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催化剂电子结构对电化学催化性能的影响

摘要第5-7页
ABSTRACT第7-8页
Abbreviations and symbols第12-14页
CHAPTER 01 INTRODUCTION第14-64页
    1.1 Green energy第16-20页
    1.2 EFC technological perspective第20-23页
    1.3 Electrochemical catalyst第23-35页
        1.3.1 Adsorption第25-28页
        1.3.2 The Electrical Double Layer第28-32页
        1.3.3 Kinetics(brief description of Butler Volmer equation)第32-35页
    1.4 The atomic structure of metal surface第35-39页
        1.4.1 The miller indices and notation system第36-39页
    1.5 Electrochemical Practices第39-57页
        1.5.1 Mass transport第42-57页
            1.5.1.1 Diffusion in chronoamperometry第44-46页
            1.5.1.2 Diffusion in CV第46-51页
            1.5.1.3 Role of Hydrodynamic in Voltammetry第51-57页
                1.5.1.3.1 Rotating disc electrode(RDE)第52-55页
                1.5.1.3.2 Rotating Ring Disc Electrode(RRDE)第55-57页
    1.6 References第57-64页
CHAPTER 02 BOOSTING FUEL CELL CATALYSIS BY SURFACE DOPING OF W ON PdNANOCUBES第64-92页
    2.1 Introduction第65-68页
    2.2 Experimental section第68-72页
        2.2.1 Chemicals第68页
        2.2.2 Nanoparticle synthesis第68-69页
            2.2.2.1 Synthesis of Pd nanocubes (NCs)第68-69页
            2.2.2.2 Synthesis of W_Pd nanocubes with different W composition第69页
        2.2.3 Physicochemical characterization第69-70页
            2.2.3.1 Transmission Electron Microscopy (TEM)第69页
            2.2.3.2 High Resolution Transmission Electron Microscopy(HR-TEM)第69-70页
            2.2.3.3 X-ray Photoelectron Spectroscopy (XPS)第70页
            2.2.3.4 X-ray Diffraction Spectroscopy (XRD)第70页
            2.2.3.5 Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES)第70页
        2.2.4 Electrochemical characterization第70-72页
            2.2.4.1 Cyclic voltammetry第71页
            2.2.4.2 Chronoamperometry第71-72页
    2.3 Physical properties of the catalyst第72-79页
        2.3.1 Transmission Electron Microscopy第72-74页
        2.3.2 High Resolution Transmission Electron Microscopy(HR-TEM)第74-76页
        2.3.3 X-ray Photoelectron Spectroscopy (XPS)第76-78页
        2.3.4 X-ray Diffraction Spectroscopy (XRD)第78-79页
    2.4 Electrochemical properties of the catalyst第79-86页
        2.4.1 The Oxygen Reduction Reaction (ORR)第80-84页
        2.4.2 Ethanol Oxidation Reaction(EOR)第84-86页
    2.5 Conclusion第86-87页
    2.6 References第87-92页
CHAPTER 03 CARBON DIOXIDE ELECTROCHEMICAL REDUCTION OVER METAL ANDMETAL FREE NANOSTRUCTURES: RECENT PROGRESS AND FUTUREPERSPECTIVE第92-132页
    3.1 Scope the review第93页
    3.2 Background第93-99页
    3.3 Recent Progress in Carbon Dioxide Electrochemical Reduction over Metal andmetal free nanocrystals第99-117页
        3.3.1 Size effect第101-102页
        3.3.2 Crystal planes effect第102-104页
        3.3.3 Oxide-Derived metal catalysts第104-107页
        3.3.4 Metal-Oxide Interface and Grain Boundary(MOI & GB)第107-110页
        3.3.5 Metal alloy第110-115页
        3.3.6 Metal free catalyst(MFC)第115-117页
    3.4 Conclusion and Future Perspective第117-119页
    3.5 References第119-132页
CHAPTER 04 BOOSTING OER ACTIVITY OF NiOOH SHEETS BY Fe DOPING第132-146页
    4.1 Introduction第133-134页
    4.2 Experimental第134-143页
        4.2.1 Chemicals第134-135页
        4.2.2 Synthesis of NiOOH and Fe doped NiOOH sheets第135-136页
        4.2.3 Characterization第136-139页
            4.2.3.1 TEM & SEM第136-137页
            4.2.3.2 ICP-AES第137页
            4.2.3.3 EDX第137页
            4.2.3.4 XPS第137-138页
            4.2.3.5 XRD第138-139页
        4.2.4 Electrochemical analysis第139-143页
    4.3 Conclusions第143页
    4.4 References第143-146页
ACKNOWLEDGEMENT第146-147页
LIST OF PUBLICATIONS第147页

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