| Acknowledgements | 第5-7页 |
| 摘要 | 第7-15页 |
| Abstract | 第15-18页 |
| Chapter 1. Literature review | 第22-61页 |
| 1.1 Introduction | 第22-24页 |
| 1.2 Synthesis of ferrocene-based derivatives and polymers with redox responsive properties | 第24-32页 |
| 1.2.1 Ferrocene-based polypyrroles and polythiophenes | 第25-27页 |
| 1.2.2 Ferrocene-based dendrimers | 第27-31页 |
| 1.2.3 Ferrocene-based polyvinylferrocene | 第31-32页 |
| 1.3 Application of ferrocene-based polymers and derivatives for glucose sensing with redox responsive properties | 第32-35页 |
| 1.3.1 Ferrocene-based polypyrroles | 第32-33页 |
| 1.3.2 Ferrocene-based polythiophenes | 第33-34页 |
| 1.3.3 Ferrocene-based dendrimers | 第34页 |
| 1.3.4 Ferrocene-based polyvinylferrocene | 第34-35页 |
| 1.4 Performance of glucose biosensors containing ferrocene-based polymers and derivatives with redox responsive properties | 第35-38页 |
| 1.4.1 Metal coordination | 第36页 |
| 1.4.2 Spacer of the ferrocene to polymer | 第36-37页 |
| 1.4.3 Interferences | 第37页 |
| 1.4.4 Crosslinking | 第37页 |
| 1.4.5 Polymer backbone flexibility | 第37-38页 |
| 1.5 Additional systems for saccharide sensing | 第38-46页 |
| 1.5.1 Lectin-based system | 第38页 |
| 1.5.2 Phenylboronic acid-based system | 第38-46页 |
| 1.6 Research objectives | 第46-47页 |
| References | 第47-61页 |
| Chapter 2. Synthesis of ferrocene-based boronic acid derivatives and their saccharides sensing properties | 第61-90页 |
| 2.1 Introduction | 第61-63页 |
| 2.2 Experimental | 第63-66页 |
| 2.2.1 Materials | 第63页 |
| 2.2.2 Schlenk line system | 第63-64页 |
| 2.2.3 Synthesis of BMAPBA, BDAPBA, FcMAPBA and FcDAPBA | 第64-66页 |
| 2.3 Results and discussion | 第66-83页 |
| 2.3.1 Synthesis and characterization of BMAPBA, BDAPBA, FcMAPBA and FcDAPBA | 第66-71页 |
| 2.3.2 Electrochemical properties of FcMAPBA and FcDAPBA | 第71-73页 |
| 2.3.3 Saccharide sensing of FcMAPBA | 第73-80页 |
| 2.3.4 Thermal properties of FcMAPBA and FcDAPBA | 第80-83页 |
| 2.4 Conclusion | 第83页 |
| References | 第83-90页 |
| Chapter 3. Synthesis of PMAEFc-b-PVAPBA, PMAEFc-b-PMVAPBA and PMAEFc-b-PSBA by using MCPDB as RAFT agent and their micellization, redox responsive and glucose sensing properties | 第90-129页 |
| 3.1 Introduction | 第90-93页 |
| 3.2 Experimental | 第93-98页 |
| 3.2.1 Materials | 第93页 |
| 3.2.2 Synthesis of PMAEFc-b-PVAPBA, PMAEFc-b-PMVAPBA and PMAEFc-b-PSBA | 第93-98页 |
| 3.3 Results and discussion | 第98-120页 |
| 3.3.1 Synthesis of diblock copolymers (PMAEFc-b-PVAPBA, PMAEFc-b-PMVAPBA and PMAEFc-b-PSBA) | 第98-106页 |
| 3.3.2 Micellization of PMAEFc-b-PMVAPBA | 第106-111页 |
| 3.3.3 Glucose binding of PMAEFc-b-PMVAPBA micelles | 第111-112页 |
| 3.3.4 Redox reactions of PMAEFc-b-PMAVPBA micelles | 第112-114页 |
| 3.3.5 Saccharide sensing of PMAEFc-b-PVAPBA | 第114-118页 |
| 3.3.6 Thermal properties of PMAEFc-b-PVAPBA,PMAEFc-b-PMVAPBA and PMAEFc-b-PSBA | 第118-120页 |
| 3.4 Conclusion | 第120-121页 |
| References | 第121-129页 |
| Chapter 4. Synthesis of PMAEFc-b-PMVAPBA by using DDMAT as RAFT agent and their micellization, redox responsive and glucose sensing properties | 第129-157页 |
| 4.1 Introduction | 第129-131页 |
| 4.2 Experimental | 第131-134页 |
| 4.2.1 Materials | 第131-132页 |
| 4.2.2 Synthesis and micellization of PMAEFc-b-PMVAPBA | 第132-134页 |
| 4.3 Results and discussion | 第134-148页 |
| 4.3.1 Synthesis of MAEFc and MVAPBA and their RAFT polymerization | 第134-138页 |
| 4.3.2 Micellization of PMAEFc-b-PMAVPBA | 第138-140页 |
| 4.3.3 Glucose binding of PMAEFc-b-PMVAPBA micelles | 第140-141页 |
| 4.3.4 Effect of redox responsive ferrocene on glucose binding and morphology of PMAEFc-b-PMVAPBA micelles | 第141-143页 |
| 4.3.5 Thermal properties of PMAEFc and PMAEFc-b-PMVAPBA | 第143-145页 |
| 4.3.6 Electrochemical properties of PMAEFc and PMAEFc-b-PMVAPBA | 第145-146页 |
| 4.3.7 UV-vis of PMAEFc-b-PMVAPBA | 第146-147页 |
| 4.3.8 X-ray diffraction studies of PMAEFc and PMAEFc-b-PMVAPBA | 第147-148页 |
| 4.4 Conclusion | 第148-149页 |
| References | 第149-157页 |
| Chapter 5. Conclusion | 第157-160页 |
| List of abbreviations | 第160-163页 |
| Curriculum vitae | 第163-166页 |
