| 摘要 | 第1页 |
| 详细摘要 | 第5-19页 |
| Abstract | 第19-25页 |
| Chapter 1 Introduction | 第25-55页 |
| ·Polymer networks | 第25-26页 |
| ·Cyclodextrins | 第26-30页 |
| ·Cyclodextrin structure | 第26-28页 |
| ·Cyclodextrin host-guest interaction | 第28-29页 |
| ·Linear free energy relationship | 第29-30页 |
| ·Cyclodextrin polymers | 第30-34页 |
| ·Non-linear cyclodextrin polymer | 第30-31页 |
| ·Linear cyclodextrin polymer | 第31-34页 |
| ·Polymer networks formed by cyclodextrin complexation | 第34-41页 |
| ·Polymer networks formed by substituents association | 第34-36页 |
| ·Polymer networks formed by crystallization of polyrotaxanes | 第36-39页 |
| ·Other polymer networks assembled by cyclodextrin complexation | 第39-41页 |
| ·Aims of this research | 第41-42页 |
| References | 第42-55页 |
| Chapter 2 Synthesis of β-cyclodextrin substituted poly (acrylic acid)s | 第55-64页 |
| ·Introduction | 第55-56页 |
| ·Materials | 第56页 |
| ·Characterization | 第56页 |
| ·Synthesis | 第56-62页 |
| ·Synthesis of monotosylated β-CD | 第56-57页 |
| ·Synthesis of monoamino derivatives of β-CD | 第57-60页 |
| ·Synthesis of P-CD substituted PAAs | 第60-62页 |
| ·Chapter conclusions | 第62页 |
| References | 第62-64页 |
| Chapter 3 Polymer networks assembled by alternative hydrophobic and inclusiveassociations of side groups in poly (acrylic acid)s | 第64-78页 |
| ·Introduction | 第64-65页 |
| ·Experimental | 第65-67页 |
| ·Materials | 第65-66页 |
| ·Synthesis of HMPAA | 第66-67页 |
| ·Characterization | 第67页 |
| ·Results and discussion | 第67-75页 |
| ·Effect of molar ratio of alkyl group/β-CD | 第67-68页 |
| ·Effect of alkyl length grafted to PAA | 第68页 |
| ·Effect of polymer concentration | 第68-69页 |
| ·Effect of salt concentration and pH value | 第69-70页 |
| ·Effect of addition of native β-CD molecules | 第70-71页 |
| ·Effect of temperature | 第71-75页 |
| ·Chapter conclusions | 第75页 |
| References | 第75-78页 |
| Chapter 4 Polymer networks assembled by adamantyl and β-cyclodextrin substitutedpoly (acrylic acid)s | 第78-112页 |
| ·Introduction | 第78-80页 |
| ·Experimental | 第80-84页 |
| ·Materials | 第80页 |
| ·Synthesis of AD substituted PAAs | 第80-83页 |
| ·Characterization | 第83-84页 |
| ·Results and discussion | 第84-107页 |
| ·Stoichiometry of β-CD/AD complexation | 第84-85页 |
| ·Competition between native β-CD and β-CD substituents | 第85页 |
| ·Temperature effect on host-guest inclusion | 第85-88页 |
| ·Host-guest inclusion identification by 2D ~1H NOESY NMR spectroscopy | 第88-90页 |
| ·Complexation constant characterized by isothermal titration calorimetry | 第90-92页 |
| ·Effect of sodium chloride on viscosity | 第92-93页 |
| ·Effect of the extent of substitution of PAA on rheological properties | 第93-95页 |
| ·Competitive intra-and intermolecular host-guest complexation | 第95-103页 |
| ·Steric hindrance and relative size effects on host-guest complexation | 第103页 |
| ·Rheological studies of the polymer networks with different tether length | 第103-107页 |
| ·Chapter conclusions | 第107-108页 |
| References | 第108-112页 |
| Chapter 5 Polymer networks assembled by inclusion complexation betweencyclodextrin dimers and hydrophobe substituted poly (acrylic acid)s | 第112-130页 |
| ·Introduction | 第112-113页 |
| ·Experimental | 第113-115页 |
| ·Materials | 第113-114页 |
| ·Synthesis of CD dimers | 第114页 |
| ·Characterization | 第114-115页 |
| ·Results and discussion | 第115-126页 |
| ·~1H NMR studies of the host-guest interactions between AD substituted PAAs and β-CD dimers | 第115-119页 |
| ·Rheological studies of the networks formed by AD substituted PAAs and β-CD dimers | 第119-120页 |
| ·Effect of tether length in AD substituted PAAs and linker length in β-CD dimers | 第120-122页 |
| ·Host-guest interactions between alkyl substituents in PAAs and CD dimers | 第122-125页 |
| ·Effect of alkyl substituent length and CD annular size | 第125-126页 |
| ·Chapter conclusions | 第126-127页 |
| References | 第127-130页 |
| Chapter 6 Polymer networks assembled by fluorophore substituted poly (acrylic acid)sand β-cyclodextrin dimer or β-cyclodextrin substituted poly (acrylic acid) | 第130-156页 |
| ·Introduction | 第130-131页 |
| ·Experimental | 第131-135页 |
| ·Materials | 第131页 |
| ·Synthesis of dansyl substituted PAAs | 第131-133页 |
| ·Characterization | 第133-135页 |
| ·Results and discussion | 第135-152页 |
| ·Host-guest inclusion identification by 2D NOESY ~1H NMR | 第135-139页 |
| ·Fluorescence and UV-vis studies of dansyl group complexation by β-CD | 第139-147页 |
| ·Time resolved fluorescence studies of the dansyl species | 第147-151页 |
| ·Rheological studies of fluorescence polymer networks | 第151-152页 |
| ·Chapter conclusions | 第152-153页 |
| References | 第153-156页 |
| Chapter 7 Polymer networks assembled by inclusion complexation of poly (ethyleneglycol) with α-cyclodextrin | 第156-169页 |
| ·Introduction | 第156-157页 |
| ·Experimental | 第157页 |
| ·Materials | 第157页 |
| ·Hydrogel preparation | 第157页 |
| ·Characterization | 第157页 |
| ·Results and discussion | 第157-166页 |
| ·Effect of PEG molecular weight on formation of hydrogels | 第157-160页 |
| ·Effect of the gap between the plate and the stage of the rheometer | 第160-161页 |
| ·Effect of storage time | 第161-162页 |
| ·Effect of sonication | 第162-164页 |
| ·Thermal properties and crystalline structure | 第164-166页 |
| ·Chapter conclusions | 第166页 |
| References | 第166-169页 |
| SUMMARY | 第169-172页 |
| ACKNOWLEDGEMENTS | 第172-173页 |
| PUBLICATIONS | 第173-176页 |
