| 摘要 | 第1-10页 |
| Abstract | 第10-20页 |
| Chapter 1.Introduction | 第20-47页 |
| ·The structure and composition of montmorillonite | 第20-21页 |
| ·The basic concept of gallery areas of montmorillonite | 第21-22页 |
| ·The modification and application of montmorillonite | 第22-33页 |
| ·Acidic montmorillonite | 第23页 |
| ·Organic pillared montmorillonite | 第23-26页 |
| ·Inorganic pillared montmorillonite | 第26-32页 |
| ·single-component inorganic pillared montmorillonite | 第27-30页 |
| ·Inorganic composite pillared montmorillonite | 第30-32页 |
| ·Organic-inorganic composite pillared montmorillonite | 第32-33页 |
| ·The impact on porous clay materials of self-assembly mesoporous materials | 第33-34页 |
| ·The research basis and the significance | 第34-37页 |
| References | 第37-47页 |
| Chapter 2.Experimental Procedures | 第47-54页 |
| ·The materials | 第47-48页 |
| ·The chemical reagents | 第47页 |
| ·The chemical reagents prepared | 第47-48页 |
| ·The oil for catalytic evaluation | 第48页 |
| ·The used natural montmorillonite | 第48页 |
| ·Synthesis procedure of silica pillared clay with ordered mesoporous structure | 第48-49页 |
| ·The synthesis of SPC with mixed surfactants | 第49-50页 |
| ·The synthesis with cationic-cationic mixed surfactants | 第49页 |
| ·The synthesis with cationic-anionic mixed surfactants | 第49-50页 |
| ·Synthesis of cobalt or nickel containing SPC derivatives | 第50页 |
| ·Characterization | 第50-52页 |
| ·The X-ray diffraction analysis | 第51页 |
| ·N_2 adsorption-desorption analysis | 第51页 |
| ·Scanning electron microscopy(SEM) analysis | 第51页 |
| ·FT-IR analysis | 第51页 |
| ·UV-Vis absorption spectra | 第51页 |
| ·Temperature-programmed reduction analysis | 第51-52页 |
| ·Transmission electron microscopy(TEM) analysis | 第52页 |
| ·High-resolution transmission electron microscopy(HRTEM) analysis | 第52页 |
| ·The catalytic activity test | 第52-54页 |
| Chapter 3.The synthesis and characterization of SPC-16 derivatives | 第54-70页 |
| ·Introduction | 第54页 |
| ·The experiment process | 第54-55页 |
| ·Results and discussion | 第55-64页 |
| ·The molar ratios of gel mixture during synthesis process | 第55-56页 |
| ·The reaction time of synthesis of SPC-16 | 第56-58页 |
| ·The calcination temperature | 第58页 |
| ·Powder X-ray analysis for SPC-16 | 第58-59页 |
| ·SEM images for the SPC-16 | 第59-61页 |
| ·Porous structure analysis | 第61-63页 |
| ·The TEM and HRTEM analysis | 第63-64页 |
| ·The mechanism discussion | 第64-67页 |
| ·Summary | 第67-68页 |
| References | 第68-70页 |
| Chapter 4.Synthesis of SPC derivatives by different surfactants as the gallery templates | 第70-83页 |
| ·Introduction | 第70页 |
| ·Preparation of SPC derivatives using different surfactants | 第70-71页 |
| ·Results and discussion | 第71-79页 |
| ·Powder X-ray analysis | 第71-72页 |
| ·The gallery pore structure of the SPC derivatives | 第72-76页 |
| ·FT-IR analysis for SPC derivatives | 第76-77页 |
| ·The SEM images for the SPC derivatives | 第77-78页 |
| ·The catalytic property for CGO cracking | 第78-79页 |
| ·Summary | 第79-81页 |
| References | 第81-83页 |
| Chapter 5.The synthesis of SPC derivatives with mixed surfactants | 第83-102页 |
| ·Introduction | 第83-84页 |
| ·The experiment procedure | 第84-85页 |
| ·The experiment process using cationic-cationic mixed surfactants | 第84页 |
| ·The experiment process using cationic-anionic mixed surfactants | 第84-85页 |
| ·The results and discussion | 第85-98页 |
| ·The physical and chemical properties of the SPC derivatives tempalting from cationic-cationic surfactants | 第85-91页 |
| ·The layered structure analysis by XRD | 第85页 |
| ·The gallery pore structure analysis | 第85-87页 |
| ·The FT-IR spectroscopy | 第87-88页 |
| ·The SEM images for the samples | 第88-91页 |
| ·The catalytic property for CGO cracking | 第91页 |
| ·The physical and chemical properties of SPC derivatives templating from cationic-anionic surfactants | 第91-98页 |
| ·The layered structure | 第91-92页 |
| ·The porous structure of the materials | 第92-95页 |
| ·The FT-IR analysis | 第95-96页 |
| ·The SEM image | 第96-97页 |
| ·The wide angle XRD patterns for the two samples | 第97-98页 |
| ·Summary | 第98-100页 |
| References | 第100-102页 |
| Chapter 6.Synthesis and characterization of metals-containing SPC derivatives and the catalytic properties research | 第102-125页 |
| ·Introduction | 第102页 |
| ·The experiment process | 第102-104页 |
| ·The synthesis of nickel-containing SPC derivatives | 第102-103页 |
| ·Synthesis of comparable samples | 第103页 |
| ·The synthesis of cobalt-containing SPC derivatives | 第103-104页 |
| ·The synthesis of comparable sample Co/SPC | 第104页 |
| ·Results and discussion | 第104-121页 |
| ·The physical and chemical properties of Ni-SPC derivatives | 第104-114页 |
| ·The layered structure of Ni-SPC derivatives | 第105-107页 |
| ·The FT-IR analysis | 第107-108页 |
| ·The porous structure of Ni-SPC derivatives | 第108-110页 |
| ·The temperature-programmed reduction(TPR) analysis | 第110-111页 |
| ·The DR UV-vis spectroscopy for the Ni-SPC derivatives | 第111-112页 |
| ·The catalytic test | 第112-114页 |
| ·The physical and chemical properties of Co-SPC derivatives | 第114-121页 |
| ·The layered structure of Co-SPC derivatives | 第114-117页 |
| ·The FT-IR spectroscopy analysis | 第117页 |
| ·The porous structure of Co-SPC derivatives | 第117-119页 |
| ·H_2-TPR analysis | 第119-120页 |
| ·DR UV-Dis analysis | 第120-121页 |
| ·Summary | 第121-123页 |
| References | 第123-125页 |
| Chapter 7.The mechanism discussion of porous structure form | 第125-130页 |
| ·The mechanism of porous structure formed by single surfactants | 第125-127页 |
| ·The mechanism of porous structure formed by surfactants mixture | 第127页 |
| ·The porous structure formed by cationic-cationic surfactants mixture | 第127页 |
| ·The porous structure formed by cationic-anionic surfactants mixture | 第127页 |
| ·The metals containing SPC derivatives | 第127-128页 |
| ·The catalytic properties influence from pore size | 第128-130页 |
| The main conclusion and the future view | 第130-133页 |
| 论文创新点 | 第133-134页 |
| 主要成就和研究成果 | 第134-135页 |
| 致谢 | 第135-136页 |
| 作者与导师简介 | 第136页 |
