| 摘要 | 第4-5页 |
| Abstract | 第5-6页 |
| CHAPTER 1 INTRODUCTION | 第10-25页 |
| 1.1 RESEARCH BACKGROUND AND SIGNIFICANCE ON METAL COMPLEXES | 第10-12页 |
| 1.2 SYNTHESIS AND PREPARATION OF SCHIFF BASES AND THEIR COMPLEXES | 第12-13页 |
| 1.2.1 In situ synthesis | 第12页 |
| 1.2.2 Template synthesis | 第12页 |
| 1.2.3 Drop by drop reaction | 第12页 |
| 1.2.4 Crystal growth | 第12-13页 |
| 1.3 THE BLIOLOGICAL EFFECT OF SCHIFF BASE COPPER(Ⅱ)COMPLEXES | 第13-21页 |
| 1.3.1 Antibacterial activity of Schiff base copper(Ⅱ) complexes | 第14-16页 |
| 1.3.2 The biological activity of Schiff base copper(Ⅱ) complexes on Tetrahymena | 第16-17页 |
| 1.3.3 Study methods and laboratory instruments | 第17-21页 |
| 1.3.3.1 Thermochcmical and isothermal microcalorimetry Profile | 第17-18页 |
| 1.3.3.2 Isothermal calorimetry (thermometric 3114/3236 TAM air isothermal calorimeter) | 第18-20页 |
| 1.3.3.3 ATR attenuated total reflection infrared (ATR-FTIR) spectroscopy | 第20-21页 |
| 1.4 ELECTROCHEMICAL CATALYSIS OF METALS COMPLEX | 第21-22页 |
| 1.5 THE METHOD OF PREPARATION OF CHEMICALLY MODIFIED ELECTRODES | 第22-24页 |
| 1.5.1 Adsorption | 第22-23页 |
| 1.5.2 Electrochemical polymerization | 第23-24页 |
| 1.6 THE PURPOSE AND CONTENT OF CURRENT RESEARCH WORK | 第24-25页 |
| CHAPTER 2 THE BIOLOGICAL PROPERTIES OF THE [CU(SAL-B-ALA)(3,5-DMPZ)_2] ONE.COLI AND TETRAHYMENA | 第25-36页 |
| 2.1 INTRODUCTION | 第25-26页 |
| 2.2 EXPERIMENTAL | 第26-28页 |
| 2.2.1 Reagents | 第26-27页 |
| 2.2.2 Biological materials | 第27页 |
| 2.2.3 Instruments and Methods | 第27-28页 |
| 2.3 RESULTS AND DISCUSSION | 第28-35页 |
| 2.3.1 The biological properties of [Cu(Sal-β-Ala)(3,5-DMPz)_2] on E.coli | 第28-31页 |
| 2.3.1.1 The thermogenic curves | 第28-29页 |
| 2.3.1.2 The growth rate constant (k) | 第29-30页 |
| 2.3.1.3 Relationship between k and concentration of [Cu(Sal-β-Ala)(3,5-DMPz)_2] | 第30-31页 |
| 2.3.1.4 Inhibitory ratio (Ⅰ) and half inhibition concentration (IC_(50)) | 第31页 |
| 2.3.2 The biological properties of [Cu(Sal-β-Ala)(3,5-DMPz)_2] on Tetrahymena | 第31-35页 |
| 2.3.2.1 Thermogenic curves | 第31-33页 |
| 2.3.2.2 The growth rate constant (k) | 第33-34页 |
| 2.3.2.3 Relationship between k and concentration of [Cu(Sal-β-Ala)(3,5-DMPz)_2] | 第34页 |
| 2.3.2.4 Inhibitory ratio I and half inhibition concentration IC_(50) | 第34-35页 |
| 2.4 CONCLUSION | 第35-36页 |
| CHAPTER 3 THE ELECTROCHEMICAL DETECTION OF AA, DA AND UA WITHCU(SAL-B-ALA)(3,5-DMPZ)_2]/SWCNTS/GCE MODIFIED ELECTRODE | 第36-59页 |
| 3.2 EXPERIMENTAL | 第37-39页 |
| 3.2.1 Reagents and apparatus | 第37-38页 |
| 3.2.2 Shorten of the Single-walled carbon nanotubes (SWCNTs) | 第38页 |
| 3.2.3 The preparation of the [Cu(Sal-P-Ala)(3,5-DMPz)_2]/SWCNTs/GCE | 第38页 |
| 3.2.4 The electrochemical tests | 第38-39页 |
| 3.3 RESULTS AND DISCUSSION | 第39-57页 |
| 3.3.1 The modification on the glassy carbon electrode | 第39-41页 |
| 3.3.2 The electrochemical detection of AA | 第41-45页 |
| 3.3.2.1 The electrochemical performance of AA on the modified electrode | 第41-42页 |
| 3.3.2.2 The effect of scan rate on the peak current of AA | 第42页 |
| 3.3.2.3 Influence of detecting conditions | 第42-44页 |
| 3.3.2.4 Amperometric determination of AA | 第44-45页 |
| 3.3.2.5 Interference | 第45页 |
| 3.3.3 The electrochemical dection of DA | 第45-50页 |
| 3.3.3.1 The electrochemical performance of DA at the modified electrode | 第45-46页 |
| 3.3.3.2 The effect of scan rate on the peak current of DA | 第46-47页 |
| 3.3.3.3 The influence of detecting conditions | 第47-48页 |
| 3.3.3.4 Amperometric determination of DA | 第48-49页 |
| 3.3.3.5 Interference | 第49-50页 |
| 3.3.4 The electrochemical detection of UA with [Cu(Sal-β-Ala)(3,5-DMPz)_2]/SWCNTs/GCE41 | 第50-54页 |
| 3.3.4.1 The electrochemical performance of UA at the modified electrodes | 第50-51页 |
| 3.3.4.2 The effect of scan rate | 第51页 |
| 3.3.4.3 The influence detecting conditions | 第51-53页 |
| 3.3.4.4 Amperometric determination of UA | 第53-54页 |
| 3.3.5 The simultaneous electrochemical detection of DA and UA with [Cu(Sal-β-Ala)(3,5-DMPz)_2] /SWCNTs/GCE | 第54-57页 |
| 3.3.5.1 The electrochemical performance of DA and UA on [Cu(Sal-β-Ala)(3,5-DMPz)_2]/SWCNTs/GCE | 第55-56页 |
| 3.3.5.2 Simultaneous determination of DA and UA with [Cu(Sal-β-Ala)(3,5-DMPz)_2]/SWCNTs/GCE | 第56-57页 |
| 3.4 CONCLUSION | 第57-59页 |
| CHAPTER 4 THE SIMULTANEOUS ELECTROCHEMICAL DETECTION OF CATECHOLAND HYDROQUINONE WITH (CU(SAL-B-ALA)(3,5-DMPZ)_2]/SWCNTS/GCE MODIFIEDELECTRODE | 第59-69页 |
| 4.1 INTODUCTION | 第59-60页 |
| 4.2 EXPERIMENTAL | 第60-61页 |
| 4.2.1 Reagents and apparatus | 第60-61页 |
| 4.2.2 Shorten of the Single-walled carbon nanotubes (SWCNTs) | 第61页 |
| 4.2.3 The preparation of the [Cu(Sal-β-Ala)(3,5-DMPz)_2]/SWCNTs/GCE | 第61页 |
| 4.3 Results and discussion | 第61-68页 |
| 4.3.1 Electrochemical behaviors of CT and HQ | 第62-63页 |
| 4.3.2 Effect of scan rate on the electrochemical behavior of CT and HQ | 第63-64页 |
| 4.3.3 The influence of detecting conditions | 第64-65页 |
| 4.3.4 Determination of CT using differential pulse voltammetry | 第65-66页 |
| 4.3.5 Determination of HQ using differential pulse voltammetry | 第66-67页 |
| 4.3.6 Simultaneous determination of CT and HQ using differential pulse voltammetry | 第67-68页 |
| 4.4 CONCLUSION | 第68-69页 |
| CHAPTER 5 CONCLUSION | 第69-70页 |
| ACKNOWLEDGEMENT | 第70-71页 |
| REFERENCES | 第71-83页 |
