| Abstract | 第4页 |
| Table of contents | 第5-7页 |
| Acknowledgements | 第7-9页 |
| Chapter Ⅰ:Introduction | 第9-11页 |
| Bibliographic Review | 第11-41页 |
| 1.1. Benzannulation | 第11-20页 |
| 1.1.1. Synthesis of fluoranthene via [3+3] cycloaddition | 第11-12页 |
| 1.1.2. Synthesis of tetrahydroindolizidines and hexahydroquinolines 11 | 第12页 |
| 1.1.3. Nucleophilic aryl and heteroaryl-methyl | 第12-19页 |
| 1.1.4. Other nucleophiles | 第19-20页 |
| 1.2. Synthesis of diaryl sulfides | 第20-25页 |
| 1.2.1 Brief introduction | 第20-21页 |
| 1.2.2. Synthesis of arene 113a | 第21-22页 |
| 1.2.3. Synthesis of arenes 116 and 119 | 第22-23页 |
| 1.2.4. Synthesis of arene 122b | 第23-25页 |
| 1.3. Synthesis of trisubstituted benzofurans | 第25-27页 |
| 1.4. Benzannulation of 3-Substituted Pyrroles to Indoles | 第27-28页 |
| 1.5. Synthesis of polysubstituted benzene derivatives from precursors such a Nitroalkanes | 第28-31页 |
| 1.5.1. Synthesis of poly-substituted nitrobenzene derivatives | 第28-29页 |
| 1.5.2. Synthesis of symmetrical diarylamines | 第29-30页 |
| 1.5.3. One-pot synthesis of 3,5-alkylated acetophenone and benzoate derivatives via ananionic domino process | 第30-31页 |
| 1.6. Synthesis of Substituted aromatic hydrocarbon | 第31-33页 |
| 1.7. Synthesis of chiral tetrahydronaphthalenes | 第33-34页 |
| 1.8. Synthesis of calamenene sesquiterpenes | 第34-35页 |
| 1.9. Synthesis of six-membered carbo- and heterocyclic compounds | 第35-36页 |
| 1.10. Synthesis substituted aromatic amines | 第36-37页 |
| 1.11. Asymmetric synthesis of biaryls | 第37-38页 |
| 1.12. Dimerization followed by aromatization | 第38-39页 |
| 1.13 -Synthesis of multiply-substituted benzenes via a formal [3+3] cycloadditionapproach | 第39-41页 |
| ChapterⅡ:Synthesis of polysubstituted benzenes via Tandem [3+3] and [3+2+1]Annulation-Aerobic Oxidative Benzannulations | 第41-55页 |
| 2.1. General procedure for the synthesis of α,β-unsatured carbonyl compounds 1 | 第41-42页 |
| 2.2. General procedure for synthesis of 3-benzylidenepentan-2,4-dione lo and ethyl 2-benzyli-dene-3-oxobutanoate 1p | 第42页 |
| 2.3. General procedure for the synthesis of polysubstituted benzene 3 | 第42-43页 |
| 2.4. General procedure by one-pot synthesis of polysubstituted benzene via the [3+2+1]cycloaddition from acetophenone, aldehyde and dimethyl glutaconate | 第43-44页 |
| 2.5. Results and Discussion | 第44-47页 |
| 2.6. Conclusion | 第47-48页 |
| 2.7. Spectrum Data of compounds 3 | 第48-55页 |
| Chapter Ⅲ:Synthesis of polysubstituted benzene derivatives from a-Oxo-ketenedithioacetals with ethyl 4-(S,S-dimethylbromothio)crotonate via [3+3] cycloadditionapproach | 第55-68页 |
| 3.1. General procedure for the synthesis of α-Oxo-ketene dithioacetal 2 | 第55-56页 |
| 3.2. General procedure for synthesis of compounds 3 | 第56-57页 |
| 3.3. General procedure for synthesis of reagent 4 | 第57页 |
| 3.4. General procedure for the synthesis of benzene polysubstituted 5 | 第57-58页 |
| 3.5. Results and Discussion | 第58-60页 |
| 3.6. Conclusion | 第60-61页 |
| 3.7. Spectrum Data of compounds 5 | 第61-68页 |
| References | 第68-77页 |
| Appendix | 第77-112页 |
