| 摘要 | 第1-7页 |
| Abstract | 第7-10页 |
| Part Ⅰ Introduction | 第10-24页 |
| 1. Introduction of chemically modified electrodes | 第10-14页 |
| ·Introduction | 第10页 |
| ·Modificatory methods of the CMEs | 第10-12页 |
| ·Characterization methods of the CMEs | 第12页 |
| ·Applications of CMEs in electroanalysis | 第12-14页 |
| 2. Introduction of hydrogen peroxide | 第14-15页 |
| 3. References | 第15-24页 |
| Part Ⅱ Main research works #15 Chapter 1.Hydrogen peroxide sensor based on Prussian blue electrodeposited on (3-mercaptopropyl)-trimethoxysilane polymer modified gold electrode | 第24-37页 |
| 1. Introduction | 第24-25页 |
| 2. Experimental | 第25-26页 |
| ·Reagents | 第25页 |
| ·Apparatus | 第25-26页 |
| ·Electrode preparation | 第26页 |
| ·Electrochemical measurement | 第26页 |
| 3. Results and discussion | 第26-33页 |
| ·Cyclic voltammetry characterization of self-assembly process | 第26-27页 |
| ·Electrochemical impedance spectroscopy characterization of self-assembly process | 第27-28页 |
| ·Characterization of PB film | 第28-30页 |
| ·Electrochemical characteristics of the modified electrodes | 第30-31页 |
| ·Performance of the PB modified electrode for H_2O_2 detection | 第31-32页 |
| ·Tolerance of potentially interfering substances | 第32-33页 |
| 4. Conclusions | 第33页 |
| 5. References | 第33-37页 |
| Chapter 2.Hydrogen peroxide sensor based on Prussian blue analogue doped with Cd(Ⅱ) electrodeposited on the self-assembled(3-mercaptopropyl)-trimethoxysilane gold electrode | 第37-50页 |
| 1. Introduction | 第37-38页 |
| 2. Experimental | 第38-39页 |
| ·Reagents | 第38页 |
| ·Apparatus | 第38页 |
| ·Fabrication of the Modified Electrode | 第38-39页 |
| 3. Results and Discussion | 第39-46页 |
| ·Electrochemical characteristics of self-assembly process | 第39-41页 |
| ·Characterization of cadmium hexacyanoferrate(CdHCF)film | 第41-42页 |
| ·Electrochemical characteristics of the Au/MPS/CdHCF modified electrode | 第42-43页 |
| ·Performance of the modified electrode for H_2O_2 detection | 第43-45页 |
| ·Tolerance of foreign substances | 第45-46页 |
| 4. Conclusions | 第46页 |
| 5. References | 第46-50页 |
| Chapter 3. Preparation of macroporous silver film electrode for hydrogen peroxide sensor application | 第50-61页 |
| 1. Introduction | 第50-51页 |
| 2. Experimental | 第51-52页 |
| ·Reagents | 第51页 |
| ·Apparatus | 第51页 |
| ·Synthesis of PS latex spheres | 第51页 |
| ·Fabrication of the macroporous silver film electrode | 第51-52页 |
| 3. Results and Discussion | 第52-57页 |
| ·Elaboration of macroporous silver film | 第52-53页 |
| ·Electrocatalytic behavior of the macroporous silver film-modified electrode towards H_2O_2 | 第53-54页 |
| ·Optimization of experimental variables | 第54-56页 |
| ·Amperometric performance of the macroporous silver membrane sensor to H_2O_2 | 第56-57页 |
| 4. Conclusions | 第57页 |
| 5. References | 第57-61页 |
| Chapter 4. Preparation of ordered macroporous Prussian blue film electrode for hydrogen peroxide sensor application | 第61-72页 |
| 1. Introduction | 第61-62页 |
| 2. Experimental | 第62-64页 |
| ·Reagents | 第62页 |
| ·Apparatus | 第62页 |
| ·Synthesis of PS latex spheres | 第62-63页 |
| ·Fabrication of the ordered macroporous Prussian blue film electrode | 第63-64页 |
| 3. Results and Discussion | 第64-68页 |
| ·Fabrication and characterization of ordered macroporous PB film | 第64-65页 |
| ·Electrocatalytic behavior of the macroporous PB film-modified electrode towards H_2O_2 | 第65-67页 |
| ·Amperometric performance of the macroporous PB membrane sensor to H_2O_2 | 第67-68页 |
| 4. Conclusions | 第68页 |
| 5. References | 第68-72页 |
| Conclusions | 第72-74页 |
| 致谢 | 第74-75页 |
| Appendix | 第75页 |
