| ACKNOWLEDGEMENTS | 第6-7页 |
| ABSTRACT | 第7-8页 |
| 摘要 | 第9-11页 |
| CHAPTER Ⅰ INTRODUCTION | 第11-22页 |
| 1.1 METAL-ORGANIC COORDINATION NETWORK: AN INTERPLAY BETWEEN METAL IONS (NODES) AND ORGANIC LIGANDS (SPACERS) | 第12-17页 |
| 1.2 ORGANIC NETWORK:SUPRAMOLECULAR ASSEMBLIES VIA SECONDARY INTERACTIONS | 第17-19页 |
| 1.3 DESIGN AND APPLICATION | 第19-20页 |
| REFERENCES | 第20-22页 |
| CHAPTER Ⅱ A SYSTEMATIC STUDY OF SUBSTITUENT EFFECT OF R-ISOPHTHALIC ACIDS (R=-H, -NH_2, -NO_2, -SO_3H) ON REGULATING THE SUPRAMOLECULAR ASSEMBLY WITH N-DONOR LIGAND | 第22-36页 |
| 2.1 EXPERIMENTAL SECTION | 第23-26页 |
| 2.2 RESULTS AND DISCUSSION | 第26-32页 |
| 2.2.1 Structural Description of Compounds 1-4 | 第26-32页 |
| 2.2.2 Disscussion | 第32页 |
| 2.3 CONCLUSION | 第32-35页 |
| REFERENCES | 第35-36页 |
| CHAPTER Ⅲ A NEW FAMILY OF SILVER(I) COORDINATION POLYMERS FROM COLIGANDS: EFFECT OF THE R-SUBSTITUENTS (R =-H, -OH,-NH_2, -NO_2) ON CRYSTAL STRUCTURES | 第36-51页 |
| 3.1 EXPERIMENTAL SECTION | 第37-38页 |
| 3.2 RESULTS AND DISCUSSION | 第38-49页 |
| 3.3 CONCLUSION | 第49页 |
| REFERENCES | 第49-51页 |
| CHAPTER Ⅳ VARIOUS ISOMERS OF 4-AMINO-3,5-BIS(X-PYRIDYL)-1,2,4-TRIAZOLE (X =2, 3, 4) AS MODULAR BUILDING BLOCKS FOR MIXED-LIGAND COORDINATION COMPLEXES INCORPORATED WITH A VERSATILE CONNECTOR 5-SULFOISOPHTHALIC ACID | 第51-80页 |
| 4.1 EXPERIMENTAL SECTION | 第52-56页 |
| 4.2 RESULTS AND DISCUSSION | 第56-78页 |
| 4.2.1 Two groups of Cu~Ⅱ and Cd~Ⅱ Mixed-ligand Coordination Complexes | 第56-70页 |
| 4.2.1.1 Structural Analysis of Complexes 9-14 | 第56-69页 |
| 4.2.1.2 Discussion | 第69-70页 |
| 4.2.2 Other Metal Ions Mixed-Ligand Coordination Complexes | 第70-78页 |
| 4.2.2.1 Structural Analysis of Complexes 15-20 | 第70-76页 |
| 4.2.2.2 Discussion | 第76-78页 |
| 4.3 CONCLUSION | 第78页 |
| REFERENCES | 第78-80页 |
| CHAPTER Ⅴ SYNTHESIS AND CRYSTAL STRUCTURES OF NEW METAL-ORGANIC COORDINATION COMPLEXES | 第80-92页 |
| 5.1 EXPERIMENTAL SECTION | 第81-82页 |
| 5.2 RESULTS AND DISCUSSION | 第82-89页 |
| 5.3 CONCLUSION | 第89-90页 |
| REFERENCES | 第90-92页 |
| APPENDIX | 第92页 |
