| Abstract | 第5-6页 |
| 摘要 | 第7-16页 |
| 1 Literature Review | 第16-49页 |
| 1.1 General Introduction | 第16页 |
| 1.2 Propargylation and Allenylation of (Hetero)aromatic Compounds | 第16-22页 |
| 1.2.1 General Mechanism of Propargylation and Allenylation Reaction via Cross-Coupling Reactions | 第17-18页 |
| 1.2.2 Synthesis of Propargylated/Allenylated Compounds from Propargylic Halidesor Allenylic Halides | 第18-19页 |
| 1.2.3 Synthesis of Propargylated Compounds from Organoboron Reagents | 第19页 |
| 1.2.4 Synthesis of Propargylated/Allenylated Compounds from Organozinc Reagents | 第19-20页 |
| 1.2.5 Synthesis of Propargylated/Allenylated Compounds from Alkynes | 第20-21页 |
| 1.2.6 Synthesis of Propargylated/Allenylated Compounds from Allenyltin Reagents | 第21-22页 |
| 1.3 Allylation of (Hetero)aromatic Compounds | 第22-35页 |
| 1.3.1 Biological Profile of Allylated Compounds | 第22-23页 |
| 1.3.2 Friedel-Crafts Allylation Reaction | 第23-26页 |
| 1.3.3 Transition-Metal-Catalyzed Allylation Reaction | 第26-30页 |
| 1.3.4 Allylation Through Direct C-H Activation | 第30-35页 |
| 1.4 Isomerization of Allylbenzenes into β-Methylstyrenes | 第35-46页 |
| 1.4.1 Biological Profile of β-Methylstyrenes | 第35-36页 |
| 1.4.2 Base-Catalyzed Isomerization of Allylbenzenes into β-Methylstyrenes | 第36-38页 |
| 1.4.3 Transition-Metal-Catalyzed Isomerization of Allylbenzenes | 第38-44页 |
| 1.4.4 Mechanism of Transition-Metal-Catalyzed Isomerization of Allylbenzenes | 第44-46页 |
| 1.5 Topic Selection and Research Motivation | 第46-49页 |
| 2 Palladium-Catalyzed Propargylative and Allenylative Dearomatization of 2-(Chloromethyl)thiophenes: Remarkable Effect of Solvents | 第49-75页 |
| 2.1 Introduction | 第49-50页 |
| 2.2 Experimental Section | 第50-67页 |
| 2.2.1 Materials and Instruments | 第50-52页 |
| 2.2.2 Representative Procedure for Preparation of Starting Materials (2-la)-(2-lo) | 第52-59页 |
| 2.2.3 Representative experimental procedure for synthesis of propargylated products(2-2a)-(2-2o) | 第59页 |
| 2.2.4 Representative experimental procedure for synthesis of allenylated products (2-3a)-(2-3i) | 第59-60页 |
| 2.2.5 Characterization Data for All Products | 第60-67页 |
| 2.3 Results and Discussion | 第67-72页 |
| 2.3.1 Screening the Reaction Conditions | 第67-68页 |
| 2.3.2 Substrate Scope Extension for Propargylation Reaction | 第68-70页 |
| 2.3.3 Substrate Scope Extension for Allenylation | 第70-72页 |
| 2.4 Reaction Mechanism | 第72-74页 |
| 2.5 Summary | 第74-75页 |
| 3 Palladium-Catalyzed Regioselective Allylation of Chloromethyl(hetero)arenes withAllylpinacolborate | 第75-96页 |
| 3.1 Introduction | 第75-76页 |
| 3.2 Experimental Section | 第76-86页 |
| 3.2.1 Materials and Instruments | 第76-77页 |
| 3.2.2 Representative Procedure for Synthesis of Allylated Products (3-2a)-(3-5f) | 第77-78页 |
| 3.2.3 Control Experiments | 第78-79页 |
| 3.2.4 Characterization Data for All Products | 第79-86页 |
| 3.3 Results and Discussion | 第86-93页 |
| 3.3.1 Screening the Reaction Conditions | 第86-87页 |
| 3.3.2 Substrate Scope Extension | 第87-93页 |
| 3.4 Reaction Mechanism | 第93-95页 |
| 3.5 Summary | 第95-96页 |
| 4 Facile Synthesis of β-Methylstyrenes via Palladium-Catalyzed Isomerization ofAllylbenzenes | 第96-109页 |
| 4.1 Introduction | 第96-97页 |
| 4.2 Experimental Section | 第97-102页 |
| 4.2.1 Materials and Instruments | 第97-98页 |
| 4.2.2 Representative Procedure for the Synthesis of Products (4-2a)-(4-2p) | 第98页 |
| 4.2.3 Characterization Data for All Products | 第98-102页 |
| 4.3 Results and Discussion | 第102-106页 |
| 4.3.1 Screening the Conditions | 第102-103页 |
| 4.3.2 Substrate Scope Extension | 第103-106页 |
| 4.4 Reaction Mechanism | 第106-107页 |
| 4.5 Summary | 第107-109页 |
| 5 Conclusion | 第109-110页 |
| 6 Innovation Points and Future Horizons | 第110-112页 |
| 6.1 Innovation Points | 第110页 |
| 6.2 Future Horizons | 第110-112页 |
| References | 第112-129页 |
| Copies of NMR Spectra of Some Selected Compounds | 第129-143页 |
| Published Academic Papers During PhD Period | 第143-144页 |
| Acknowledgement | 第144-145页 |
| About the Author | 第145-147页 |
