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混合型环磷腈聚合物的制备新方法及其化学机理和性能研究

ABSTRACT第7-9页
摘要第10-15页
ABBREVIATIONS第15-21页
Chapter 1 Introduction to Polyphosphazene第21-69页
    1.0 Introduction第21-22页
    1.1. POLYPHOSPHAZENES第22页
    1.2. HISTORY OF POLYPHOSPHAZENES第22-23页
    1.3. TYPES OF POLYPHOSPHAZENE COMPOUNDS第23-31页
        1.3.1. Cyclomatrix types of polyphosphazene compounds第24-29页
            1.3.1.1. Electronic structure of small molecule phosphazene第26-29页
        1.3.2. LINEAR POLYPHOSPHAZENES第29-31页
    1.4. MECHANISMS OF SUBSTITUTION AND REACTION PATTERNS第31-33页
        1.4.1. Pattern of Halogen Replacement第31-33页
    1.5. SYNTHESIS OF MIXED-SUBSTITUENT POLYPHOSPHAZENES第33-35页
        1.5.1. Different nucleophiles for halogen replacement第34-35页
    1.6. ORGANOMETALLIC POLYPHOSPHAZENES第35-40页
    1.7. VARIATION IN POLYPHOSPHAZENES ARCHITECTURE第40-44页
        1.7.1. Polymer based on chain第40-41页
        1.7.2. Macrocyclic polyphosphazenes第41-42页
        1.7.3. Cyclolinear and cyclomatrix polymers第42-43页
        1.7.4. Comb, Branched and Dendritic第43页
        1.7.5. Cross-linked structures and their uses第43-44页
        1.7.6. Organic polymers with phosphazene groups (hybrid polymerarchitectures)第44页
    1.8. PROPERTIES AND APPLICATIONS OF POLYPHOSPHAZENES第44-53页
        1.8.1. Applications of phosphazenes: Biodegradable polyphosphazenes第46-47页
        1.8.2. Applications of phosphazenes: Flame retardants第47-48页
        1.8.3. Army Contributions to Phosphazene Chemistry第48-50页
        1.8.4. Applications of phosphazenes:Optical and electro-optical polymers第50-51页
        1.8.5. Composite materials based on phosphazenes第51-53页
    1.9. OBJECTIVE AND SIGNIFICANT OF CURRENT WORK第53-55页
    REFERENCES第55-69页
CHAPTER 2 HIGH-THROUGHPUT SYNTHESIS OF CROSS-LINKED POLY(CYCLOTRIPHOSPHA-ZENE-CO-BIS(AMINOMETHYL)FERROCENE) MICROSPHERES AND THEIR PERFORMANCES第69-106页
    2.1. INTRODUCTION第69-73页
    2.2. EXPERIMENTAL第73-76页
        2.2.1. Materials第73页
        2.2.2. Characterization第73-74页
        2.2.3. Preparation of cross-linked poly(cyclotriphosphazene-co-bis(aminomethyl)ferrocene) microspheres第74-75页
        2.2.4. Adsorption test of cross-linked poly(cyclotriphosphazene-co-bis(aminomethyl)- ferrocene) microspheres for methylene blue第75-76页
    2.3. RESULTS AND DISCUSSION第76-93页
        2.3.1. Mechanism of formation第76-78页
        2.3.2. Characterization and properties of cross-linkedpoly(cyclotriphosphazene-co- bis(aminomethyl)ferrocene) microspheres第78-93页
    2.4. SUMMARY第93-95页
    REFERENCES第95-106页
CHAPTER 3 MULTIPLE FUNCTIONALITIES OF AG NANOPARTICLES SUPPORTED ON CROSS-LINKED HYBRID FERROCENYLPHOSPHAZENE NANOFIBERS: CATALYTIC PERFORMANCE FOR REDUCTION OF 4-NITROPHENOI第106-125页
    3.1. BACKGROUND第106-107页
    3.2. EXPERIMENTAL第107-109页
        3.2.1. Materials and Reagents第107-108页
        3.2.2. Characterizations第108页
        3.2.3. Facile preparation of the ferrocenylphosphazene nanofibers (FcPZ)第108页
        3.2.4. Preparation of the FcPZ@Ag NPs composite第108-109页
        3.2.5. NaBH_4 reduction of 4-NP catalyzed by the FcPZ@Ag NPs composite第109页
    3.3. RESULTS AND DISCUSSION第109-119页
    3.4. SUMMARY第119-120页
    REFERENCES第120-125页
CHAPTER 4 HIGHLY POROUS CROSS-LINKED POLY(CYCLOTRIPHOSPHAZENE-CO-BIS(METHAOXY)FERROCENE HYBRID MICROSPHERES AS DRUG CARRIER第125-144页
    4.1. INTRODUCTION第125-127页
    4.2. EXPERIMENTAL第127-130页
        4.2.1. Materials and reagents第127页
        4.2.2. Characterizations第127页
        4.2.3. Highly porous cross-linked poly(cyclotriphosphazene-co-bis(methaoxy)ferrocene) microspheres formation第127-128页
        4.2.4. Drug loading methodology第128-129页
        4.2.5. Drug Release第129页
        4.2.6. Cytotoxicity第129-130页
        4.2.7. Antioxidant activity第130页
    4.3. RESULTS AND DISCUSSION第130-139页
    4.4. SUMMARY第139-140页
    REFERENCES第140-144页
CONCLUSION第144-148页
ACKNOWLEDGEMENTS第148-150页
LIST OF PUBLICATIONS第150-151页
CONFERENCE PARTICIPATION第151-152页
Shafqat Ali (Author)第152-154页
Prof, Dr, Zhanpeng Wu (Supervisor)第154-156页
附件第156-157页

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