| CHAPTER 1 GENERAL INTRODUCTION | 第14-20页 |
| CHAPTER 2 SYNTHESIS OF NOVEL DITHIA CROWN ETHER ANNULATED TETRATHIAFULVALENE DERIVATIVES | 第20-45页 |
| 2.1 INTRODUCTION | 第20-22页 |
| 2.2 RESULTS AND DISCUSSION | 第22-30页 |
| 2.2.1 Synthesis of Target Compounds (porphyrazine) | 第22-26页 |
| 2.2.2 Electrochemical Properties of TTF-Crown-Ethers | 第26-28页 |
| 2.2.2 Ion Sensor Property of TTF-Crown-Ethers | 第28-30页 |
| 2.3 EXPERIMENTAL | 第30-43页 |
| 2.4 CONCLUSION | 第43-44页 |
| 2.5 REFERENCES | 第44-45页 |
| CHAPTER 3 SYNTHESIS AND PROPERTY OF NANOSCALE OCTATHIA 36-CROWN-12 ANNULATED TETRATHIAFULVALENE TETRAMERS | 第45-65页 |
| 3.1 INTRODUCTION | 第45-47页 |
| 3.2 RESULTS AND DISCUSSION | 第47-55页 |
| 3.2.1 Synthesis of Target Compounds | 第47-49页 |
| 3.2.2 Electrochemical Properties of 7c and 8c | 第49-51页 |
| 3.2.3 Computer-generated Inclusion Complex of 8a and [60]fulerene | 第51-52页 |
| 3.2.4 Study on Charge-transfer Complex of 8c and [60]fullerene by 1H- NMR Spectroscopy | 第52-55页 |
| 3.3 EXPERIMENTAL | 第55-63页 |
| 3.4 CONCLUSION | 第63-64页 |
| 3.5 REFERENCES | 第64-65页 |
| CHAPTER 4 SYNTHESIS AND PROPERTY OF TETRATfflAFULVALENES ANNULATED PORPHYRAZINE | 第65-90页 |
| 4.1 INTRODUCTION | 第65-68页 |
| 4.2 RESULTS AND DISCUSSION | 第68-83页 |
| 4.2.1 Synthesis of Target Compounds (porphyrazinee) | 第68-73页 |
| 4.2.2 Electrochemical Behavior of 2,3-Dicyano-TTF Derivatives (13a-f) | 第73-75页 |
| 4.2.3 1H-NMR、 EPR and MALDI-TOF-MS Spectra of TTF-Porphyrazine Derivatives | 第75-76页 |
| 4.2.4 UV-VIS Spectra of TTF-Porphyrazine Derivatives | 第76-78页 |
| 4.2.5 Fluorescence Spectra of TTF-Porphyrazine Derivatives | 第78-79页 |
| 4.2.6 Electrochemical Behavior of Mg- Porphyrazine (15) and metal-free Porphyrazine (16 | 第79-82页 |
| 4.2.7 Solubility of the Target Compounds(15-17) | 第82-83页 |
| 4.3 EXPERIMENTAL | 第83-88页 |
| 4.4 CONCLUSION | 第88-89页 |
| 4.5 REFERENCES | 第89-90页 |
| CHAPTER 5 SYNTHESIS AND PROPERTY OF TETRATHIAFULVALENO PORPHYRAZINE SUSTITUTED WITH CROWN ETHER MOIESE | 第90-113页 |
| 5.1 INTRODUCTION | 第90-92页 |
| 5.2 RESULTS AND DISCUSSION | 第92-107页 |
| 5.2.1 Synthesis of target compounds (8a-b) | 第92-95页 |
| 5.2.2 1H NMR Spectra of Dithia Crown Ether Annulated Dicyano TTFs(7a-c) | 第95-98页 |
| 5.2.3 Electrochemical Properties of Dicyano TTF Annulated Dithia Crown Ethers(7a-c) | 第98-100页 |
| 5.2.4 1H-NMR Spectra and MALDI-TOF-MS Spectra of TTF Crown ether porphyrazine Derivatives | 第100-102页 |
| 5.2.5 Electrochemical Behavior of Target Compounds(8a-b) | 第102-104页 |
| 5.2.6 UV-VIS and Fluorescence spectroscopy | 第104-106页 |
| 5.2.7 Solubility of the target compounds | 第106-107页 |
| 5.3 EXPERIMENTAL | 第107-112页 |
| 5.4 CONCLUSION | 第112-113页 |
| 5.5 REFERENCE | 第113页 |
