Abstract in chinese | 第1-5页 |
Abstract | 第5-10页 |
Introduction | 第10-20页 |
1 Gemini surfactants | 第10-16页 |
2 Cationic and anionic surfactant mixtures | 第16-18页 |
3 Cationic and anionic surfactant mixtures containing gemini component(s) | 第18-20页 |
Experimental | 第20-27页 |
1 Materials | 第20-21页 |
2 Methods | 第21-24页 |
3 Appendix | 第24-27页 |
Chapter 1 Adsorption thermodynamics of C(m-1)ρPHCNa and C_mTABr mixture at air/water interface | 第27-36页 |
·Adsorption thermodynamics of the mixture | 第27-30页 |
·Effects of diffusion rate, hydrophobicity and concentration on the mixed adsorption | 第30-35页 |
·Conclusions | 第35-36页 |
Chapter 2 Adsorption kinetics of surfactant mixtures at air/water interface | 第36-43页 |
·Adsorption kinetics of C9ρPHCNa and C_(10)TABr mixture | 第36-40页 |
·Adsorption kinetics of C9ρPHCNa and C_(10)-2-E_2-C_(10)·2Br mixture | 第40-42页 |
·Conclusions | 第42-43页 |
Chapter 3 Mixed monolayers of 2C_(12)-s-2C_(12)·2Br and C11_ρPHCOOH at air/water Interface | 第43-54页 |
·Monolayers of individual surfactants on pure water subphase and on pH2 aqueous subphase | 第43-44页 |
·Mixed monolayers on pH2 aqueous subphase | 第44-49页 |
·Mixed monolayers on pure water subphase | 第49-50页 |
·conclusions | 第50-54页 |
Chapter 4 Mixed micellization of cationic gemini surfactant with anionic conventional surfactat in aqueous solution | 第54-65页 |
·Mixed micellization of C_(12)-3-C_(12)·2Br and SDS in aqueous solution | 第54-62页 |
·Mixed micellization of C_(12)-2-E_n-C_(12)·2Br and SDS in aqueous solution | 第62-64页 |
·Conclusions | 第64-65页 |
Chapter 5 Dissociation kinetics of the mixed C9ρPHCNa and C_(10)TABr micelles in aqueous solution | 第65-68页 |
·Dissociation kinetics of the mixed micelles | 第65-67页 |
·Conclusions | 第67-68页 |
Chapter 6 Aqueous two-phase in the mixtures of C11ρPHCNa and C_(12)TABr and multiple morphologies of aggregates | 第68-79页 |
·Aqueous two-phase formation | 第68-69页 |
·Multiple morphologies of the aggregates in the ASTP | 第69-74页 |
·Phase separation properties of the ASTP | 第74-78页 |
·Conclusions | 第78-79页 |
Chapter 7 pH induced morphology transformation of the mixed C11ρPHCNa/C_(12)TABr aggregates in aqueous solution | 第79-83页 |
·Species distribution of C11ρPHCNa in aqueous solution | 第79-80页 |
·Morphology transformation of the mixed aggregates | 第80-81页 |
·Conclusions | 第81-83页 |
Supplementary information (Ⅰ) | 第83-95页 |
1 Molecular synergism | 第83-86页 |
2 Adsorption kinetics at air/water interface | 第86-91页 |
3 Molecule geometry and packing | 第91-95页 |
Supplementary information (Ⅱ) | 第95-97页 |
The characteristic data of individual gemini surfactants | 第95-97页 |
References | 第97-102页 |
Paper list | 第102-104页 |
Acknowledgements | 第104-105页 |