| Abstract | 第1-8页 |
| Contents | 第8-13页 |
| List of Schemes | 第13-14页 |
| List of Figures | 第14-21页 |
| List of Tables | 第21-22页 |
| Abbreviations | 第22-24页 |
| Chapter 1 General introduction and Objectives | 第24-57页 |
| ·HIERARCHICAL STRUCTURED COMPOSITE MICROSPHERES AND THEIR FUNCTIONS | 第25-28页 |
| ·METHOD FOR CONSTRUCTION OF HIERARCHICAL STRUCTURE COMPOSITE MICROSPHERES | 第28-43页 |
| ·Self-assembled heterocoagulation | 第28-30页 |
| ·Hetero-phase polymerization | 第30-42页 |
| ·Emulsion polymerization | 第31-33页 |
| ·Seeded emulsion polymerization | 第33-35页 |
| ·Soap-free emulsion polymerization and Pickering emulsion polymerization | 第35-38页 |
| ·Miniemulsion polymerization | 第38页 |
| ·Dispersion polymerization and precipitation polymerization | 第38-42页 |
| ·Other methods | 第42-43页 |
| ·OBJECTIVE AND SCOPE OF THIS STUDY | 第43-46页 |
| Appendix | 第46页 |
| ·Reference | 第46-57页 |
| Chapter 2 Fabrication of Raspberry Si02/Polystyrene Particles andSuperhydrophobic Particulate Film with High AdhesiveForce | 第57-89页 |
| ·INTRODUCTION | 第58-61页 |
| ·EXPERIMENTAL | 第61-65页 |
| ·Materials | 第61页 |
| ·Fabrication of Raspberry SiO_2/PS Hybrid Particles and Superhydrophobic Particulate Film | 第61-63页 |
| ·Synthesis of w-SiO_2 Particles | 第62页 |
| ·Modification of w-Silica Particles by MPS | 第62页 |
| ·Preparation of Raspberry SiO_2/PS Hybrid Particles by Radiation Miniemulsion Polymerization | 第62-63页 |
| ·Fabrication of SiO_2/PS Particulate Film | 第63页 |
| ·Characterization of Silica Particles and SiO_2/PS Hybrid Particles | 第63-64页 |
| ·Characterization of the SiO_2/PS Particulate Film | 第64-65页 |
| ·RESULTS AND DISCUSSIONS | 第65-80页 |
| ·Effect of Surface Chemistry of the Silica Particles on the Morphology and Wettability of SiO_2/PS Hybrid Particles | 第65-70页 |
| ·Effect of the St to o-SiO_2 Weight Ratio (W_(St/o-SiO_2)) on the Morphology and Wettability of Raspberry-like SiO_2/PS Hybrid Particles | 第70-71页 |
| ·Effect of the SDS Concentration on the Morphology and Wettability of SiO_2/PS Hybrid Particles | 第71-72页 |
| ·The adhesive property of the superhydrophobic SiO_2/PS particulate film | 第72-74页 |
| ·The Discussion on Mechanism for the Strong Adhesion to Water | 第74-77页 |
| ·Effect of DVB on the morphology of SiO_2/PS hybrid particles | 第77-80页 |
| ·SUMMARY | 第80-81页 |
| Appendix | 第81-83页 |
| Reference | 第83-89页 |
| Chapter 3 A Facile Approach to RaspberryPolystyrene/Polyacrylonitrile (PS/PAN) Hybrid Particles forSuperhydrophilic Materials | 第89-114页 |
| ·INTRODUCTION | 第90-91页 |
| ·EXPERIMENTAL | 第91-96页 |
| ·Materials | 第91页 |
| ·Preparation of monodisperse PAA-functionalized PS particles | 第91-92页 |
| ·Preparation of PS/PAN hybrid Particles | 第92-93页 |
| ·Fabrication of PS/PAN Particulate Film | 第93页 |
| ·Characterization | 第93-96页 |
| ·Characterization of P(St-AA) seed particles and PS/PAN hybrid particles | 第93-95页 |
| ·Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) | 第93-94页 |
| ·Particle Size and Size Distribution: Nanoparticle Tracking Analysis (NTA) | 第94-95页 |
| ·X-ray Photoelectron Spectroscopy (XPS) #72 XPS spectra were measured on Thermo ESCALAB 250 X-ray photoelectron spectrometer with the exciting source Al K_α=1486.6 eV under high vacuum (5×10~(-9)Pa). All the samples were dried in vacuum at 50 ℃ | 第95页 |
| ·Thermogravimetric Analyses (TGA) | 第95页 |
| ·Characterization of the PS/PAN Particulate Film | 第95-96页 |
| ·RESULTS AND DISCUSSIONS | 第96-109页 |
| ·FT-IR analysis | 第96页 |
| ·Microstructures of the particles | 第96-97页 |
| ·Nanoparticle Tracking Analysis (NTA) | 第97-98页 |
| ·XPS analysis | 第98-99页 |
| ·TGA analysis | 第99-101页 |
| ·Effect of mass ratio of monomer/polymer (W_(AN/PS)) on the morphology of PS/PAN hybrid particles | 第101-103页 |
| ·Effect of reaction medium pH on the morphology of PS/PAN hybrid particles | 第103-108页 |
| ·The surface wettability of PS/PAN hybrid particles | 第108-109页 |
| ·Summary | 第109页 |
| Appendix | 第109-110页 |
| Reference | 第110-114页 |
| Chapter 4 Facile Method to the Preparation of Raspberry-likeSiCyPAN Hybrid Microsphere | 第114-130页 |
| ·INTRODUCTION | 第115-117页 |
| ·EXPERIMENTAL | 第117-119页 |
| ·Materials | 第117页 |
| ·Synthesis of SiO_2 Particles | 第117-118页 |
| ·Preparation of SiO_2/PAN hybrid microspheres by radiation seeded polymerization | 第118页 |
| ·Characterization | 第118-119页 |
| ·Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) | 第118-119页 |
| ·X-ray Photoelectron Spectroscopy (XPS) | 第119页 |
| ·Thermogravimetric Analyses (TGA) | 第119页 |
| ·RESULTS AND DISCUSSIONS | 第119-127页 |
| ·FT-IR analysis | 第119-120页 |
| ·Microstructures of the particles | 第120-121页 |
| ·XPS analysis | 第121-122页 |
| ·TGA analysis | 第122-123页 |
| ·Effect of mass ratio of monomer/silica (W_(AN/SiO2)) on the morphology of SiO_2/PAN hybrid particles | 第123-124页 |
| ·Preparation of SiO2/C hybrid particles | 第124-126页 |
| ·The surface wettability of SiO_2/PAN hybrid particles | 第126-127页 |
| ·SUMMARY | 第127页 |
| REFERENCE | 第127-130页 |
| Chapter 5 Preparation of Core-shell PS/Si02 Microspheres andTriangle Hybrid Microspheres | 第130-148页 |
| ·INTRODUCTION | 第131-133页 |
| ·EXPERIMENTAL | 第133-135页 |
| ·Materials | 第133页 |
| ·Synthesis of the PS Microspheres | 第133-135页 |
| ·Synthesis of anisotropic hybrid microspheres | 第135页 |
| ·Calculation of the size of PS microspheres and PS/SiO_2 core-shell particles #l12 | 第135页 |
| ·RESULTS AND DISCUSSIONS | 第135-145页 |
| ·TEM, SEM images and FT-IR spectra | 第135-139页 |
| ·Influence of catalysts on the morphology of the PS/SiO_2 hybrid microspheres | 第139-140页 |
| ·Swelling properties of PS/SiO_2 microspheres and preparation of anisotropic hybrid particles | 第140-141页 |
| ·Effect of silica-shell on the morphology of the PS/SiO_2 triangle particles | 第141-142页 |
| ·Effect of weight ratios of monomer/seed particles (W_(St/Seed))on the morphology of the PS/SiO_2 triangle particles | 第142-143页 |
| ·Thermogravimetric analyses (TGA) | 第143-144页 |
| ·Proposed mechanism for the formation of the triangle PS/SiO_2 hybrid particles | 第144-145页 |
| ·SUMMARY | 第145页 |
| REFERENCE | 第145-148页 |
| Chapter 6 Synthesis of Hydrophilic Polystyrene Particles throughRadiation Emulsion Polymerization in the Presence ofP-Cyclodextrin | 第148-166页 |
| ·INTRODUCTION | 第149-151页 |
| ·EXPERIMENTAL | 第151-154页 |
| ·Materials | 第151页 |
| ·Preparation of solid St/β-CD IC particles | 第151-152页 |
| ·Preparation of hydrophilic PS microspheres via γ-ray induced emulsion polymerization | 第152-153页 |
| ·Preparation of the PS latexes via chemically initiated emulsion polymerization | 第153页 |
| ·Characterization | 第153-154页 |
| ·Transmission Electron Microscopy (TEM) | 第153页 |
| ·X-ray Photoelectron Spectroscopy (XPS) | 第153-154页 |
| ·Thermogravimetric analyses (TGA) | 第154页 |
| ·Powder X-Ray Diffraction (XRD) | 第154页 |
| ·Solid-State ~(13)C NMR Spectroscopy | 第154页 |
| ·The Static Water Contact Angle Measurement | 第154页 |
| ·RESULTS AND DISCUSSIONS | 第154-162页 |
| ·Characterization of PS microspheres | 第154-160页 |
| ·The hydrophilic property of PS particles | 第160-162页 |
| ·SUMMARY | 第162页 |
| REFERENCE | 第162-166页 |
| Chapter 7 General conclusions and future work | 第166-171页 |
| ·CONCLUSIONS | 第167-169页 |
| ·FUTURE STUDIES | 第169-171页 |
| 论文图文摘要 | 第171-193页 |
| Appendix. Articles | 第193-194页 |
| Acknowledgements | 第194页 |
