| 摘要 | 第5-8页 |
| Abstract | 第8页 |
| Chapter 1 Introduction | 第12-28页 |
| 1.1 Study background | 第12-25页 |
| 1.1.1 Rare earth elements specifications | 第13-19页 |
| 1.1.2 LED lightening | 第19-20页 |
| 1.1.3 Lightening glass ceramic | 第20-21页 |
| 1.1.4 Nitric oxide fluorescence powder | 第21-22页 |
| 1.1.5 Rare earth ion spectrum | 第22-23页 |
| 1.1.6 Rare earth doped nitric oxide glass ceramic | 第23-24页 |
| 1.1.7 Rare earth doped oxiflyoride glass ceramic | 第24-25页 |
| 1.2 Existing problems | 第25-26页 |
| 1.3 Contents of this thesis | 第26-28页 |
| Chapter 2 Experimental procedure | 第28-35页 |
| 2.1 Preparation of glasses and glass ceramics | 第28-30页 |
| 2.1.1 Experiment materials and equipment | 第28-29页 |
| 2.1.2 Preparation of glasses and glass ceramics | 第29-30页 |
| 2.2 Characterization | 第30-35页 |
| 2.2.1 Differential Thermal Analysis(DTA) | 第30页 |
| 2.2.2 X-Ray Diffraction(XRD) | 第30-31页 |
| 2.2.3 Absorption Spectra(Abs) | 第31页 |
| 2.2.4 Photoluminescence(PL) | 第31-33页 |
| 2.2.5 Luminescence decay curves | 第33页 |
| 2.2.6 CIE Coordinate Diagram(CIE) | 第33-35页 |
| Chapter 3 spectroscopic properties of europium doped nitric oxide glass ceramicsprepared by nitrogen ventilation | 第35-49页 |
| 3.1 Preparation of glasses and glass ceramics | 第35-36页 |
| 3.2 Structure and spectroscopic properties of glasses and glass ceramics | 第36-47页 |
| 3.2.1 Differential thermal analysis | 第36页 |
| 3.2.2 X-ray diffraction analysis | 第36-38页 |
| 3.2.3 Electron microscope | 第38-39页 |
| 3.2.4 Absorption spectrum | 第39-41页 |
| 3.2.5 Fluorescence spectrum | 第41-44页 |
| 3.2.6 CIE chromaticity coordinates, color temperature, and color rendering index estimation | 第44-46页 |
| 3.2.7 quantum yields(QYs) | 第46-47页 |
| 3.3 Summary | 第47-49页 |
| Chapter 4 spectroscopic properties of europium doped nitric oxide glass ceramicprepared by Si3N4 | 第49-61页 |
| 4.1 Preparation of glasses and glass ceramics | 第49-50页 |
| 4.2 Influence of composition on the microstructure and spectroscopic properties of glass ceramics | 第50-59页 |
| 4.2.1 Phase composition | 第50-52页 |
| 4.2.2 Fluorescence spectroscopy | 第52-56页 |
| 4.2.3 CIE chromaticity coordinates, color temperature and color rendering index estimation | 第56-57页 |
| 4.2.4 Decay curves and luminescence theory | 第57-59页 |
| 4.3 Summary | 第59-61页 |
| Chapter 5 preparation and spectroscopic properties of the Ce~(3+) and Ln~(3+)(Ln=Tb,Dy, Sm, Eu) codoped SiO_2-Al_2O_3-SrF_2-GdF_3-NaF oxyflouride glasse | 第61-76页 |
| 5.1 Preparation of glasses | 第61页 |
| 5.2 Spectroscopic properties of glasses | 第61-75页 |
| 5.2.1 Ce~(3+) and Tb~(3+) codoped glasses | 第67-70页 |
| 5.2.2 Ce~(3+) and Sm~(3+) codoped glasses | 第70-72页 |
| 5.2.3 Ce~(3+) and Dy~(3+) codoped glasses | 第72-73页 |
| 5.2.4 Ce~(3+) and Eu~(3+) codoped glasses | 第73-75页 |
| 5.3 Summery | 第75-76页 |
| Chapter 6:Conclusions | 第76-78页 |
| References | 第78-82页 |
| Publications | 第82-83页 |
| Acknowledgement | 第83页 |
