| ACKNOWLEDGMENTS | 第1-6页 |
| DOCTORAL STUDENT'S INNOVATIVE THOUGHT | 第6-8页 |
| TABLE OF CONTENTS | 第8-11页 |
| ABSTRACT | 第11-19页 |
| 摘要 | 第19-24页 |
| Chapter one Introduction | 第24-76页 |
| 1. Conjugated polymers | 第24-49页 |
| ·Applications of conjugated polymers | 第26-31页 |
| ·Anticorrosion coatings | 第26-27页 |
| ·Sensors | 第27页 |
| ·Field effect transistors | 第27-28页 |
| ·Light emitting diodes | 第28-29页 |
| ·Polymer heterojunction solar cell | 第29-31页 |
| ·Synthesis of conjugated polymer | 第31-49页 |
| ·Chemical(using oxidizing agents)oxidative polymerization | 第32-33页 |
| ·Electrochemical oxidative polymerization | 第33-37页 |
| ·Polycondensation method | 第37-44页 |
| ·Solid-state polymerization of conjugated polymer | 第44-48页 |
| ·Other polymerization methods | 第48-49页 |
| 2. Conducting polymers | 第49-62页 |
| ·A brief history of conducting polymers | 第49-50页 |
| ·Theory of conducting polymers | 第50-51页 |
| ·P-type doping and n-type doping conducting polymer | 第51-53页 |
| ·General properties of conducting polymers | 第53-57页 |
| ·Conducting polymers in industrial applications | 第57-59页 |
| ·Conducting polymers in biological applications | 第59-60页 |
| ·Synthesis of conducting polymers | 第60-62页 |
| REFERENCES | 第62-76页 |
| CHAPTER TWO Design and invesitgation of parallel, stradegy thiophene derivatives containing heteroatom linkers for solid state polymerization | 第76-98页 |
| ·Introduction | 第76页 |
| ·Experimental details | 第76-80页 |
| ·Materials | 第77页 |
| ·Monomers synthesis and solid state polymerization | 第77-79页 |
| ·General solid state polymerization | 第79页 |
| ·Other characterizations | 第79-80页 |
| ·Results and discussion | 第80-95页 |
| ·Synthesis of monomers and their behavior under SSP | 第80-82页 |
| ·XRD patterns of monomers and respective polymers | 第82-84页 |
| ·Absorption of polymers and hydrazine treated polymer | 第84-85页 |
| ·FTIR spectroscopy | 第85页 |
| ·Photo-picture and SEM of monomers and polymers | 第85-87页 |
| ·Crystallographic X-ray Analysis | 第87-92页 |
| ·Cyclic voltammetry behavior of polymers | 第92-93页 |
| ·SSP yield dependence of reaction time at 60 degree | 第93-94页 |
| ·Conductivity | 第94-95页 |
| ·Conclusion | 第95-96页 |
| REFEERENCE | 第96-98页 |
| Chapter three Effect of flexible linker length in 3,4-ethylenedioxythiophene derivatives forsolid state polymerization | 第98-116页 |
| ·Introduction | 第98-99页 |
| ·Experimental section | 第99-102页 |
| ·Materials | 第99页 |
| ·Monomer synthesis and solid state polymerization | 第99-101页 |
| ·General solid state polymerization | 第101页 |
| ·Crystal structure determination | 第101页 |
| ·Other characterizations | 第101-102页 |
| ·Results and discussion | 第102-113页 |
| ·Synthesis of monomers and solid state polymerization | 第102-104页 |
| ·XRD patterns of monomers and respective polymers | 第104页 |
| ·Absorption of polymers by SSP and hydrazine treated polymers | 第104-105页 |
| ·FTIR Spectroscopy | 第105-106页 |
| ·Photo-picture of monomer and polymer | 第106页 |
| ·Cyclic voltammetry behavior of the polymers | 第106-107页 |
| ·Crystallographic X-ray Analysis | 第107-112页 |
| ·Molecule weight | 第112-113页 |
| ·Conclusions | 第113-114页 |
| REFERENCE | 第114-116页 |
| Chapter four Effect of monomer's structure on self acid assisted-polycondensation for thesynthesis of poly(3,4-ethylenedioxythiophene) and homopolythiophene | 第116-134页 |
| ·Introduction | 第116-117页 |
| ·Experimental | 第117-121页 |
| ·Materials | 第117页 |
| ·Monomers synthesis and sefl acid assisted-polycondensation | 第117-120页 |
| ·Self acid assisted-polycondensation | 第120页 |
| ·Other Characterizations | 第120-121页 |
| ·Results and discussion | 第121-130页 |
| ·Synthesis of monomer and their behavior under SAAP | 第121-123页 |
| ·XRD patterns of the monomers and respective polymers | 第123-124页 |
| ·Absorption of all polymers and fluorescence of P(S-S-OHexy) | 第124-125页 |
| ·FTIR spectroscopy and thermal stability | 第125-127页 |
| ·Photo picture under SAAP | 第127-128页 |
| ·Electrochemical behavior of corresponding polymers | 第128-129页 |
| ·Molecule weight of P(S-S-OHexy) vs temperature dependence | 第129-130页 |
| ·Conclusions | 第130页 |
| REFERENCES | 第130-134页 |
| List of publications | 第134页 |
