derivatives第32-33页
        1.4.5.Water-soluble macromolecules and surfactants第33页
        1.4.6.Co-enhancers第33-34页
    1.5.The origin of my research work第34-36页
Chapter2 Enhancement effect of p-iodophenol on gold nanoparticle-catalyzed chemiluminescence第36-64页
    2.1.Introduction第36-37页
    2.2.Experimental第37-40页
        2.2.1.Apparatus and reagents第37-39页
        2.2.2.Synthesis and characterization of Au NPs第39-40页
        2.2.3.Procedure of CL measurement第40页
    2.3.Results and discussions第40-62页
        2.3.1.Characterization of Au NPs第40-42页
        2.3.2.The enhancement effect of PIP on the luminol-H_2O_2-Au NPs CL system第42-44页
        2.3.3.The enhancement effect of nine enhancers on the luminol-O_2-Au NPs CL system第44-47页
        2.3.4.Kinetic curve of PIP-enhanced luminol-O_2-Au NPs CL system第47-48页
        2.3.5.Optimization of the reaction conditions for the PIP-enhanced luminol-O_2-Au NPs CL system第48-50页
        2.3.6.Catalytic activity of Au NPs with different diameters第50-52页
        2.3.7.Selectivity of the proposed CL system第52-53页
        2.3.8.Possible mechanism of the PIP-enhanced CL system第53-59页
        2.3.9.Analytical applications of the proposed CL system第59-62页
    2.4.Conclusions第62-64页
Chapter3 Application of p-iodophenol-enhanced chemiluminescence reaction to immunoassay第64-80页
    3.1.Introduction第64-65页
    3.2.Experimental第65-69页
        3.2.1.Apparatus and reagents第65-67页
        3.2.2.Synthesis and characterization of Au NPs第67-68页
        3.2.3.Preparation of Au NPs-labeled goat-anti-rabbit IgG secondary antibody..第68页
        3.2.4.Assay procedure for CL detection of rabbit IgG第68-69页
    3.3.Results and discussions第69-79页
        3.3.1.Characterization of Au NPs第69-70页
        3.3.2.Scheme for the detection of rabbit IgG第70-71页
        3.3.3.Optimization of the assay conditions第71-76页
        3.3.4.Assay performance for detection of rabbit IgG第76-77页
        3.3.5.Selectivity of the proposed CL immunoassay system第77-78页
        3.3.6.Analysis of rabbit IgG in the serum sample第78-79页
    3.4.Conclusions第79-80页
Chapter4 Conclusions and outlook第80-82页
References第82-96页
Published papers and scientific research第96-98页
Acknowledgements第98页

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