| 摘要 | 第6-7页 |
| ABSTRACT | 第7页 |
| Chapter 1 introduction | 第11-72页 |
| 1.1 Introduction | 第11-12页 |
| 1.2 Introduction to Nano catalysis | 第12-20页 |
| 1.2.1 Properties of metal nanoparticles | 第13-20页 |
| 1.3 Metal Nano catalyst Synthesis | 第20-29页 |
| 1.3.1 Bottom-up and Top-down approach | 第21-22页 |
| 1.3.2 Synthesis of Monometallic Nano catalyst | 第22-24页 |
| 1.3.3 Synthesis of Bimetallic Nano catalyst | 第24-26页 |
| 1.3.4 Synthesis of Bismuth nano tubes by hydrothermal reduction method | 第26页 |
| 1.3.5 Synthesis of Bismuth Nano-films and rhombuses by Bi(SC_(12)H_(25))_3 | 第26-27页 |
| 1.3.6 Selective synthesis of HCP and FCC Nickel Nano crystals | 第27-28页 |
| 1.3.7 Solution combustion synthesis Nano-Ni on SiO_2 | 第28-29页 |
| 1.4 Applications of Nano Catalysts | 第29-37页 |
| 1.4.1 Carbon-Carbon coupling Reaction by Pd Nanoparticles | 第30-32页 |
| 1.4.2 Preparation of azo compounds by Au/HT Nano catalyst | 第32-33页 |
| 1.4.3 Preparation of azo compounds by Au/meso-CeO_2 Nano catalyst | 第33-34页 |
| 1.4.4 Preparation of azo compounds by Ag Nano catalyst | 第34-35页 |
| 1.4.5 Quinoline synthesis by TiO_2 Nano powder | 第35页 |
| 1.4.6 Quinoline synthesis by SiO_2 Nano powder | 第35-36页 |
| 1.4.7 Quinoline synthesis by Nano Au or Ag supported onTiO_2 | 第36-37页 |
| 1.5 Review on Azobenzene Synthesis | 第37-46页 |
| 1.5.1 Azo coupling reaction | 第37-38页 |
| 1.5.2 Mills reaction | 第38页 |
| 1.5.3 Wallach reaction | 第38-39页 |
| 1.5.4 Reduction of Azoxybenzenes | 第39页 |
| 1.5.5 Reductive coupling of aromatic nitro derivatives | 第39-40页 |
| 1.5.6 Oxidation of anilines | 第40页 |
| 1.5.7 Dehydrogenation of Arylhydrazines | 第40-41页 |
| 1.5.8 Dimerization reaction of diazonium salts | 第41页 |
| 1.5.9 Triazene rearrangement | 第41-42页 |
| 1.5.10 Thermolysis of azides | 第42-43页 |
| 1.5.11 Decomposition of N, N'-p-benzoquinonediimine dioxides | 第43页 |
| 1.5.12 Reaction of arylcalcium derivatives with nitrous oxide | 第43-44页 |
| 1.5.13 Metal catalyzed coupling of arylhydrazines | 第44-45页 |
| 1.5.14 Opening of benzotriazoles | 第45页 |
| 1.5.15 Reaction of quinones with arylhydrazines | 第45-46页 |
| 1.5.16 Reaction of quinone acetals with arylhydrazines | 第46页 |
| 1.6 Review on Quinoline synthesis | 第46-61页 |
| 1.6.1 Synthesis of quinoline by In/NH_4Cl | 第48页 |
| 1.6.2 Synthesis of quinoline by Al/HCl | 第48-49页 |
| 1.6.3 Synthesis of quinoline by potassium dodecatungsto-cobaltate | 第49页 |
| 1.6.4 Synthesis of quinoline from Isatins | 第49-50页 |
| 1.6.5 Synthesis of quinoline by InCl_3/SiO_2 | 第50页 |
| 1.6.6 Synthesis of quinoline by Montmorillonite | 第50-51页 |
| 1.6.7 Synthesis of quinoline by Zinc triflate | 第51页 |
| 1.6.8 Synthesis of quinoline by Mont K-10 | 第51-52页 |
| 1.6.9 Synthesis of quinoline by Ionic liquids | 第52页 |
| 1.6.10 Synthesis of quinoline by NCW | 第52-53页 |
| 1.6.11 Synthesis of quinoline by zeolite | 第53页 |
| 1.6.12 Synthesis of quinoline by Pd | 第53-54页 |
| 1.6.13 Synthesis of quinoline by zirconium tetrakisdodecyl sulfate | 第54页 |
| 1.6.14 Synthesis of quinoline by Iodine | 第54-55页 |
| 1.6.15 Synthesis of quinoline by NH_2SO_3H | 第55-56页 |
| 1.6.16 Synthesis of quinoline by Fe/HCl and KOH | 第56页 |
| 1.6.17 Synthesis of quinoline by Ru/HT | 第56-57页 |
| 1.6.18 Synthesis of quinoline by HCl | 第57页 |
| 1.6.19 Synthesis of quinoline by Tin Chloride | 第57-58页 |
| 1.6.20 Synthesis of quinoline by Iron triflate | 第58页 |
| 1.6.21 Synthesis of quinoline by copper triflate | 第58-59页 |
| 1.6.22 Synthesis of quinoline by BIL | 第59页 |
| 1.6.23 Synthesis of quinoline by photo cyclisation | 第59-60页 |
| 1.6.24 Synthesis of quinoline by I_2/Photo irradiation | 第60-61页 |
| 1.6.25 Synthesis of quinoline by TiO_2 | 第61页 |
| 1.7 Research Motivation and Thesis Outline | 第61-62页 |
| References | 第62-72页 |
| Chapter 2 Bismuth nanoparticles:an efficient catalyst for reductive coupling of nitroarenes to azocompounds | 第72-98页 |
| 2.1 Introduction | 第72页 |
| 2.2 Background | 第72-73页 |
| 2.3 Preparation of Bismuth Nano Particles | 第73-74页 |
| 2.4 TEM analysis of Bismuth Nano Particles | 第74页 |
| 2.5 XRD analysis of Bismuth Nano Particles | 第74-75页 |
| 2.6 Application of Bi nano particles for Azobenzene synthesis | 第75-76页 |
| 2.7 Control experiments and Reaction mechanism | 第76-78页 |
| 2.8 Substrate scope | 第78-79页 |
| 2.9 Recycling of Bismuth nano particles | 第79-80页 |
| 2.10 Experimental procedures and characterization data | 第80-94页 |
| 2.11 Summary | 第94页 |
| References | 第94-98页 |
| Chapter 3 Synthesis of quinolines via C-N and a C-C bond formation catalyzed by nickel nanoparticles | 第98-121页 |
| 3.1 Introduction | 第98页 |
| 3.2 Background | 第98-99页 |
| 3.3 Preparation of Nano Nickel crystals | 第99页 |
| 3.4 XRD and TEM analysis of Nickel nano crystals | 第99-101页 |
| 3.5 Preparation of Quinolines | 第101-103页 |
| 3.6 Control experiments and reaction mechanism | 第103-105页 |
| 3.7 Experimental procedures and Characterization data | 第105-117页 |
| 3.8 Summary | 第117页 |
| References | 第117-121页 |
| Chapter 4 Nickel fabricated reactor and its application as a catalyst for reduction reactions in water | 第121-141页 |
| 4.1 Introduction | 第121-122页 |
| 4.2 Background | 第122-124页 |
| 4.3 preparation of Nickel fabricated glass tube | 第124-125页 |
| 4.4 XRD,SEM and XPS analysis of Nickel film | 第125-127页 |
| 4.5 Magnetic strength of Nickel film | 第127-128页 |
| 4.6 EDS analysis of Nickel film | 第128页 |
| 4.7 Applications of Nickel fabricated tube | 第128-131页 |
| 4.8 Recycling of Nickel fabricated tube for Aniline synthesis | 第131-139页 |
| 4.9 Summary | 第139页 |
| References | 第139-141页 |
| Main experimental chemicals | 第141-144页 |
| LIST OF PUBLICATIONS | 第144-145页 |
| ACKNOWLEDGEMENTS | 第145页 |
