| 摘要 | 第1-10页 |
| Abstract | 第10-14页 |
| Part Ⅰ Introduction | 第14-22页 |
| 1. Resonance Rayleigh scattering and its application in analytical chemistry | 第14-16页 |
| ·Light scattering phenomenon | 第14页 |
| ·Rayleigh scattering | 第14-15页 |
| ·Resonance Rayleigh scattering spectrometry and its application in analytica #1 chemistry | 第15-16页 |
| 2. Resonance non-linear scattening and its applications in analytical chemistry | 第16页 |
| 3. Nanoparticles | 第16-18页 |
| 4. Determination of sodium alginate | 第18-19页 |
| 5. Determination of potassium ferrocyanide | 第19-20页 |
| 6. Determination of epinephrine | 第20页 |
| 7. Significance of this paper | 第20-22页 |
| Part Ⅱ Main research work | 第22-84页 |
| Chapter 1.Analytical application of resonance Rayleigh scattering,frequency doublingscattering and second-order scattering spectra for the sodium alginate-CTAB ion-associationnanoparticles system | 第22-32页 |
| 1. Experimental | 第23-24页 |
| ·Reagents | 第23页 |
| ·Apparatus | 第23-24页 |
| ·General procedure | 第24页 |
| 2. Results and discussion | 第24-31页 |
| ·Formation,shape and diameter of SA-CTAB ion-association nanoparticles | 第24-25页 |
| ·RRS,FDS and SOS Spectra | 第25-27页 |
| ·Optimum conditions for the reaction | 第27-31页 |
| 3. Conclusion | 第31-32页 |
| Chapter 2.Resonance Rayleigh scattering spectra of sodium alginate—chitosan ion-associationnanoparticles and its analytical application | 第32-40页 |
| 1. Experimental | 第32-33页 |
| ·Reagents | 第32-33页 |
| ·Apparatus | 第33页 |
| ·General procedure | 第33页 |
| 2. Results and discussion | 第33-39页 |
| ·Formation,shape and diameter of SA-CS nanoparticles | 第33-34页 |
| ·RRS spectra | 第34-35页 |
| ·Optimum conditions for the reaction | 第35-37页 |
| ·Reaction speed and stability of the system | 第37页 |
| ·Sequence of reagents addition | 第37页 |
| ·Relation between RRS intensity and concentration of SA | 第37页 |
| ·Selectivity of the method | 第37-38页 |
| ·Analytical application | 第38-39页 |
| 3. Conclusions | 第39-40页 |
| Chapter 3. Determination of potassium ferrocyanide in food by resonance Rayleigh scattering,frequency doubling scattering and second-order scattering methods based on the formation ofCo_2[Fe(CN)_6] nanoparticles | 第40-54页 |
| 1. Experimental | 第41-42页 |
| ·Reagents | 第41页 |
| ·Apparatus | 第41-42页 |
| ·General procedure | 第42页 |
| 2. Results and discussion | 第42-53页 |
| ·RRS, FDS and SOS spectra | 第42-45页 |
| ·Optimum conditions for the reaction | 第45-46页 |
| ·Effect of ionic strength | 第46-47页 |
| ·Relation between RRS, FDS and SOS intensities and concentrations of potassium ferrocyanide | 第47-49页 |
| ·Composition and formation of Co_2[Fe(CN)_6] nanoparticles | 第49-51页 |
| ·Selectivity of the method | 第51-52页 |
| ·Analytical application | 第52-53页 |
| 3. Conclusions | 第53-54页 |
| Chapter 4. Study on resonance Rayleigh scattering, frequency doubling scattering andsecond-order scattering spectra of Ni_2[Fe(CN)_6] nanoparticles and their analytical applications | 第54-68页 |
| 1. Experimental | 第55-56页 |
| ·Reagents | 第55页 |
| ·Apparatus | 第55页 |
| ·General procedure | 第55-56页 |
| 2. Results and discussion | 第56-66页 |
| ·Composition of the Ni_2[Fe(CN)_6] complex | 第56页 |
| ·Formation, shape and diameter of Ni_2[Fe(CN)_6] nanoparticles | 第56-57页 |
| ·RRS, FDS and SOS spectra | 第57-60页 |
| ·Optimum conditions for the reaction | 第60-61页 |
| ·Reaction speed and stability of the system | 第61页 |
| ·Relation between RRS, FDS and SOS intensities and concentration of potassium ferrocyanide | 第61-64页 |
| ·Selectivity of the method | 第64-65页 |
| ·Analytical application | 第65页 |
| ·Reasons for enhancement of RRS, FDS and SOS | 第65-66页 |
| 3. Conclusions | 第66-68页 |
| Chapter 5. Determination of epinephrine by resonance Rayleigh scattering, frequencydoubling scattering and second-order scattering methods based on the formation ofFe_3[Fe(CN)_6]_2 nanoparticles | 第68-84页 |
| 1. Experimental | 第69-70页 |
| ·Reagents | 第69页 |
| ·Apparatus | 第69页 |
| ·General procedure | 第69-70页 |
| 2. Results and discussion | 第70-83页 |
| ·Absorption spectra | 第70页 |
| ·RRS, FDS and SOS spectra | 第70-73页 |
| ·Optimum conditions for the reaction | 第73-76页 |
| ·Reaction speed and stability of the system | 第76页 |
| ·Effect of ionic strength | 第76-77页 |
| ·Relation between RRS.FDS and SOS intensities and concentrations of EP | 第77-79页 |
| ·Selectivity of the method | 第79-80页 |
| ·Analytical application | 第80-81页 |
| ·Reaction mechanism | 第81-83页 |
| 3. Conclusions | 第83-84页 |
| Conclusions | 第84-86页 |
| References | 第86-102页 |
| 致谢 | 第102-104页 |
| Appendix:Papers published during the graduate | 第104页 |
