| ABSTRACT | 第4-7页 |
| Chapter 1 Introduction | 第11-42页 |
| 1.1 Contaminated land issue | 第11-19页 |
| 1.1.1 Contaminated land issue: size, market, and emerging trends in the USA, Europe Union and China | 第11-16页 |
| 1.1.2 Risk posed by petroleum hydrocarbon contaminated land | 第16-19页 |
| 1.2 Fate and transport of hydrocarbons in soil environments | 第19-21页 |
| 1.3 Fate and transport modeling approaches | 第21-26页 |
| 1.4 Traditional vs Green remediation approaches | 第26-40页 |
| 1.4.1 The application of soil clean up technologies | 第26-33页 |
| 1.4.2 Use of soil ozonation | 第33-36页 |
| 1.4.3 Soil composting | 第36-40页 |
| 1.5 Knowledge gaps, aims and objectives | 第40-42页 |
| Chapter 2 Fate and transport of diesel components in chalk | 第42-70页 |
| 2.1 Introduction | 第42-44页 |
| 2.2 Materials and methods | 第44-49页 |
| 2.2.1 Chalk sample preparation and characterisation | 第44-45页 |
| 2.2.2 Distribution coefficient determination | 第45-46页 |
| 2.2.3 Leaching column test | 第46-47页 |
| 2.2.4 Extraction and analysis of the hydrocarbon fractions | 第47-49页 |
| 2.3 Modeling of petroleum hydrocarbons fate and transport in chalk | 第49-54页 |
| 2.3.1 Mathematical equations | 第49-51页 |
| 2.3.2 Modelling framework and parameters | 第51-54页 |
| 2.4 Results and discussion | 第54-59页 |
| 2.4.1 Identification of alkanes and PAHs in diesel | 第54-55页 |
| 2.4.2 Distribution coefficient | 第55-57页 |
| 2.4.3 Concentration in leachate | 第57页 |
| 2.4.4 Concentration in chalk | 第57-59页 |
| 2.5 Modeling fate and transport of the hydrocarbons | 第59-68页 |
| 2.5.1 Scenario 1: chalk without organic carbon | 第59-61页 |
| 2.5.2 Scenario 2: chalk with 1% organic carbon | 第61-65页 |
| 2.5.3 Monte Carlo analysis results | 第65-66页 |
| 2.5.4 Sensitivity analysis | 第66-68页 |
| 2.6 Conclusion | 第68-70页 |
| Chapter 3 Ozone treatment of contaminated soil with diesel | 第70-95页 |
| 3.1 Introduction | 第70-71页 |
| 3.2 Materials and Methods | 第71-77页 |
| 3.2.1 Sample preparation | 第71-72页 |
| 3.2.2 Experimental setup | 第72-73页 |
| 3.2.3 Analysis method for aldehydes and carboxylic acids | 第73-76页 |
| 3.2.4 Data analysis | 第76页 |
| 3.2.5 Modelling of n-alkanes ozonation framework and parameters | 第76-77页 |
| 3.3 Results and discussion | 第77-93页 |
| 3.3.1 Effect of ozone concentration on n-alkanes and PAHs removal | 第77-81页 |
| 3.3.2 Influence of grain size on the ozonation efficacy | 第81-82页 |
| 3.3.3 Influence of water content | 第82-85页 |
| 3.3.4 Formation of aldehydes during ozonation | 第85-86页 |
| 3.3.5 Formation of carboxylic acids during ozonation | 第86-90页 |
| 3.3.6 Infrared spectrum analysis results | 第90-92页 |
| 3.3.7 Modelling results and discussion | 第92-93页 |
| 3.4 Conclusion | 第93-95页 |
| Chapter 4 Multi factorial analysis of the environmental parameters influencingcrude oil degradation in soil | 第95-110页 |
| 4.1 Introduction | 第95-96页 |
| 4.2 Materials and Methods | 第96-100页 |
| 4.2.1 Sample preparation | 第96-98页 |
| 4.2.2 Statistical analysis | 第98页 |
| 4.2.3 Soil composting modelling framework and parameters | 第98-100页 |
| 4.3 Results and discussion | 第100-109页 |
| 4.3.1 Analysis of n-alkanes and PAHs in crude oil | 第100-101页 |
| 4.3.2 Composition changes of alkanes | 第101-103页 |
| 4.3.3 Composition changes of PAHs | 第103-105页 |
| 4.3.4 Principal component analysis (PCA) of composting variables | 第105-107页 |
| 4.3.5 Modelling results and discussion | 第107-109页 |
| 4.4 Conclusion | 第109-110页 |
| Chapter 5 Energy consumption and air emissions during soil ozonation and soilcompost amendment | 第110-119页 |
| 5.1 Introduction | 第110-111页 |
| 5.2 Site conditions and background | 第111-113页 |
| 5.3 Estimation of energy consumption and GHG emissions | 第113-117页 |
| 5.3.1 SEFA input parameters | 第113-115页 |
| 5.3.2 Results and discussion | 第115-117页 |
| 5.4 Conclusion | 第117-119页 |
| Chapter 6 Conclusions and future works | 第119-123页 |
| 6.1 Conclusions | 第119-121页 |
| 6.2 Recommendations for future work | 第121-123页 |
| References | 第123-136页 |
| Publication, patents and projects participation | 第136-137页 |
| Published papers | 第136页 |
| Patents | 第136页 |
| Projects involved | 第136-137页 |
| Appendix: Chinese Abstract | 第137-144页 |
| Acknowledgement | 第144-145页 |
