| Acknowledgement | 第1-11页 |
| Abstract | 第11-16页 |
| 摘要 | 第16-19页 |
| List of Tables | 第19-20页 |
| List of Figures | 第20-23页 |
| Nomenclature | 第23-28页 |
| Terminology | 第28-30页 |
| Chapter 1 Introduction | 第30-44页 |
| ·Overview of Researches on Reactive Distillation Columns(RDCs) | 第30-39页 |
| ·Studies on Reaction Kinetics and Thermodynamics for RDCs | 第32-33页 |
| ·Steady-State and Dynamic Modeling of RDCs | 第33-35页 |
| ·Synthesis and Design of RDCs | 第35-36页 |
| ·Dynamics and Control of RDCs | 第36-38页 |
| ·Industrial Applications of RDCs | 第38-39页 |
| ·Motivation of This Dissertation | 第39-41页 |
| ·Outline of This Dissertation | 第41-44页 |
| Chapter 2 Proposal of a Systematic Strategy for RDCs with ExternalRecycle | 第44-54页 |
| ·Structural Limitations of RDCs | 第44-48页 |
| ·External Recycle and its Potential Efiects to RDCs | 第48页 |
| ·A Systematic Strategy for Developing RDCs with External Recycle | 第48-53页 |
| ·Category Ⅰ:a_c>a_A>a_B>a_D | 第49-50页 |
| ·Category Ⅱ:a_A>a_B>a_C>a_D and a_C>a_D>a_A>a_B | 第50页 |
| ·Category Ⅲ:a_A>a_C>a_B>a_D and a_C>a_A>a_D>a_B | 第50-52页 |
| ·Category Ⅳ:a_A>a_C>a_D>_B | 第52-53页 |
| ·Summary | 第53-54页 |
| Chapter 3 Steady-State and Dynamic Modeling of RDCs withExternal Recycle | 第54-72页 |
| ·Derivation of Steady-State Model | 第54-65页 |
| ·Solving Steady-State Model with Mathematica | 第62-63页 |
| ·Solving Steady-State Model with Aspen Plus | 第63页 |
| ·Evaluation of Steady-State Model | 第63-65页 |
| ·Derivation of Dynamic Model | 第65-70页 |
| ·Solving Dynamic Model with Mathematica | 第69页 |
| ·Solving Dynamic Model with Aspen Plus | 第69页 |
| ·Evaluation of Dynamic Model | 第69-70页 |
| ·Summary | 第70-72页 |
| Chapter 4 Theoretical Analysis of the Impact of External Recycle | 第72-78页 |
| ·Category Ⅳ:a_A>a_C>a_D>a_B | 第72-74页 |
| ·Principle for Theoretical Analysis for Category IV | 第72页 |
| ·Impact of External Recycle for Category IV | 第72-74页 |
| ·Category Ⅲ:a_A>a_C>a_B>a_D and a_C>a_A>a_D>a_B | 第74-77页 |
| ·Principle for Theoretical Analysis for Category III | 第74-75页 |
| ·Impact of External Recycle for Category III | 第75-77页 |
| ·Summary | 第77-78页 |
| Chapter 5 Evaluation of RDCs with Top-Bottom External Recycle(RDC-TBER) (a_A>a_C>a_D>a_B) | 第78-102页 |
| ·Principle for Evaluating RDC-TBER | 第78-80页 |
| ·Synthesis and Design of RDC-TBER | 第80页 |
| ·A Generalized Procedure for Process Synthesis and Design | 第80-82页 |
| ·Example Ⅰ:Separation of a Hypothetical Exothermic Quaternary Reaction | 第82-88页 |
| ·Example Ⅱ:Separation of a Hypothetical Endothermic Quaternary Reaction | 第88-91页 |
| ·Example Ⅲ:Separation of the Esterification of Lactic Acid with Methanol | 第91-96页 |
| ·Example Ⅳ:Separation of the Esterification of Plamitic Acid with Isopropanol | 第96-100页 |
| ·Summary | 第100-102页 |
| Chapter 6 Evaluation of RDCs with Two External Recycles(RDC-TER) (a_A>a_C>_D>a_B) | 第102-112页 |
| ·Principle for Evaluating RDC-TER | 第102-103页 |
| ·Synthesis and Design of RDC-TER | 第103-104页 |
| ·A Generalized Procedure for Process Synthesis and Design | 第104-106页 |
| ·Example Ⅰ:Separation of a Hypothetical Exothermic Quaternary Reaction | 第106-108页 |
| ·Example Ⅱ:Separation of a Hypothetical Endothermic Quaternary Reaction | 第108-111页 |
| ·Summary | 第111-112页 |
| Chapter 7 Evaluation of RDCs with External Recycles fromTop/Bottom to a Certain Stage of Reactive Section(RDC-ERTR/RDC-ERBR) (a_A>a_C>a_B>a_D and a_C>a_A>a_D>a_B) | 第112-125页 |
| ·Principle for Evaluating RDC-ERTR/RDC-ERBR | 第112-113页 |
| ·Synthesis and Design of RDC-ERTR/RDC-ERBR | 第113-114页 |
| ·A Generalized Procedure for Process Synthesis and Design | 第114-115页 |
| ·Example Ⅰ:Separation of a Hypothetical Exothermic Quaternary Reaction | 第115-118页 |
| ·Example Ⅱ:Separation of the Esterification of Acetate Acid with Methanol | 第118-121页 |
| ·Example Ⅲ:Separation of the Transterification of Butyl Acetate with Ethanol | 第121-124页 |
| ·Summary | 第124-125页 |
| Chapter 8 Dynamics and Control of RDC-TBER(a_A>a_C>a_D>a_B) | 第125-135页 |
| ·Steady-State Behaviors Loop Dynamic Behaviors of RDC-TBER | 第125-126页 |
| ·Open-Loop Dynamic Behaviors of RDC-TBER | 第126-127页 |
| ·Synthesis and Design of Decentralized Control Systems | 第127-128页 |
| ·Closed-Loop Control of RDC-TBER | 第128-134页 |
| ·Summary | 第134-135页 |
| Chapter 9 Synthesis and Design of Plant-Wide Flow-Sheet Involvinga Reactive Distillation Column with Top-Bottom External Recycle(RDC-TBER Flow-Sheet) | 第135-147页 |
| ·Principle for Developing RDC-TBER Flow-Sheet | 第135页 |
| ·Example Ⅰ:Separation of Adipic Acid Esterification | 第135-141页 |
| ·Conventional RDC (CRDC) Flow-Sheet | 第137页 |
| ·RDC-TBER Flow-Sheet | 第137-138页 |
| ·Comparison between CRDC Flow-Sheet and RDC-TBER Flow-Sheet | 第138-141页 |
| ·Example Ⅱ:Separation of Glutaric Acid Esterification | 第141-146页 |
| ·CRDC Flow-Sheet | 第142页 |
| ·RDC-TBER Flow-Sheet | 第142-143页 |
| ·Comparison between CRDC Flow-Sheet and RDC-TBER Flow-Sheet | 第143-146页 |
| ·Summary | 第146-147页 |
| Chapter 10 Plant-Wide Control of RDC-TBER Flow-Sheet | 第147-153页 |
| ·Problem Description:Separation of a Hypothetical Exothermic Quaternary Reaction | 第147页 |
| ·Synthesis and Design of Decentralized Control Systems | 第147-149页 |
| ·Closed-Loop Control of RDC-TBER Flow-Sheet | 第149-152页 |
| ·Summary | 第152-153页 |
| Chapter 11 Conclusions and Recommendations | 第153-157页 |
| ·Main Conclusions of This Dissertation | 第153-155页 |
| ·Main Contributions of This Dissertation | 第155-156页 |
| ·Future Researches | 第156-157页 |
| Appendix | 第157-159页 |
| Bibliography | 第159-169页 |
| Papers and Patents Related to the Dissertation | 第169-171页 |
| Research Projects | 第171页 |
| Rewards Received | 第171-173页 |
| Vitae of Author | 第173-177页 |
| Vitae of Advisor | 第177-179页 |
| 附件 | 第179-180页 |
