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卟啉—多金属氧酸盐杂化材料的制备、表征及非线性光学性质

Abstract第7-10页
摘要第11-16页
Abbreviations第16-22页
Chapter 1第22-36页
    1.1 Introduction第22页
    1.2 Nonlinear Susceptibility第22-23页
    1.3 Importance of Third-Order NLO Materials第23-24页
    1.4 Nonlinear Optical Materials第24-26页
    1.5 Importance of Porphyrins第26-27页
    1.6 Importance of Porphyrins as NLO Materials第27-31页
        1.6.1 Symmetric Porphyrins第27-28页
        1.6.2 Asymmetric Porphyrins第28-29页
        1.6.3 Expanded Porphyrin第29-30页
        1.6.4 Oligomers of Porphyrins第30页
        1.6.5 Porphyrin Supramolecular Arrays第30-31页
    1.7 Porphyrin Based Hybrids第31-32页
    1.8 Limitation of Porphyrins Regarding NLO and its Solution第32页
    1.9 What Are Polyoxometalate?第32-33页
    1.10 Aims and Objectives of the Study第33-34页
    1.11 Applications of NLO Materials第34-36页
Chapter 2 Anionic Effect of δ and χ Forms of Tris(alkoxo) Ligand FunctionalizedAnderson-type Polyoxometalates on Nonlinear Optical Response of Porphyrin-POM Based Supramolecular Compounds第36-60页
    Abstract第36-37页
    2.1 Introduction第37-39页
    2.2 Experimental Section第39-41页
    2.3 Results and Discussions第41-59页
        2.3.1 Third Order NLO Properties and the Effect of Anion第52-59页
    2.4 Conclusions第59-60页
Chapter 3 Covalently Linked Porphyrins with Lindqvist-Type Polyoxometalate:AComparative Analysis for Outstanding Third Order NLO and SecondHyperpolarizability第60-82页
    Abstract第60-61页
    3.1 Introduction第61-75页
    3.3第75-80页
        3.3.1 Third Order NLO Measurement and Second Hyperpolarizability第75-80页
    3.4 Conclusions第80-82页
Chapter 4 Effect of Different Electron Donors in Supramolecular Compounds ofSymmetrical Porphyrins with Keggin-type Molybdovanadophosphoric Acid forNLO Properties第82-104页
    Abstract第82-83页
    4.1 Introduction第83-85页
    4.2 Experimental Section第85-88页
        4.2.1. Synthesis of [C_(44)H_(32)N_4O_4][H_4PMo_(10)V_2O_(40)]_2 (compound 1)第86页
        4.2.2. Synthesis of [C_(40)H_(28)N_8][H_4PMo_(10)V_2O_(40)]_2(compound 2)第86-87页
        4.2.3. Synthesis of [C_(52)H_(48)N_4O_8] [H_4PMo_(10)V_2O_(40)]_2(compound 3)第87页
        4.2.4. Protocol for preparation of 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin (compound 4)第87页
        4.2.5. Synthesis of 5,10,15,20-tetrakis(3,4-Dimethoxy phenyl)porphyrin(compound 6)第87-88页
    4.3 Results and Discussions第88-102页
        4.3.1. Third Order NLO Properties第97-102页
    4.4 Conclusions第102-104页
5.1 References第104-118页
Conclusion第118-120页
Novelty第120-122页
Acknowledgements第122-124页
List of Publications第124-126页
Farooq Khurum Shehzad (Author)第126-128页
Prof. Dr. Yunshan Zhou (Supervisor)第128-130页
附件第130-131页

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