| 作者简介 | 第1-9页 |
| 摘要 | 第9-12页 |
| ABSTRACT | 第12-15页 |
| Table of Contents | 第15-18页 |
| Chapter 1 Background and Related works | 第18-50页 |
| ·What are polymer lithium ion batteries | 第18-22页 |
| ·Research progress of electrolytes for polymer lithium ion batteries | 第22-44页 |
| ·Introduction and research progress of liquid electrolytes | 第23-25页 |
| ·Introduction and research progress of other liquid electrolytes | 第25-32页 |
| ·The safety issue of liquid organic electrolyte | 第32-34页 |
| ·Introduction and research progress of gel polymer electrolytes | 第34-41页 |
| ·poly(ethylene oxide)(PEO)based gel polymer electrolytes | 第35-36页 |
| ·poly(vinylidene fluoride)(PVdF)based gel polymer electrolytes | 第36-37页 |
| ·poly(methyl methacrylate)(PMMA)based gel polymer electrolytes | 第37-38页 |
| ·poly(acrylonitrile)(PAN)based gel polymer electrolytes | 第38-39页 |
| ·poly(vinyl chloride)(PMMA)based gel polymet electrolytes | 第39-40页 |
| ·Summary | 第40-41页 |
| ·Research progress of single ion conducting polymer electrolytes | 第41-44页 |
| ·TFSI based single ion conducting polymer electrolytes | 第42-43页 |
| ·sp~3 boron based single ion conducting polymer electrolytes | 第43-44页 |
| ·About this Work | 第44-46页 |
| ·Motivations | 第46页 |
| ·Reagents and characterization | 第46-50页 |
| ·Reagents | 第46-48页 |
| ·Characterization | 第48-50页 |
| ·Fourier transform infra-red(FTIR)spectroscopy | 第48页 |
| ·NMR spectroscopy | 第48页 |
| ·Thermal Characterization | 第48页 |
| ·SEM test | 第48页 |
| ·Electrochemical stability | 第48-49页 |
| ·Ionic ic conductivity characterization | 第49页 |
| ·X-ray diffraction spectroscopy | 第49-50页 |
| Chapter 2 Synthesis and characterization of lithium poly(hydroquinone borate)(LiPHB) | 第50-65页 |
| ·Experimental | 第50-53页 |
| ·Synthesis of the lithium tetramethanolatoborate | 第50页 |
| ·Synthesis of lithium poly(hydroquinone borate)(LiPHB) | 第50-52页 |
| ·Preparation of single ion conductor membrane | 第52-53页 |
| ·Results and Discusssion | 第53-63页 |
| ·Morphology and microstructure characterization | 第53-54页 |
| ·Thermal property | 第54-55页 |
| ·Electrochemical stability | 第55页 |
| ·Interfacial and bulk resistance of EC/PC swollen SS|GPEM|SS cells | 第55-58页 |
| ·Interfacial and bulk resistance of M1 polymer electrolyte membrane | 第55-57页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第57-58页 |
| ·SEM test | 第58-61页 |
| ·Ionic Conductivity | 第61-63页 |
| ·Chapter summary | 第63-65页 |
| Chapter 3 Synthesis and characterization of lithium poly(phloroglucinol borate)(LiPPB) | 第65-77页 |
| ·Experimental | 第65-67页 |
| ·Synthesis of lithium poly(phloroglucinol borate)(LiPPB) | 第65-67页 |
| ·Preparation of single ion conductor membrane | 第67页 |
| ·Results and Discussion | 第67-76页 |
| ·Morphology and microstructure characterization | 第67-68页 |
| ·Thermal properties | 第68-69页 |
| ·Electrochemical stability | 第69页 |
| ·Interfacial and bulk resistance of EC/PC swollen SS|GPEM|SS cell | 第69-72页 |
| ·Interfacial and bulk resistance of M1 polymer electrolyte membrane | 第69-71页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第71-72页 |
| ·SEM test | 第72-74页 |
| ·Ionic Conductivity | 第74-76页 |
| ·Chapter summary | 第76-77页 |
| Chapter 4 Synthesis and characterization of lithium poly(4,4'-biphenol borate)(LiPBB) | 第77-89页 |
| ·Experimental | 第77-79页 |
| ·Synthesis of lithium poly(4,4'-biphenol borate)(LiPBB) | 第77-79页 |
| ·Preparation of single ion conductor membrane | 第79页 |
| ·Results and Discussion | 第79-88页 |
| ·Morphology and microstructure characterization | 第79-80页 |
| ·Thermal properties | 第80页 |
| ·Electrochemical stability | 第80-81页 |
| ·Interfacial and bulk resistance of EC/PC swollen SS|GPEM|SS cell | 第81-84页 |
| ·Interfacial and bulk resistance of M1 polymer electrolyte membrane | 第81-82页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第82-84页 |
| ·SEM test | 第84-86页 |
| ·Ionic Conductivity | 第86-88页 |
| ·Chapter summary | 第88-89页 |
| Chapter 5 Synthesis and characterization of lithium poly(1,2,3,4-Butanetetracarboxylic acidborate)(LiPBAB) | 第89-102页 |
| ·Experimental | 第89-92页 |
| ·Synthesis of lithium poly(1,2,3,4-Butanetetracarboxylic acid borate)(LiPBAB) | 第89-91页 |
| ·Preparation of single ion conductor membrane | 第91-92页 |
| ·Results and Discussion | 第92-100页 |
| ·Morphology and microstructure characterization | 第92-93页 |
| ·Thermal properties | 第93页 |
| ·Electrochemical stability | 第93-94页 |
| ·Interfacial and bulk resistance of EC/PC swollell SS|GPEM|SS cell | 第94-96页 |
| ·Interfacial and bulk resistance of M1 polymet electrolyte membrane | 第94-95页 |
| ·Interfacial and bulk resistance of M2 polymet electrolyte membrane | 第95-96页 |
| ·SEM test | 第96-99页 |
| ·Ionic Conductivity | 第99-100页 |
| ·Chapter summary | 第100-102页 |
| Chapter 6 Synthesis and characterization of lithium poly(diacylbenzenesulfonylimidediphenylsulfoneamide)(LiPDSPA) | 第102-117页 |
| ·Experimental | 第102-106页 |
| ·Synthesis of bis(4-carboxyl benzene sulphonyl)imide | 第102-103页 |
| ·Synthesis of lithium poly(diacylbenzenesulfonylimide diphenylsulfoneamide) (LiPDSPA) | 第103-106页 |
| ·Preparation of single ion conductor membrane | 第106页 |
| ·Results and Discussion | 第106-115页 |
| ·Thermal properties | 第106-107页 |
| ·Electrochemical stablity | 第107-108页 |
| ·Interfacial and bulk resistance of EC/PC swollen SS|GPEM|SS cell | 第108-111页 |
| ·Interfacial and bulk resistance of M1 polymer electrolyte membrane | 第108-110页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第110-111页 |
| ·SEM test | 第111-114页 |
| ·Ionic Conductivity | 第114-115页 |
| ·Chapter summary | 第115-117页 |
| Chapter 7 Synthesis and characterization of lithium poly(diacylphenylsulfonylimide octylamide)(LiPDSOA) | 第117-130页 |
| ·Experimental | 第117-120页 |
| ·Synthesis of lithium Poly(diacylphenylsulfonylimide octylamide)(LiPDSOA) | 第117-119页 |
| ·Preparation of single ion conductor membrane | 第119-120页 |
| ·Results and Discussion | 第120-128页 |
| ·Thermal properties | 第120页 |
| ·Electrochemical stability | 第120-121页 |
| ·Interfacial bulk resistance of EC/PC swollen SS|GPEM|SS cell | 第121-124页 |
| ·Interfacial and bulk resistance of M1 polymer electrolyte membrane | 第121-123页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第123-124页 |
| ·SEM test | 第124-127页 |
| ·Ionic Conductivity | 第127-128页 |
| ·Chapter summary | 第128-130页 |
| Chapter 8 Synthesis and characterization of Poly(isophthaloyl benzenesulfonic acid-2,4-diamidediphenylsulfone diamide)with pended lithium sulfonimide(LiPIBPSI) | 第130-142页 |
| ·Experimental | 第130-132页 |
| ·Synthesis of Bis(sulfonyl)imine-functionalized polyamide | 第130-132页 |
| ·Preparation of single ion conductor membrane | 第132页 |
| ·Results and Discussion | 第132-141页 |
| ·Thermal properties | 第132-133页 |
| ·Electrochemical stability | 第133-134页 |
| ·Interfacial and bulk resistance of EC/PC swollen SS|GPEM|SS cell | 第134-136页 |
| ·Interfacial and bulk resistance of M1 polymet electrolyte membrane | 第134-135页 |
| ·Interfacial and bulk resistance of M2 polymer electrolyte membrane | 第135-136页 |
| ·SEM test | 第136-139页 |
| ·Ionic Conductivity | 第139-141页 |
| ·Chapter Summary | 第141-142页 |
| Chapter 9 Conclusion | 第142-146页 |
| Acknowledgements | 第146-149页 |
| Reference | 第149-155页 |
