| 摘要 | 第1-7页 |
| Abstract | 第7-9页 |
| Part I Introduction | 第9-25页 |
| 1. Introduction of Prussian blue and its analogue | 第9-13页 |
| ·Introduction | 第9页 |
| ·Methods of immobilization PB or PBA on the electrode | 第9-10页 |
| ·pH stability of PB and its analogue | 第10-11页 |
| ·Application of PB and its analogue in sensors | 第11-13页 |
| 2. Introduction of sugars | 第13页 |
| 3. Introduction of hydrogen peroxide | 第13-14页 |
| 4. References | 第14-25页 |
| Part II Main research works | 第25-69页 |
| Chapter 1. Electrochemical recognition for sugars on the chitosan-poly(diallyldimethylammonium chloride)-Prussian blue /nano-Au/4-mercaptophenylboronic acid modified glassy carbon electrode | 第25-41页 |
| 1. Introduction | 第25-26页 |
| 2. Experimental section | 第26-28页 |
| ·Reagents | 第26页 |
| ·Apparatus | 第26页 |
| ·Synthesis of PB nanoparticles protected by CS and PDDA | 第26-27页 |
| ·Preparation of colloidal gold | 第27页 |
| ·Fabrication of the modified electrode | 第27-28页 |
| 3. Results and discussion | 第28-37页 |
| ·UV-vis absorption spectra and TEM characterizations of CS-PDDA-PB | 第28-29页 |
| ·Electrochemical characteristics of the self.assembled electrode | 第29-34页 |
| ·Electrochemical behavior of the self-assembled electrode towards sugars | 第34-37页 |
| 4. Conclusions | 第37页 |
| 5. References | 第37-41页 |
| Chapter 2.Multilayer structured amperometric biosensor based on the self-assembled technique for recognition of sugars | 第41-55页 |
| 1. Introduction | 第41-42页 |
| 2. Experimental section | 第42-44页 |
| ·Reagents | 第42页 |
| ·Apparatus | 第42页 |
| ·Synthesis of PB nanoparticles protected by CS and PDDA | 第42-43页 |
| ·Fabrication of the modified electrode | 第43-44页 |
| 3. Results and discussion | 第44-52页 |
| ·TEM characterization of CS-PDDA-PB nanoparticles | 第44页 |
| ·Electrochemical characteristics of the GC/CS-PDDA-nano-PB/nano-Au/Cys/Glu/APBA electrode | 第44-49页 |
| ·Electrochemical behavior of the GC/CS-PDDA-nano-PB/nano-Au/ Cys/Glu/APBA electrode towards sugars | 第49-52页 |
| 4. Conclusions | 第52页 |
| 5. References | 第52-55页 |
| Chapter 3. A new material based on nanostructured Prussian blue analogue film doped with Ce(III) for development of hydrogen peroxide sensor | 第55-69页 |
| 1. Introduction | 第55-56页 |
| 2. Experimental section | 第56-57页 |
| ·Reagents | 第56页 |
| ·Apparatus | 第56页 |
| ·Synthesis of PB analogue nanoparticles protected by CS and PDDA | 第56-57页 |
| ·Fabrication of the modified electrode | 第57页 |
| 3. Results and discussion | 第57-64页 |
| ·TEM, UV-vis absorption spectra and RRS spectra characteristics of CeHCF nanoparticles protected by CS and PDDA | 第57-59页 |
| ·Cyclic voltammetry behavior of the CS-PDDA-CeHCF nanoparticles modified glassy carbon electrode | 第59-62页 |
| ·Electrocatalytic reduction of H2O2 at the CS-PDDA-CeHCF nanoparticles modified glassy carbon electrode | 第62-64页 |
| 4. Conclusions | 第64页 |
| 5. References | 第64-69页 |
| Conclusions | 第69-71页 |
| 致谢 | 第71-73页 |
| Appendix:Papers published during the graduate | 第73页 |
