| 摘要 | 第4-6页 |
| Abstract | 第6-7页 |
| 1 Introduction | 第17-60页 |
| 1.1 Water Pollution | 第17-18页 |
| 1.2 Water Pollution with Organic Compounds | 第18-19页 |
| 1.3 Conventional Technologies and Water Pollution | 第19-20页 |
| 1.4 Advanced Oxidation Process (AOPs) | 第20-28页 |
| 1.4.1 Catalytic Wet Hydrogen Peroxide Oxidation (CWPOs) Appeared to be the Best Solution | 第22页 |
| 1.4.2 Application and Limitations of Fenton's Based Technology in Waste Water Treatment | 第22-24页 |
| 1.4.3 Need for Searching an Alternative of Fenton's like Reagent in Waste Water Treatment | 第24-27页 |
| 1.4.4 Application of Heterogeneous Catalyst in the Treatment of Wastewater | 第27-28页 |
| 1.5 Hydrotalcite Based Supported Catalyst | 第28-33页 |
| 1.5.1 Structure of Hydrotalcite | 第28-31页 |
| 1.5.2 Layered Double Hydrotacites as Catalyst | 第31-32页 |
| 1.5.3 Metals Exchanged Zeolites Based Supported Catalyst | 第32-33页 |
| 1.6 Challenges in Catalytic Waste Water Treatments | 第33-35页 |
| 1.7 Bicarbonate Activation of Hydrogen Peroxide system (BAP) | 第35-40页 |
| 1.7.1 Role of Bicarbonate Activation of Hydrogen Peroxide (BAP) in Wastewater (M/HCO_3~-/H_2O_2 system) | 第35-38页 |
| 1.7.2 Future of BAP System in the Development of Green Treatment System | 第38-40页 |
| 1.8 Target Strategy and Content | 第40-41页 |
| 1.9 Research Aim and Conclusion | 第41-42页 |
| References | 第42-60页 |
| 2 Degradation of Chlorophenols by Supported Co-Mg-Al LDH BasedCatalyst in BAP System | 第60-85页 |
| 2.1 Experimental Section | 第61-64页 |
| 2.1.1 Chemicals and Reagents | 第61-62页 |
| 2.1.2 Preparation of Powdered Catalyst for Bench Experiments (CoMgAl-HTs and MgAl-HTs) | 第62页 |
| 2.1.3 Preparation of Supported Catalyst for Fixed Bed Experiments (CoMgAl-SHTs) | 第62-63页 |
| 2.1.4 Pollutants Degradation in Bench Test Experiments | 第63页 |
| 2.1.5 Pollutants Degradation in Fixed Bed Experiments | 第63页 |
| 2.1.6 Analyses | 第63-64页 |
| 2.2 Results and Discussion | 第64-69页 |
| 2.2.1 Characterization of powdered catalysts | 第64-65页 |
| 2.2.2 Activity of Catalyst/HCO_3~-/H_2O_2 System on Bench Level | 第65-69页 |
| 2.3 Mechanistic Discussions | 第69-76页 |
| 2.4 Application of Catalyst in Fixed Bed Reactor | 第76-78页 |
| 2.5 Conclusions | 第78页 |
| References | 第78-85页 |
| 3 Controlled Leaching with Prolonged Activity for Co-LDH SupportedCatalyst during Treatment of Organic Dyes Using BAP System | 第85-113页 |
| 3.1 Experimental section | 第87-89页 |
| 3.1.1 Chemical and Reagents | 第87页 |
| 3.1.2 Preparation of Powdered Catalyst for Bench Expeirments (CoMgAl-HTs andMgAI-HTs) | 第87-88页 |
| 3.1.3 Preparation of Catalyst for Fixed Bed | 第88页 |
| 3.1.4 Degradation of Methylene Orange and Methylene Blue in Bench Experiment | 第88页 |
| 3.1.5 Degradation of Methylene Blue in Fixed Bed Experiments | 第88-89页 |
| 3.1.6 Procedure of Analysis | 第89页 |
| 3.2 Result and Discussion | 第89-93页 |
| 3.2.1 Catalyst Characterizations | 第89-93页 |
| 3.3 Catalytic Performance of CoMgAl Catalysts in the Degradation of Methyl Orange | 第93-96页 |
| 3.4 Effect of Operating Parameters | 第96-102页 |
| 3.4.1 Effect of Hydrogen Peroxide | 第96-97页 |
| 3.4.2 Effect of Sodium Bicarbonate | 第97-98页 |
| 3.4.3 Effect of Catalyst Dose | 第98-99页 |
| 3.4.4 Effect of Solution pH | 第99-100页 |
| 3.4.5 Influence of Anions | 第100-101页 |
| 3.4.6 Role of Bicarbonate in Controlling Catalyst Leaching | 第101-102页 |
| 3.5 Stability and Life of CoMgAl-Na-Y Supported Catalyst in Fixed Bed Glass Reactor | 第102-104页 |
| 3.6 Mechanistic Study for the Presence of Main Reactive Oxygen Species(ROS) | 第104-107页 |
| 3.7 Conclusion | 第107页 |
| References | 第107-113页 |
| 4 Effect of Cu on Promoting the Catalyst Activity of CoMgAl LDH BasedCatalyst Using Chlorophenols as Target Compounds | 第113-150页 |
| 4.1 Experimental Section | 第116-118页 |
| 4.1.1 Chemical and Reagents | 第116页 |
| 4.1.2 Preparation of Powdered Catalyst for Bench Experiments | 第116-117页 |
| 4.1.3 Catalyst Characterization Techniques | 第117页 |
| 4.1.4 Degradation and Analysis of CPs (chlorophenols) During Bench Expeirment | 第117-118页 |
| 4.1.5 Procedure for Monitoring the Stability of the Powdered Catalyst | 第118页 |
| 4.2 Results and Discussion | 第118-124页 |
| 4.2.1 Catalyst Characterization | 第118-124页 |
| 4.3 Catalytic Performance | 第124-137页 |
| 4.3.1 Influence of Different Metals on the Activity of MgAl Based Catalyst | 第124-125页 |
| 4.3.2 Effect of Cu on Promotion CP Degradation with CuCoMgAl Catalyst Derived from CoMgAl Based LDH Catalyst | 第125-127页 |
| 4.3.3 Redox Properties of CuCoMgAl Catalyst | 第127-129页 |
| 4.3.4 Stability of CuCoMgAl Catalyst | 第129-130页 |
| 4.3.5 Activity of CuCoMgAl Catalyst in Bicarbonate Activation of Hydrogen Peroxide System | 第130-131页 |
| 4.3.6 Effect of CP Concentration on the Activity of the Catalyst...115 | 第131-132页 |
| 4.3.7 Effect of H_2O_2 on the Degradation of 4-Chlorophenol | 第132-133页 |
| 4.3.8 Effect of Bicarbonate on the Degradation of 4-CP | 第133-134页 |
| 4.3.9 Effect of Temperature on the Degradation of 4-CP | 第134-135页 |
| 4.3.10 Effect of Solution pH on Degradation of CP | 第135-136页 |
| 4.3.11 Activity of Catalyst for Other Organic Compounds | 第136-137页 |
| 4.4 Mechanistic Study | 第137-142页 |
| 4.4.1 Detection of Free Radicals | 第138-141页 |
| 4.4.2 Possible Reaction Mechanism | 第141-142页 |
| 4.5 Conclusion | 第142页 |
| References | 第142-150页 |
| 5 Project Summary and Future Out Look | 第150-153页 |
| 5.1 Project Summary | 第150-151页 |
| 5.2 Future Out Look | 第151-153页 |
| Acknowledgement | 第153-155页 |
| List of Articles Published During PhD | 第155页 |
