英文摘要 | 第1-6页 |
中文摘要 | 第6-8页 |
Part Ⅰ Progress in Synthesis, Curing, Properties, and Application of Bisphenol-S Epoxy Resin | 第8-20页 |
1 Synthesis of BPSER and Its Derivaives | 第8-11页 |
1.1 Preparation of Low Molecular Weight BPSER | 第9页 |
1.2 Preparation of High Molecular Weight BPSER | 第9-10页 |
1.3 Preparation of BPSER Derivatives | 第10-11页 |
2 Curing Mechanism | 第11-14页 |
2.1 Two General Kinetic Models | 第11-12页 |
2.2 Auocatalytic Mechanism | 第12-13页 |
2.3 Diffusion Stage | 第13-14页 |
3 Properties and Application | 第14-20页 |
3.1 Thermal Properties | 第14页 |
3.2 Applied for Adhesive | 第14-15页 |
3.3 Applied for Pulverized Coating | 第15-20页 |
Part Ⅱ Kinetics of Epoxy Resin Formation from Bisphenol-A, Bisphenol-S, and Epichlorohydrin | 第20-29页 |
1 Experimental | 第20-21页 |
2 Results and Discussion | 第21-27页 |
2.1 Kinetics of Reaction of ECH with BPA and BPS | 第23-25页 |
2.2 Kinetics of Reaction of Phenol with EG in Oligomer | 第25-27页 |
3 Conclusions | 第27-29页 |
Part Ⅲ Curing Kinetics of Bisphenol-S Epoxy Resin and Hardener System | 第29-46页 |
1 Experimental | 第29-31页 |
2 Results and Discussion | 第31-46页 |
2.1 IR Analysis for BPSER/DDS and BPSER/phthalic anhydride System | 第31-32页 |
2.2 Autocatalytic Kinetics Model | 第32-33页 |
2.3 Curing Kinetics Behavior for Amines as Hardener | 第33-39页 |
2.4 Curing Kinetics Behavior for Phthalic Anhydrides as Hardener | 第39-43页 |
2.5 Molecular Mechanism for BPSER/amine Curing System | 第43-44页 |
2.6 Molecular Mechanism for BPSER/anhydride Curing System | 第44-46页 |
Part Ⅳ Thermal Characterization of BPSER/hardener Curing System | 第46-60页 |
1 Experimental | 第46-47页 |
2 Results and Discussion | 第47-60页 |
2.1 Isothermal curing by TBA for BPSER/DDM System | 第47-48页 |
2.2 T_g Value and Curing Process | 第48-54页 |
2.2.1 T_g of BPSER/amine System with Cure Degrees | 第48-51页 |
2.2.2 T_g of BPSER/anhydride System with Cure Degrees | 第51-53页 |
2.2.3 Curing Process of BPSER Modified BPAER/DDM System | 第53-54页 |
2.3 Thermal Degradation Kinetics | 第54-60页 |
2.3.1 BPSER/amine Cured System | 第54-56页 |
2.3.2 BPSER/anhydride Cured System | 第56-60页 |