| ABSTRACT | 第1-8页 |
| 摘要 | 第8-9页 |
| 目录 | 第9-15页 |
| CHAPTER 1-INTRODUCTION | 第15-27页 |
| ·General introduction on trace elements in coal | 第15-16页 |
| ·Importance of coal in energy | 第15页 |
| ·Trace elements in coal | 第15-16页 |
| ·Trace elements partitioning behaviors during coal combustion in coal-fired utility boilers （CFUBs） | 第16-19页 |
| ·Basic configuration in coal-fired power plants (CFPPs) | 第16-18页 |
| ·Classification of trace elements according to their volatile behaviors | 第18页 |
| ·Environmental implication of elemental emissions | 第18-19页 |
| ·The impact of trace elements on human health | 第19-21页 |
| ·Potential health impacts of trace elements | 第19-20页 |
| ·Progresses on the research of risk assessment of trace elements | 第20-21页 |
| ·Significance of platinum group elements as a new class of potential anti-cancer agents | 第21-25页 |
| ·Medicinal inorganic chemistry | 第21-22页 |
| ·Anticancer platinum drugs | 第22-24页 |
| ·Anticancer ruthenium drugs | 第24-25页 |
| ·The study of osmium complexes as potential anticancer agents | 第25页 |
| ·Overall objective | 第25-27页 |
| ·Environmentally sensitive trace elements geochemistry and their human health impact | 第25-26页 |
| ·The anticancer properties of some osmium(Ⅵ) nitrido complexes | 第26-27页 |
| CHAPTER 2-SAMPLES AND EXPERIMENTS | 第27-34页 |
| ·Basic situation of sampling area | 第27-28页 |
| ·Sample collection | 第28-31页 |
| ·Samples from Huainan Coal-fired power plants | 第28-30页 |
| ·Soil samples in the proximity of the Huainan Coal-fired Power Plant | 第30-31页 |
| ·Experimental analysis | 第31-34页 |
| CHAPTER 3-PHYSICAL AND CHEMICAL PROPERTIES OFFEED COAL AND COMBUSTION RESIDUES FROM TWOCOAL-FIRED POWER PLANTS (CFPPS) AT HUAINAN, ANHUI,CHINA | 第34-49页 |
| ·Introduction | 第34页 |
| ·Results and disussion | 第34-48页 |
| ·Characterization of feed coal and combustion residues | 第34-42页 |
| ·Occurrence of trace elements in feed coal and combustion residues | 第42-48页 |
| ·Conclusions | 第48-49页 |
| CHAPTER 4-TRANSFORMATION BEHAVIOR OF TRACEELEMENTS IN FEED COAL AND COMBUSTION RESIDUESFROM TWO COAL-FIRED POWER PLANTS AT HUAINAN,ANHUI,CHINA | 第49-59页 |
| ·Introduction | 第49-50页 |
| ·Results and discussion | 第50-58页 |
| ·The dispersion and enrichment characteristics of trace elements in coal | 第50-51页 |
| ·Transformation behavior of trace elements during combustion process | 第51-54页 |
| ·Partitioning of trace elements in fly ash of different particles | 第54-56页 |
| ·Environmental implication | 第56-58页 |
| ·Conclusions | 第58-59页 |
| CHAPTER 5-ATMOSPHERIC EMISSION OFENVIRONMENTALLY SENSITIVE ELEMENTS (ARSENIC,MERCURY, STIBIUM AND SELENIUM) IN COAL-FIREDPOWER PLANTS AT HUAINAN,ANHUI,CHINA | 第59-65页 |
| ·Introduction | 第59-60页 |
| ·Results and discussion | 第60-64页 |
| ·Overall material balances of As,Hg,Sb and Se | 第60-61页 |
| ·Removal efficiencies of As,Hg,Sb and Se by ESP and WFGD | 第61-63页 |
| ·Annual released amounts of As,Hg,Sb and Se from Huainan coal-fired power plants | 第63-64页 |
| ·Conclusions | 第64-65页 |
| CHAPTER 6-RISK ASSESSMENT OF HEAVY METALS INRESIDENTIAL AREA SOILS IN THE PROXIMITY OF THEHUAINAN COAL-FIRED POWER PLANT | 第65-80页 |
| ·Introduction | 第65页 |
| ·Methods | 第65-70页 |
| ·Assessment of potential ecological risk | 第65-66页 |
| ·Assessment of health risks | 第66-70页 |
| ·Results and discussion | 第70-79页 |
| ·Concentrations of heavy metals in residential area soils around the Huainan power plant | 第70-76页 |
| ·Assessment of potential ecological risk from residential area soils | 第76-78页 |
| ·Health risk from residential area soils | 第78-79页 |
| ·Conclusions | 第79-80页 |
| CHAPTER 7-OSMIUM(Ⅵ) NITRIDO COMPLEXESSUPPORTED BY QUINOLINOLATO LIGANDS AS POTENTANTI-CANCER AGENTS | 第80-96页 |
| ·Introduction | 第80-82页 |
| ·Experimental | 第82-87页 |
| ·Materials | 第82-85页 |
| ·Cell cultare | 第85页 |
| ·Cellular-uptake ICP-MS analysis | 第85-86页 |
| ·Cytotoxicity tests in cancer celll lines | 第86页 |
| ·Flow cytometric studies | 第86-87页 |
| ·Reaction of complex 1 and 3 with Plasmid DNA pBR322 | 第87页 |
| ·Physical measurements and instrumentation | 第87-88页 |
| ·Results and discussion | 第88-95页 |
| ·Syntheses and characterizations of some Osmium(Ⅵ)Nitrido complexes supported by quinolinolato ligands | 第88-89页 |
| ·Antiproliferative activity of nitridoosmium complexes supported by quinolinolato ligands | 第89-91页 |
| ·Cellular uptake studies | 第91-92页 |
| ·Cell cycle analysis and apoptosis | 第92-95页 |
| ·Reaction of complex 1 and 3 with plasmid DNA pBR322 | 第95页 |
| ·Conclusions | 第95-96页 |
| 附中文全文 | 第96-142页 |
| 参考文献 | 第142-162页 |
| 附录 | 第162-165页 |
| 致谢 | 第165-166页 |
| Acknowledgements | 第166-167页 |
| 学位申请者简介 | 第167页 |
