| Abstract | 第4-5页 |
| 摘要 | 第7-14页 |
| List of compounds in this thesis | 第14-23页 |
| 1 Introduction | 第23-51页 |
| 1.1 Brief Background of Metal-organic Coordination Polymers | 第23-29页 |
| 1.1.1 Design | 第24-25页 |
| 1.1.2 Synthesis | 第25-27页 |
| 1.1.3 Secondary Building units (SBUs) in metal organic frameworks | 第27页 |
| 1.1.4 Dimensionality | 第27-29页 |
| 1.1.5 Potential Applications of Metal organic Coordination Polymers | 第29页 |
| 1.2 Recent research progress on luminescent metal organic coordination polymers | 第29-32页 |
| 1.3 Luminescence phenomena of metal-organic coordination polymers | 第32-34页 |
| 1.4 Luminescence sensing mechanism of metal organic coordination polymers | 第34-36页 |
| 1.5 Lanthanide coordination polymers | 第36-39页 |
| 1.6 Lanthanide metal organic frameworks as sensors | 第39-48页 |
| 1.6.1 Sensing metal ions | 第42-44页 |
| 1.6.2 Sensing nitroaromatic compounds | 第44-48页 |
| 1.7 Motivation, Significance and Design of this Thesis | 第48-51页 |
| 2 Red luminescence of europium (Ⅲ) coordination polymers and their sensing towards4 -nitrophenol and Fe~(3+)ion | 第51-77页 |
| 2.1 Introduction | 第51-52页 |
| 2.2 Experimental Section | 第52-55页 |
| 2.2.1 Materials and general methods | 第52-53页 |
| 2.2.2 Synthesis of Eu(H_2O)_5(BTEC)_2·[H(C_5H_6N_2)]·3H_2O(1) | 第53页 |
| 2.2.3 Synthesis of [Eu(BPDC)_2]·(CH_3)_2NH_2(2) | 第53页 |
| 2.2.4 X-ray crystallography | 第53-54页 |
| 2.2.5 Luminescent measurements | 第54-55页 |
| 2.3 Structural characterization of Eu-based coordination polymers 1 and 2 | 第55-58页 |
| 2.3.1 Structure determination of compound 1 | 第55-56页 |
| 2.3.2 Structure determination of compound 2 | 第56-58页 |
| 2.4 Luminescent properties of Eu-coordination polymers 1 and 2 | 第58-59页 |
| 2.5 Eu-based coordination polymers as sensors for metal ions and nitroaromaatics(NACs) | 第59-70页 |
| 2.5.1 Sensing metal ions | 第59-65页 |
| 2.5.2 Sensing nitroaromatic compounds | 第65-70页 |
| 2.6 Possible sensing mechanisms of compounds 1 and 2 towards 4-nitrophenl andFe~(3+)ion | 第70-75页 |
| 2.7 Luminescent test papers based on compounds 1 and 2 | 第75-76页 |
| 2.8 Brief Summary | 第76-77页 |
| 3 Green Luminescence of Terbium (Ⅲ) Coordination Polymers and their sensingtowards 4-nitrophenol and Fe~(3+)ion | 第77-107页 |
| 3.1 Introduction | 第77-78页 |
| 3.2 Experimental Section | 第78-81页 |
| 3.2.1 Materials and Methods | 第78-79页 |
| 3.2.2 Synthesis of Tb(BTEC)_(0.5)(HCOO)(H_2O)_2(3) | 第79页 |
| 3.2.3 Synthesis of [Tb(H_2O)_5(BTEC)]·[H(C_5H_6N_2)]·3H_2O(4) | 第79页 |
| 3.2.4 X-ray crystallography | 第79-80页 |
| 3.2.5 Luminescent measurements | 第80-81页 |
| 3.3 Structural Characterization of Tb-based coordination polymers 3 and 4 | 第81-84页 |
| 3.3.1 Structure determination of compound 3 | 第81-83页 |
| 3.3.2 Structure determination of compound 4 | 第83-84页 |
| 3.4 Luminescent Properties of Tb-Coordination Polymers 3 and 4 | 第84-87页 |
| 3.5 Tb-based coordination polymers as sensors for metal ions and nitroaromaatics(NACs) | 第87-96页 |
| 3.5.1 sensing nitroaromatic compounds | 第87-91页 |
| 3.5.2 sensing metal ions | 第91-96页 |
| 3.6 Possible Sensing Mechanisms based on Compounds 3 and 4 | 第96-101页 |
| 3.6.1 Sensing of Compound 3 Towards 4-nitrophenol and Fe~(3+) | 第96-100页 |
| 3.6.2 Sensing of Compound 4 Towards 4-nitrophenol and Fe~(3+)ion | 第100-101页 |
| 3.7 Luminescent test papers based on compounds 3 and 4 | 第101-106页 |
| 3.8 Brief Summary | 第106-107页 |
| 4 A water stable dual-channel luminescence sensor for UO_2~(2+) ion based on an anionicterbium(Ⅲ) metal-organic framework | 第107-123页 |
| 4.1 Introduction | 第107-108页 |
| 4.2 Experimental Section | 第108-110页 |
| 4.2.1 Materials and general methods | 第108-109页 |
| 4.2.2 Synthesis of [Tb(BPDC)_2]·(CH_3)_2NH_2 (5) | 第109页 |
| 4.2.3 Single-crystal structure determination | 第109-110页 |
| 4.2.4 Luminescent measurements | 第110页 |
| 4.3 Structural characterization of compound 5 | 第110-114页 |
| 4.3.1 Structure Determination of compound 5 | 第110-114页 |
| 4.4 Luminescent properties of compound 5 | 第114-115页 |
| 4.5 Sensing properties of compound 5 towards to UO_2~(2+)ion | 第115-118页 |
| 4.6 Possible sensing mechanism of compound 5 towards to UO_2~(2+)ion | 第118-122页 |
| 4.7 Luminescent test papers based on compound 5 | 第122页 |
| 4.8 Brief Summary | 第122-123页 |
| 5 Conclusions and Outlook | 第123-128页 |
| 5.1 Summary | 第123-126页 |
| 5.2 Abstract of Innovation Points | 第126-127页 |
| 5.3 Outlook | 第127-128页 |
| References | 第128-148页 |
| Appendix A Selected bond lengths (A) and angles for 1-5 | 第148-152页 |
| Published Academic Thesis during PhD Period | 第152-154页 |
| Acknowledgement | 第154-156页 |
| About the Author | 第156-158页 |
