| Abstract in Chinese | 第1-18页 |
| Abstract in English | 第18-21页 |
| Chapter 1 Introduction | 第21-65页 |
| ·Introduction of lithium ion battery in brief | 第22-24页 |
| ·Historical developments of lithium ion battery | 第22-23页 |
| ·Working principle and characteristic of lithium ion battery | 第23-24页 |
| ·Cathode materials | 第24-29页 |
| ·Layered LiMO_2 (M=Co, Ni, Mn, V) | 第25-26页 |
| ·Spinel LiMn_2O_4 | 第26-27页 |
| ·Olivine polyanion compounds | 第27-28页 |
| ·V_2O_5 | 第28-29页 |
| ·Anode materials | 第29-37页 |
| ·Lithium metal | 第30页 |
| ·Carbonaceous materials | 第30-31页 |
| ·Lithium alloys | 第31-34页 |
| ·Sn-based binary composition anodes | 第32-33页 |
| ·Sn-based ternary composition anodes | 第33-34页 |
| ·Transition metal oxide anodes | 第34-37页 |
| ·Transition metal salt anodes | 第34-35页 |
| ·Transition metal oxide anodes | 第35-37页 |
| ·Electrolyte | 第37-38页 |
| ·Electrode/electrolyte interface of lithium ion battery | 第38-43页 |
| ·The stability and reactions of nonaqueous interface | 第38-39页 |
| ·Anode/electrolyte interface | 第39-43页 |
| ·Interface of lithium/electrolyte | 第39-40页 |
| ·Interface of carbonaceous anode/electrolyte | 第40-42页 |
| ·Interface of Sn-based anode /electrolyte | 第42-43页 |
| ·Cathode/electrolyte interface | 第43页 |
| ·Spectroscopic techniques for lithium ion battery research | 第43-46页 |
| ·FTIRS studies in lithium ion battery | 第44-45页 |
| ·XPS studies of lithium ion battery | 第45页 |
| ·EQCM studies of lithium ion battery | 第45-46页 |
| ·Objectives and contents of the present thesis | 第46-47页 |
| Reference | 第47-65页 |
| Chapter 2 Instruments and experimental methods | 第65-77页 |
| ·Main reagents and materials | 第65页 |
| ·Fabrication of electrodes | 第65-68页 |
| ·Preparation of Sn and Sn-Co alloy thin film anodes by electroplating | 第65-67页 |
| ·Preparation of graphite thin film anode by spin coating | 第67页 |
| ·Preparation of Cr_2O_3, Cr_2S_3 and V_2O_5 films by thermal treatment | 第67-68页 |
| ·Instruments and experimental methods | 第68-76页 |
| ·Fourier transform infrared spectroscopy (FTIRS) | 第68-70页 |
| ·Electrochemical in situ microscope FTIRS (In situ MFTIRS) | 第68-69页 |
| ·Ex situ microscope FTIRS (Ex situ MFTIRS) | 第69-70页 |
| ·Polarization modulation infrared reflection absorption spectroscopy(PM-IRRAS) | 第70页 |
| ·Electrochemical quartz crystal microbalance (EQCM) | 第70-72页 |
| ·X-ray photoelectron spectroscopy (XPS) | 第72页 |
| ·Time-of-flight secondary ion mass spectrometry (ToF-SIMS) | 第72-73页 |
| ·Electrochemical methods | 第73-76页 |
| ·Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) | 第73-75页 |
| ·Galvanostatic charge-discharge cycling | 第75-76页 |
| ·Other experimental conditions | 第76页 |
| References | 第76-77页 |
| Chapter 3 Studies of the interfacial properties of electroplated Sn thin film electrode/electrolyte using in situ MFTIRS and EQCM | 第77-101页 |
| ·Introduction | 第77-78页 |
| ·Preparation of Sn thin film anodes | 第78-79页 |
| ·Electrochemical performances of Sn thin film anode | 第79-82页 |
| ·CV properties of Sn thin film anode | 第79-80页 |
| ·Charging and discharge properties of Sn thin film anode | 第80-82页 |
| ·Results of EQCM studies | 第82-87页 |
| ·EQCM studies of the initial negative going potential scan | 第82-85页 |
| ·EQCM studies of the first four cycles | 第85-87页 |
| ·Results of in situ MFTIRS studies | 第87-97页 |
| ·Comprehensive sets of in situ MFTIR spectra of Sn thin film anode | 第87-88页 |
| ·In situ MFTIR spectra of (de)lithiation process of Sn thin film anode | 第88-93页 |
| ·In situ MFTIRS of Cu electrode and transmission FTIRS of electrolyte with different concentration of LiPF_6 | 第93-96页 |
| ·In situ MFTIR spectra during reduction of electrolyte on Sn thin film anode | 第96-97页 |
| ·Summary | 第97-98页 |
| References | 第98-101页 |
| Chapter 4 Interfical reactions of Sn-Co and graphite film anodes investigated by MFTIRS | 第101-119页 |
| ·Introduction | 第101-102页 |
| ·Preparation and characterization of Sn-Co and graphite film anodes | 第102-104页 |
| ·preparation of Sn-Co thin film electrode by electroplating | 第102-103页 |
| ·Preparation of graphite film electrode by spin coating technique | 第103-104页 |
| ·MFTIRS studies of Sn-Co thin film anode | 第104-110页 |
| ·CV properties of Sn-Co thin film anode | 第104-105页 |
| ·Charge and discharge properties of Sn-Co thin film electrode | 第105-106页 |
| ·In situ MFTIR spectra of (de)lithiation process on Sn-Co alloy anode | 第106-109页 |
| ·Ex situ MFTIR spectra recorded on a cycled Sn-Co alloy anode | 第109-110页 |
| ·MFTIRS studies of graphite film anode | 第110-115页 |
| ·CV studies of graphite film anode | 第110-111页 |
| ·Characterization of the SEI layer by EIS and ex situ MFTIRS | 第111-113页 |
| ·In situ MFTIR spectra recorded on graphite film anode | 第113-115页 |
| ·Summery | 第115-116页 |
| References | 第116-119页 |
| Chapter 5 XPS, ToF-SIMS and PM-IRRAS studies of Cr_2O_3 thin film material as anode of lithium ion battery | 第119-147页 |
| ·Introduction | 第119-120页 |
| ·Preparation of Cr_2O_3 thin film electrodes | 第120-121页 |
| ·Characterization of pristine Cr_2O_3 thin films | 第121-126页 |
| ·XPS studies of pristine Cr_2O_3 thin films | 第121-124页 |
| ·NRA characterization of pristine Cr_2O_3 thin films | 第124-126页 |
| ·Electrochemical performance | 第126-129页 |
| ·CV properties of Cr_2O_3 thin film anodes | 第126页 |
| ·Charge and discharge properties of Cr_2O_3 thin film anodes | 第126-129页 |
| ·XPS characterization of (de)lithiated Cr_2O_3(b)/Cr #1o9 | 第129-132页 |
| ·PM-IRRAS studies of pristine and (de)lithiated Cr_2O_3(b)/Cr | 第132-134页 |
| ·ToF-SIMS depth profile analyses on pristine and (de)lithiated Cr_2O_3(b)/Cr | 第134-142页 |
| ·ToF-SIMS depth profile analyses on pristine Cr_2O_3(b)/Cr area | 第134-135页 |
| ·ToF-SIMS depth profile analyses on lithiated Cr_2O_3(b)/Cr sample | 第135-137页 |
| ·ToF-SIMS depth profile analyses on delithiated Cr2O3(b)/Cr sample | 第137-142页 |
| ·Summary | 第142-143页 |
| References | 第143-147页 |
| Chapter 6 Studies of Cr_2S_3 film as anode and V_2O_5 thin film as cathode for lithium ion battery | 第147-170页 |
| ·Introduction | 第147-148页 |
| ·Preparation and XPS characterization of Cr_2S_3 film | 第148-152页 |
| ·Electrochemical properties of Cr_2S_3 film | 第152-153页 |
| ·XPS studies of electrochemically treated Cr_2S_3 film | 第153-156页 |
| ·Preparation of nanostructured V_2O_5 thin film and XPS analysis | 第156-158页 |
| ·Preparation of nanostructured V_2O_5 thin film by thermal oxidation | 第156页 |
| ·XPS of nanostructured V_2O_5 thin film | 第156-158页 |
| ·Electrochemical properties of V_2O_5 thin film | 第158-162页 |
| ·XPS and PM-IRRAs characterizations of a cycled V_2O_5 thin film | 第162-165页 |
| ·XPS characterization | 第162-163页 |
| ·PM-IRRAS characterization | 第163-165页 |
| ·Summary | 第165-166页 |
| References | 第166-170页 |
| Conclusions and expectation | 第170-176页 |
| A list of publication | 第176-180页 |
| Acknowledgements | 第180-181页 |
