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羰基官能化的烷基取代喹吖啶酮的合成,表征及应用

Chapter 1- Introduction第9-74页
    1.1. Quinacridone第9-15页
        1.1.1. Historical background第9页
        1.1.2. Structural data and Chemical nature第9-11页
        1.1.3. Synthesis of quinacridones第11-12页
        1.1.4. Substituted Quinacridones第12-13页
        1.1.5. Properties and Applications of quinacridones第13-15页
        1.1.6. Modern area of research on Quinacridone第15页
    1.2. Introduction to Solar cell第15-34页
        1.2.1. Motivation第15-16页
        1.2.2. Organic solar cells第16-17页
        1.2.3. Basic processes in an organic solar cell第17-19页
        1.2.4. Processing of organic solar cells第19页
        1.2.5. Organic solar cell architectures and review of performance results第19-25页
        1.2.6. Characterization of solar cell第25-27页
        1.2.7. Role of morphology in organic solar cell efficiency第27-28页
        1.2.8. State-of the-art in bulk-heterojunction solar cells第28-33页
        1.2.9. Role of quinacridone based materials in organic solar cells第33-34页
    1.3. Aggregation Induced Emission第34-42页
        1.3.1. AIE systems第36-41页
        1.3.2. Role of Quinacridone in aggregation induced emission第41-42页
    1.4. One dimensional Self assembly第42-49页
        1.4.1. Frequently occurring forces in one-dimensional self-assembly第42-48页
        1.4.2. Self Assembly in Quinacrdones第48-49页
    1.5. Polymorphism第49-52页
        1.5.1. Polymorphism in Quinacridones第51-52页
    1.6. Aims, Objectives and results第52-56页
    1.7. References第56-74页
Chapter 2 _ Quinacridone Based Electron-Accepting Organic Dyes: Synthesis, Characterizations and Application in Hetrojunction Solar Cells第74-99页
    2.1. Background第74-75页
    2.2. Synthesis第75-77页
        2.2.1. Synthesis of 1 and 2第75-76页
        2.2.2. Synthesis of 3 and 4第76-77页
        2.2.3. Synthesis of 5 and 6第77页
    2.3. Results and Discussion第77-92页
        2.3.1. Crystal structure第78-81页
        2.3.2. Photophysical Properties第81-84页
        2.3.3. Redox Properties第84-86页
        2.3.4. Thermal Properties第86-88页
        2.3.5. Morphology of blend by atomic force microscopy (AFM)第88-89页
        2.3.6. Photovoltaic properties第89-92页
    2.4. Summary第92-93页
    2.5. 总结第93-94页
    2.6. References第94-99页
Chapter 3 _ Aggregation-Induced Emission: Red emiiting Quinoacridine Derivatives第99-125页
    3.1. Background第99-100页
    3.2. SYNTHESIS第100-101页
        3.2.1. Synthesis of 1第100页
        3.2.2. Synthesis of 2第100-101页
        3.2.3. Synthesis of 3第101页
    3.3. Results and Discussion第101-119页
        3.3.1. Absorption Properties第102-103页
        3.3.2. Solvent polarity effect第103-105页
        3.3.3. Effect of temperature on Molecular rotations第105-107页
        3.3.4. Temperature dependent 1HNMR第107-108页
        3.3.5. Primary spectral characterization and aggregation induced emission第108-114页
        3.3.6. Variable temperatures PL of 1-3 with different water fraction第114-115页
        3.3.7. Concentration dependence of the aggregation induced emission第115-116页
        3.3.8. Effect of morphology on luminescent properties第116-117页
        3.3.9. Crystal structure第117-119页
    3.4. Summary第119页
    3.5. 总结第119-121页
    3.6. References第121-125页
Chapter 4 _ One Dimensional Self Assembly in Quinacridine Derivatives第125-143页
    4.1. Background第125-126页
    4.2. Result and discussion第126-138页
        4.2.1. Preparation of Nanostructures and micromaterials第126-127页
        4.2.2. Effect of molecular structural design on monrphology第127页
        4.2.3. Morphology transition from 0_D nanostructures to 1_D microwires第127-131页
        4.2.4. 1DSelf-assembly第131-133页
        4.2.5. Study of single crystal structure and XRD pattern第133-135页
        4.2.6 Redox Properties第135-136页
        4.2.7. Thermal Properties第136-138页
    4.3. Summary第138-139页
    4.4. 总结第139-140页
    4.5. References第140-143页
Chapter 5 _ Quinacridone diimine Derivatives: Synthesis,Spectroscopic Characterization and Molecular Conformation Study第143-175页
    5.1. Background第143-144页
    5.2. Synthesis第144-149页
        5.2.1. Synthesis of N, N-Diphenyl-N, N‘-Di (n-butyl) quinacridonediimine (1)第145页
        5.2.2. Synthesis of N,N-Bis(4-fluorophenyl)-N,N‘-Di(n-butyl)quinaridonediimine第145页
        5.2.3. Synthesis of N,N-Diphenyl-N,N‘-Di(n-butyl)-2,9-difluoroquinacridonediimine(3)第145-146页
        5.2.4. Synthesis of N,N-Bis(4-fluorophenyl)-N,N‘-Di(n-butyl)-2,9-difluoroquinacridonediimine(4)第146页
        5.2.5. Synthesis of N,N-Diphenyl-N,N‘-Di(n-butyl)-1,3,8,10 tetramethylquinacridonediimine(5)第146-147页
        5.2.6. Synthesis of N,N-Bis(4-fluorophenyl)-N,N‘-Di(n-butyl)-1,3,8,10-tetramethylquinacridonediimine (6)第147页
        5.2.7. Synthesis of N,N-Bis(2,3,4,5,6-pentafluorophenyl)-N,N‘-Di(n-butyl)quinaridonediimine(7)第147页
        5.2.8. Synthesis of N,N-Bis(3,5-dimethylphenyl)-N,N‘-Di(n-butyl)-2,9-difluoroquinacridonediimine(8)第147-148页
        5.2.9. Synthesis of N,N-dinaphthyl-N,N‘-Di(n-butyl)quinaridonediimine(9)第148页
        5.2.10. Synthesis of N,N-Bis(4-cyanophenyl)-N,N‘-Di(n-octyl))quinacridonediimine(10)第148-149页
    5.3. Results and Discussion第149-170页
        5.3.1. Photophysical Properties第150-153页
        5.3.2. Twisting of N-phenyl ring and buckling of QA skeleton第153页
        5.3.3. Variable Temperature NMR Studies第153-155页
        5.3.4. Computational Study第155-159页
        5.3.5. X-Ray single crystal structure determination第159-168页
        5.3.6. Redox Properties第168-170页
    5.4. Summary第170页
    5.5. 总结第170-172页
    5.6. References第172-175页
Chapter 6 _ Conclusion第175-178页
Publications第178-179页
Acknowledgements第179-181页
中文摘要第181-183页
Abstract第183-185页

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