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多孔配位聚合物的可控制备及其在催化和储能领域的应用研究

ACKNOWLEDGEMENTS第4-5页
致谢第5-6页
ABSTRACT第6-7页
摘要第8-14页
LIST OF SYMBOLS AND ABBREVIATIONS第14-22页
INTRODUCTION AND GENERAL OUTLINE第22-25页
1. POROUS SOLID MATERIALS第25-43页
    1.1. Metal organic frameworks第25-36页
        1.1.1. Generality第25-26页
        1.1.2. Design of MOFs第26-28页
        1.1.3. Synthesis of MOFs第28-30页
            1.1.3.1. Synthetic methodology第29页
            1.1.3.2. Solvent第29-30页
            1.1.3.3. Time and temperature第30页
            1.1.3.4. Concentration of reagents, acidity or basicity and templates第30页
        1.1.4. Applications of MOFs第30-31页
            1.1.4.1 Gas storage第30-31页
            1.1.4.2. Gas purification第31页
        1.1.5. State of the art of acido-basic catalytic MOFs第31-35页
            1.1.5.1. Lewis acid Catalysis第31-33页
            1.1.5.2 Bronsted acid Catalysis第33页
            1.1.5.3 Base catalysis第33-34页
            1.1.5.4. Acid-base one-pot catalysis第34-35页
        1.1.6. Functional MOFs by post-synthetic modification(PSM)第35-36页
    1.2. Metal-organic gels第36-38页
        1.2.1. Generality第36-37页
        1.2.2. Synthesis of MOGs第37-38页
        1.2.3. Applications of MOGs第38页
    1.3. Organic porous polymer第38-43页
        1.3.1. Generality第38页
        1.3.2. Structure of COFs第38-41页
        1.3.3. Synthesis of porous organic polymer第41-42页
        1.3.4. Applications of porous organic polymer第42-43页
2. STATE OF THE ART OF CATALYSIS第43-46页
    2.1. Introduction第43-44页
    2.2. Characteristic of the catalytic activity第44-45页
    2.3. The different types of catalyst第45-46页
        2.3.1. Heterogeneous catalysis第45页
        2.3.2. Homogeneous catalysis第45-46页
        2.3.3. Enzymatic catalysis第46页
3. OVERVIEW OF THERMAL ENERGY STORAGE第46-55页
    3.1. Generality第46-49页
    3.2. Forms of thermal energy storage第49-51页
        3.2.1. Sensible heat storage第49-50页
        3.2.2. Thermochemical storage第50页
        3.2.3. Latent heat storage第50-51页
    3.3. Encapsulation of PCMs into construction materials and elements第51-53页
    3.4. Potential applications of latent heat storage第53-55页
4. SO_3H-FUNCTIONALIZED METAL ORGANIC FRAMEWORKS:AN EFFICIENT HETEROGENEOUS CATALYST FOR THE SYNTHESIS OF QUINOXALINE AND DERIVATIVES第55-72页
    4.1. INTRODUCTION第55-56页
    4.2. EXPERIMENTAL第56-58页
        4.2.1. Synthesis of MIL-101-Cr-NH_2 and UiO-66-Zr-NH_2第56-57页
        4.2.2. Post-synthetic modification of MIL-101-Cr-NH_2 and UiO-66-Zr-NH_2第57-58页
        4.2.3. Synthesis of the sulfonated-polystyrene(SPS)microspheres第58页
        4.2.4. General procedure for the condensation of benzene-1,2-diamine with benzil第58页
    4.3. RESULTS AND DISCUSSION第58-71页
        4.3.1. Catalysts characterization第58-64页
        4.3.2. Catalytic study第64-71页
    4.4. SUMMARY第71-72页
5. NOVEL GREEN CHEMISTRY APPROACHES FOR THE SYNTHESIS OF DIHYDROCOUMARIN,A COUMARIN DERIVATIVE BY BIFUNCTIONAL METAL-ORGANIC FRAMEWORKS第72-81页
    5.1. INTRODUCTION第72-73页
    5.2. MATERIALS AND METHODS第73-74页
        5.2.1. Synthesis of 2-methylaziridine from Amino Alcohols第73-74页
        5.2.2. Post synthetic modification of MIL-101-Cr-NH_2:第74页
    5.3. RESULTS AND DISCUSSION第74-80页
        5.3.1. Characterization第74-76页
        5.3.2. Catalytic activity第76-80页
    5.4. SUMMARY第80-81页
6. POROUS ORGANIC-INORGANIC HYBRID XEROGELS FOR STEARIC ACID SHAPE-STABILIZED PHASE CHANGE MATERIAL第81-94页
    6.1. INTRODUCTION第81-82页
    6.2. MATERIALS AND METHODS第82-83页
        6.2.1. Preparation of MOGs第82-83页
        6.2.2. Preparation of PCM@MOG composites第83页
    6.3. RESULTS AND DISCUSSION第83-93页
        6.3.1. Characterization of the support materials第83-90页
        6.3.2 Thermal properties of PCM/CrBTC composite第90-93页
    6.4. SUMMARY第93-94页
7. PEG ENCAPSULATED BY POROUS TRIAMIDE-LINKED POLYMERS AS SUPPORT FOR SOLID-LIQUID PHASE CHANGE MATERIALS FOR ENERGY STORAGE第94-107页
    7.1. INTRODUCTION第94-96页
    7.2. EXPERIMENTAL第96页
        7.2.1 General synthesis process for the Porous Triamide-linked Polymers第96页
        7.2.2 Fabrication of composite PCMS第96页
    7.3. RESULTS AND DISCUSSION第96-105页
    7.4. SUMMARY第105-107页
8. CONCLUSION GENERALE第107-108页
APPENDIX Ⅰ-EXPERIMENTAL DETAILS第108-109页
REFERENCES第109-125页
Author^s Curriculum Vitae第125-128页
学位论文数据集第128页

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